Graphene quantum dots-based nano-biointerface platform for food toxin detection

Analytical and Bioanalytical Chemistry - Due to the similar electrochemical properties to graphene oxide (GO), graphene quantum dots (GQDs) are considered as a highly potential candidate for...     

Lewis acid-catalyzed one-pot, three-component route to chiral 3,3'-bipyrroles

3,3'-Bipyrroles 3 could be synthesized using a double Michael addition reaction involving diaroyl acetylene 1 and the appropriate 1,3-dicarbonyls 2 using ammonium acetate as a nitrogen source. The axial chirality of bipyrrole was anticipated from the X-ray crystal structure and DFT calculations and confirmed by separating the racemates on a chiral column and subsequent CD spectra of the enantiomers. The absolute configuration of the enantiomers was achieved by theoretical CD spectra calculation using the ZINDO method.     

Rapid diastereocontrolled synthesis of 2,2,5-trisubstituted pyrrolidines

2,2,5-Trisubstituted pyrrolidines are available from allylic pyroglutamates by Ireland-Claisen ester rearrangement followed by Eschenmoser sulfide contraction and reduction in a highly diastereoselective and efficient sequence. Some of the products from this sequence exhibit activity against S. aureus, but are much less active against E. coli.     

Superb hydroxyl radical-mediated biocidal effect induced antibacterial activity of tuned ZnO/chitosan type II heterostructure under dark

Journal of Nanoparticle Research - With the widespread use of titanium dioxide (TiO2) human exposure is inevitable, but the exposure data on TiO2 are still limited. This study adopted off-line...     

Λ b →Λ c +a 1 decay in the heavy quark effective theory

Using the heavy quark approximation, we have studied the nonleptonic decay mode Λ _b →Λ _c a ₁. We have included nonfactorizable contributions as well as factorizable ones in our analysis. The estimated branching ratio for this process is (1.4±0.1)% and the asymmetry parameter α found to be −0.8.     

Pd-catalyzed synthesis of α-aryl ketones through couplings of α-arylacetyl chlorides with triarylbismuths as multi-coupling nucleophiles

The cross-coupling reaction of α-arylacetyl chlorides with triarylbismuths was studied under Pd-catalyzed conditions. The reaction was found to be facile under the established protocol and furnished high yields of α-aryl ketones in short reaction times. This work also demonstrated a facile synthesis of various regio-isomeric mono-, di- and tri-substituted α-aryl ketones in high yields. Triarylbismuths were employed as sub-stoichiometric multi-coupling organometallic nucleophiles in this coupling protocol.     

Enantioselective Nitroso‐Diels–Alder Reaction and Its Application for the Synthesis of (−)‐Peracetylated Conduramine A‐1

Cu^I‐catalyzed enantioselective nitroso‐Diels–Alder reactions (NDA reactions) of 2‐nitrosopyridine with various dienes are presented. The [CuPF₆(MeCN)₄]/Walphos‐CF₃ catalyst system is best suited to catalyze the NDA reaction of various dienes by using 2‐nitrosopyridine as a dienophile. In most of the cases studied, cycloadducts are obtained in quantitative yield with very good to excellent enantioselectivities. Based on DFT calculations, a model to explain the stereochemical outcome of the NDA reaction is presented. Finally, an efficient short synthesis of (?)‐peracetylated conduramine A‐1 by applying the enantioselective NDA reaction as a key step is described.     

Critically indecomposable graphs

An undirected graph G=(V,E) with a specific subset X⊂V is called X-critical if G and G(X), induced subgraph on X, are indecomposable but G(V−{w}) is decomposable for every w∈V−X. This is a generalization of critically indecomposable graphs studied by Schmerl and Trotter [J.H. Schmerl, W.T. Trotter, Critically indecomposable partially ordered sets, graphs, tournaments and other binary relational structures, Discrete Mathematics 113 (1993) 191-205] and Bonizzoni [P. Bonizzoni, Primitive 2-structures with the (n−2)-property, Theoretical Computer Science 132 (1994) 151-178], who deal with the case where X is empty.We present several structural results for this class of graphs and show that in every X-critical graph the vertices of V−X can be partitioned into pairs (a₁,b₁),(a₂,b₂),…,(a_m,b_m) such that G(V−{a_j1,b_j1,…,a_jk,b_jk}) is also an X-critical graph for arbitrary set of indices {j₁,…,j_k}. These vertex pairs are called commutative elimination sequence. If G is an arbitrary indecomposable graph with an indecomposable induced subgraph G(X), then the above result establishes the existence of an indecomposability preserving sequence of vertex pairs (x₁,y₁),…,(x_t,y_t) such that x_i,y_i∈V−X. As an application of the commutative elimination sequence of an X-critical graph we present algorithms to extend a 3-coloring (similarly, 1-factor) of G(X) to entire G.