首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6399篇
  免费   316篇
  国内免费   112篇
化学   4232篇
晶体学   36篇
力学   226篇
综合类   10篇
数学   842篇
物理学   1481篇
  2023年   35篇
  2022年   64篇
  2021年   90篇
  2020年   130篇
  2019年   111篇
  2018年   99篇
  2017年   89篇
  2016年   170篇
  2015年   153篇
  2014年   213篇
  2013年   340篇
  2012年   426篇
  2011年   476篇
  2010年   280篇
  2009年   223篇
  2008年   406篇
  2007年   357篇
  2006年   359篇
  2005年   358篇
  2004年   275篇
  2003年   234篇
  2002年   216篇
  2001年   138篇
  2000年   152篇
  1999年   77篇
  1998年   62篇
  1997年   53篇
  1996年   66篇
  1995年   72篇
  1994年   80篇
  1993年   82篇
  1992年   67篇
  1991年   56篇
  1990年   50篇
  1989年   43篇
  1988年   40篇
  1987年   43篇
  1986年   40篇
  1985年   45篇
  1984年   57篇
  1982年   45篇
  1981年   39篇
  1980年   32篇
  1979年   50篇
  1978年   42篇
  1977年   52篇
  1976年   40篇
  1975年   30篇
  1974年   36篇
  1973年   30篇
排序方式: 共有6827条查询结果,搜索用时 46 毫秒
991.
In this Letter, we introduce a simple metal waveguide array for realizing all-angle wide frequency bandwidth negative refraction from the visible to infrared frequencies. Theoretical analysis from the rigorous coupled-wave theory reveals that the negative coupling constant resulting from the anomalous coupling of guided surface plasmon polariton modes contributes to the negative refraction. The analytical results are confirmed by finite-difference time-domain numerical simulations. Our result provides an alternative way to construct robust all-angle negative refractive materials operating in a wide range of frequency from the near-infrared to the visible range.  相似文献   
992.
We have measured the pressure dependence of the supersolid fraction by a torsional oscillator technique. Superflow is found from 25.6 bar up to 136.9 bar. The supersolid fraction in the low temperature limit increases from 0.6% at 25.6 bar near the melting boundary up to a maximum of 1.5% near 55 bar before showing a monotonic decrease with pressure extrapolating to zero near 170 bar.  相似文献   
993.
Combinatorial library screening offers a rapid process for identifying potential therapies to toxins. Hinge peptide libraries, which rely on conformational diversity rather than traditional molecular diversity, reduce the need for huge numbers of syntheses and screening steps and greatly expedite the discovery process of active molecules. Hinge peptide libraries having the structures: Acetyl-X1–X2–hinge–X3–X4–NH2 (capped) and X1–hinge–X2–X3 (uncapped), where X1 through X4 are near-equimolar mixtures of twelve L-amino acids and hinge = 4-aminobutyric acid, were screened for inhibitory activity in bioassays for botulinum neurotoxins A and B (BoNT/A, BoNT/B) and saxitoxin. The zinc protease activity of the reduced light chains of BoNT/A and /B was assayed by measuring the cleavage of synthetic substrates. Saxitoxin activity was measured by the restoration of the viability of neuroblastoma cells treated with ouabain and veratridine. Deconvolution of libraries was accomplished by fixing one position at a time beginning with the C-terminus. Primary library subsets in which position 4 was fixed showed moderate levels of inhibition for BoNT/A. Secondary library subsets showed stronger inhibition in the bioassays. In each of the bioassays, inhibitory potency was stronger when the second position to be fixed was on the opposite side of the hinge, rather than on the same side with respect to the C-terminus, suggesting that the hinge facilitates the interaction of side chains. Inhibitors for all three of the toxins studied were discovered within library subsets, although not necessarily in primary subsets. These studies demonstrate that (1) the best strategy for deconvoluting hinge peptide libraries is by fixing residues alternately on each side of the hinge moiety, and (2) it is essential to investigate secondary subsets even when primary subsets are inactive. The present findings support the concept that the increased flexibility imposed by the inclusion of a central hinge residue in small peptides increases the opportunity for side chain interactions, providing a distinct advantage for hinge peptide libraries over conventional peptide libraries. Hinge peptide libraries are a rich source of novel ligands for modulation of biomechanisms. The library subsets uncovered in this study may possess peptides that will lead to effective therapies to neurotoxin poisoning.  相似文献   
994.
Modification of Newton’s method with higher-order convergence is presented. The modification of Newton’s method is based on King’s fourth-order method. The new method requires three-step per iteration. Analysis of convergence demonstrates that the order of convergence is 16. Some numerical examples illustrate that the algorithm is more efficient and performs better than classical Newton’s method and other methods.  相似文献   
995.
A numerical method is presented for solving the Maxwell-Dirac systems. The Maxwell equations with particle and current densities as the source terms are discretized explicitly. To guarantee the particle conservation, the Dirac equations coupled electromagnetic potentials are discretized by the time-splitting method and implicit finite difference. These numerical schemes are conservative in particle density and have second-order accuracy in time and space. One-dimensional numerical results are given to validate the accuracy and the conservation and three-dimensional examples are presented to describe dynamical behaviors of the Maxwell-Dirac system with several external potentials.  相似文献   
996.
We consider the fractional Burgers' equation on RNRN with the critical dissipation term. We follow the parabolic De-Giorgi's method of Caffarelli and Vasseur and show existence of smooth solutions given any initial datum in L2(RN)L2(RN).  相似文献   
997.
食品中铝的测定及超标对人体的危害   总被引:1,自引:0,他引:1  
用分光光度法测定了油炸食品、膨化、威化、面包粉、海蜇中的铝含量.利用Al3+在乙二胺-盐酸溶液缓冲介质中,与铬天青S及溴代十六烷基吡啶(CPB)反应形成蓝绿色四元胶束,在620nm处测定其吸光度,并对CPB质量浓度进行了最佳选择.结果表明,该法提高了测定灵敏度.5种类型的样品中,海蜇的铝含量最高;面包粉的铝含量最少.此方法允许pH值范围宽、稳定性好、操作简便,测定食品中微量铝得到较好的精密度和准确度.  相似文献   
998.
Abstract

The microstructure of milled mesophase pitch-based carbon fibers (mMPCFs) that have been developed as an anode material for Li ion batteries have been studied as a function of heat treatment temperature (HTT), by SEM, X-ray diffraction, and Raman spectroscopy. And the results obtained are compared with those by X-ray diffraction (XRD) and SEM observations, for the characterization of specific structural features of mMPCFs as a promising anode material.  相似文献   
999.
The normal breast tissue responds to the fluctuation of endogenous hormones during a menstrual cycle (MC) and shows changes in breast density. The changes between left and right breasts of the same women were compared to evaluate the symmetrical response. Twenty-four healthy women were recruited in this study. Four weekly magnetic resonance imaging (MRI) studies were performed during one MC. A computer algorithm was used to segment the breast and the fibroglandular tissue to measure the fibroglandular tissue volume (FV) and three morphological parameters: circularity, convexity and irregularity. The coefficient of variation (CV) for each parameter measured among four MRI studies was calculated; also, the maximal percent change between two MRI studies that show the highest and the lowest FV was calculated. These parameters measured from left and right breasts were compared using Pearson correlation.  相似文献   
1000.
The Index theorem for holomorphic line bundles on complex tori asserts that some cohomology groups of a line bundle vanish according to the signature of the associated hermitian form. In this article, this theorem is generalized to quasi-tori, i.e. connected complex abelian Lie groups which are not necessarily compact. In view of the Remmert–Morimoto decomposition of quasi-tori as well as the Künneth formula, it suffices to consider only Cousin-quasi-tori, i.e. quasi-tori which have no non-constant holomorphic functions. The Index theorem is generalized to holomorphic line bundles, both linearizable and non-linearizable, on Cousin-quasi-tori using L2L2-methods coupled with the Kazama–Dolbeault isomorphism and Bochner–Kodaira formulas.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号