全文获取类型
收费全文 | 31851篇 |
免费 | 1194篇 |
国内免费 | 244篇 |
专业分类
化学 | 21325篇 |
晶体学 | 279篇 |
力学 | 1068篇 |
综合类 | 11篇 |
数学 | 2943篇 |
物理学 | 7663篇 |
出版年
2023年 | 161篇 |
2022年 | 339篇 |
2021年 | 546篇 |
2020年 | 508篇 |
2019年 | 517篇 |
2018年 | 394篇 |
2017年 | 379篇 |
2016年 | 845篇 |
2015年 | 737篇 |
2014年 | 933篇 |
2013年 | 1730篇 |
2012年 | 2213篇 |
2011年 | 2469篇 |
2010年 | 1490篇 |
2009年 | 1297篇 |
2008年 | 2019篇 |
2007年 | 1892篇 |
2006年 | 1792篇 |
2005年 | 1683篇 |
2004年 | 1450篇 |
2003年 | 1156篇 |
2002年 | 1121篇 |
2001年 | 783篇 |
2000年 | 696篇 |
1999年 | 410篇 |
1998年 | 303篇 |
1997年 | 347篇 |
1996年 | 400篇 |
1995年 | 339篇 |
1994年 | 349篇 |
1993年 | 353篇 |
1992年 | 336篇 |
1991年 | 258篇 |
1990年 | 200篇 |
1989年 | 181篇 |
1988年 | 177篇 |
1987年 | 163篇 |
1986年 | 127篇 |
1985年 | 216篇 |
1984年 | 152篇 |
1983年 | 117篇 |
1982年 | 164篇 |
1981年 | 126篇 |
1980年 | 119篇 |
1979年 | 114篇 |
1978年 | 128篇 |
1977年 | 136篇 |
1976年 | 134篇 |
1975年 | 131篇 |
1973年 | 130篇 |
排序方式: 共有10000条查询结果,搜索用时 93 毫秒
31.
The crystal structure, magnetic and magnetotransport properties of the variation of B′-site transition metal in Sr2FeMO6 (M=Mo, W) with double perovskites structure have been investigated systematically. Measurements of magnetization vs. temperature at H=5 T show that Sr2FeMoO6 is a ferromagnet and Sr2FeWO6 is an antiferromagnet with TN∼35 K. Additionally, the large magnetoresistance ratio (MR) of ∼22% (H=3 T) at room temperature (RT) was observed in the Sr2FeWO6 compound. However, the Sr2FeMoO6 compound did not show any significant MR even at high fields and RT (MR∼1%; H=3 T and 300 K). The implications of these findings are supported by band structure calculations to explain the interaction between the 4d(Mo) and 5d(W) orbitals of transition metal ions and oxygen ions. 相似文献
32.
Jong Chan Lee Jin Young Park So Young Yoon Yong Hun Bae Seung Jun Lee 《Tetrahedron letters》2004,45(1):191-193
A novel and direct method for the synthesis of α-halocarbonyl compounds using sequential treatment of carbonyl compounds with [hydroxy(tosyloxy)iodo]benzene followed by magnesium halides under solvent-free microwave irradiation conditions is described. 相似文献
33.
Vernon Barger Cheng-Wei Chiang Paul Langacker Hye-Sung Lee 《Physics letters. [Part B]》2004,580(3-4):186-196
We study the effects of an extra U(1)′ gauge boson with flavor changing couplings with fermion mass eigenstates on certain B meson decays that are sensitive to such new physics contributions. In particular, we examine to what extent the current data on Bd→φK and Bd→η′K decays may be explained in such models, concentrating on the example in which the flavor changing couplings are left-chiral. We find that within reasonable ranges of parameters, the Z′ contribution can readily account for the anomaly in SφKS but is not sufficient to explain large branching ratio of Bd→η′K with the same parameter value. SφKS and Sη′KS are seen to be the dominant observables that constrain the extra weak phase in the model. 相似文献
34.
Sungyong Kim Lingxin Chen Sangyeop Lee Gi Hun Seong Jaebum Choo Eun Kyu Lee Chil-Hwan Oh Sanghoon Lee 《Analytical sciences》2007,23(4):401-405
A rapid DNA analysis has been developed based on a fluorescence intensity change of a molecular beacon in a PDMS microfluidic channel. Recently, we reported a new analytical method of DNA hybridization involving a PDMS microfluidic sensor using fluorescence energy transfer (FRET). However, there are some limitations in its application to real DNA samples because the target DNA must be labelled with a suitable fluorescent dye. To resolve this problem, we have developed a new DNA microfluidic sensor using a molecular beacon. By monitoring the change in the restored fluorescence intensity along the channel length, it is possible to rapidly detect any hybridization of the molecular beacon to the target DNA. In this case, the target DNA does not need to be labelled. Our experimental results demonstrate that this microfluidic sensor using a molecular beacon is a promising diagnostic tool for rapid DNA hybridization analysis. 相似文献
35.
N. Wright und W. C. Lee 《Fresenius' Journal of Analytical Chemistry》1940,120(1-2):39-40
Ohne Zusammenfassung 相似文献
36.
The transverse momentum spectra for pions observed by WA80 and NA35 collaborations are analysed within a fireball model with collective isentropic expansion and a realistic freeze-out criterion. By varing the initial state of the fireball, an excellent fit to the data is achieved for the whole measured range ofP T . Slight differences in the data for the spectral slopes from central and pheripheral collisions originate in our model from the difference in the size of the fireball and in the number of participating nucleons in central and peripheral collisions. Using additional information from two-pion correlations, we can extrapolate our model back from the freeze-out point (determined from the spectra) to the initial state; we find that an initial energy density of 1.5–2GGeV/fm3 is sufficient to explain the data from central O+Au collisions at 200A GeV. 相似文献
37.
This paper proposes and analyzes a GaAs traveling-wave optical modulator which uses a modulated coplanar strip electrode with periodic cross-tie overlay. This slow-wave structure can be designed to satisfy phase velocity and impedance matching conditions simultaneously. The dominant conductor loss in the slow-wave structure is reduced using the modulated coplanar strip electrode. The calculated 3-dB modulation bandwidth (100 GHz) is much wider than the bandwidth limit (30 GHz) of conventional electrode structures that are limited by phase velocity mismatch.This work was supported by the U.S. Army Research Office under contract DAAL-03-88-K-0005 and the Texas Advanced Technology Program. 相似文献
38.
Ching Sum Hui Lillian Sze Man Lam Chun Yin Wai Kin Chan Aleksandra B. Djurii 《Journal of polymer science. Part A, Polymer chemistry》2003,41(11):1708-1715
Polyurethanes incorporated with rhenium diimine complexes were synthesized. The polymers exhibited interesting morphologies and solution properties. Results from gel permeation chromatography suggested the formation of polymer aggregates in solutions. The polymers could act as probes for metal ions. The addition of metal ions to polymer solutions led to significant changes in the electronic absorption properties of the polymer solutions. This was attributed to the interactions between the polyether moieties and metal ions. The metal complexes could also act as efficient photosensitizers. After doping with charge‐transport viologens, the photoconductivity of the polymers was greatly enhanced. The experimental quantum efficiency was simulated with Onsager's theory. The thermalization distances and the primary yields were typically 12–14 Å and 10?3, respectively. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 1708–1715, 2003 相似文献
39.
Timothy M. Chan 《Discrete and Computational Geometry》2005,34(1):11-24
We give a surprisingly short proof that in any planar arrangement of n curves where each pair intersects at most a fixed number (s) of
times, the k-level has subquadratic (O(n2-1/2s) complexity. This answers one of the main open problems from the author’s previous paper [DCG 29, 375-393 (2003)],
which provided a weaker upper bound for a
restricted class of curves only (graphs of degree-s polynomials).
When combined with existing tools (cutting curves, sampling, etc.),
the new idea generates a slew of improved k-level results for
most of the curve families studied earlier, including a
near-O(n3/2 bound for parabolas. 相似文献
40.
Stuart P. RomerilVictor Lee Jack E. Baldwin Timothy D.W. ClaridgeBarbara Odell 《Tetrahedron letters》2003,44(42):7757-7761
The absolute configuration of the marine sponge alkaloid pyrinodemin A is established by organic synthesis. 相似文献