具有光学活性的两亲性聚炔-聚乙二醇单甲醚接枝共聚物的合成与表征

设计并合成了含手性侧基和含亲水性大分子侧基的接枝聚炔共聚物[聚(丙炔酸薄荷醇酯-co-丙炔酸聚乙二醇单甲醚酯)(poly(a-co-b),(a:propiolic acid L-menthol ester;b:propiolic acid polyethylene glycol monomethyl ether est...     

Heteroscorpionate rare-earth metal zwitterionic complexes: syntheses, characterization, and heteroselective catalysis on the ring-opening polymerization of rac-lactide

Novel neutral phosphine-modified heteroscorpionate ligand (3,5-Me(2)Pz)(2)CHPPh(2) (1) and its derivatives oxophosphine (2) and iminophosphine (3) heteroscorpionates were synthesized for the first time. These neutral heteroscorpionate ligands displayed unique chemistry towards rare-earth metal tris(alkyl)s [Ln(CH(2)SiMe(3))(3)(thf)(2)] (Ln=Y, Lu, Sc). The reaction between compound 1 and [Ln(CH(2)SiMe(3))(3)(thf)(2)] afforded heteroscorpionate rare-earth metal trialkyl adduct complexes 4a-c. Compounds 2 and 3 were treated with [Ln(CH(2)SiMe(3))(3)(thf)(2)] to give the unprecedented zwitterionic heteroscorpionate rare-earth metal dialkyls 5 and 6, respectively. In the process, the heteroscorpionates transferred to the carbanions by means of methine C-H bond cleavage that was attributed to the presence of the electron-withdrawing groups. In addition the ligand and central metal showed a concerted effect on both the catalytic activity and specific selectivity of complexes 4-6 for the ring-opening polymerization (ROP) of rac-lactide (rac-LA). All the adduct complexes 4 were nonselective and gave atactic polylactide (PLA), probably due to the dissociation of ligand 1 from the active metal center during the polymerization. Strikingly, zwitterionic complexes 5 catalyzed rapid ROP of rac-LA to produce PLAs with heterotacticity up to 0.87. However, the zwitterionic complexes 6 were less active and less selective than 5, which might be on account of the stronger coordination of the tetradentate ligand. Complexes 5 represent rare examples of the selective ROP of rac-LA mediated by rare-earth metal complexes supported by non-bisphenolate ligands.     

MICROMECHANICAL MODELLING OF PHASE TRANSFORMATION BEHAVIOUR OF A TRANSITIONAL SOIL

Experiments show that silts and silty soils exhibit contraction followed by dilation during shearing and the slope of failure line decreases at large strains, termed as phase transformation behaviour. This paper is to develop a new micromechanical stress-strain model that accounts for the phase transformation behaviour by explicitly employing the phase transformation line and its related friction angles. The overall strain includes plastic sliding and plastic compression among grains. The internal-friction angle at the phase transformation state and the void state variable are employed to describe the phase transformation behaviour. The model is examined by simulating undrained and drained triaxial compression tests performed on Pitea silts. The local stress-strain behaviour for contact planes is also investigated.     

New augmented Lyapunov–Krasovskii functional approach to stability analysis of neural networks with time-varying delays

This paper is concerned with the problem of stability analysis for neural networks with time-varying delays. By constructing a newly augmented Lyapunov functional and some novel techniques, delay-dependent criteria to guarantee the asymptotic stability of the concerned networks are derived in terms of linear matrix inequalities (LMIs). The improvement of feasible region of the proposed criteria comparing with the previous works is shown by two numerical examples.     

侵彻过程中弹引螺纹连接结构振动特性研究

针对侵彻过程中的弹引系统,对弹引螺纹连接结构振动特性进行了研究,建立了弹引螺纹连接结构弹性模型。在模型中,充分考虑了螺纹载荷分布不均匀的特性,不但给出了螺纹载荷分布规律,还给出了螺纹连接结构的等效刚度和振动频率;同时,为了验证模型的正确性,对弹引螺纹连接结构的拉伸和冲击过程进行了有限元仿真和试验,分别通过对弹引系统各结构振动特性的计算和对实测过载信号进行时频分析得到了系统的频率特性;将弹引系统的振动频率与实测过载信号的时频分析结果进行了对比。分析计算和试验结果发现:与静载荷时相比,冲击载荷作用下第一扣螺纹承受的载荷更大;螺纹连接结构的刚度明显小于固连结构;增加螺纹材料刚度、增加螺纹旋合长度、减小螺距能够有效增加螺纹连接结构固有频率;在侵彻过载测试信号的时频分析结果中明显存在与螺纹连接结构的振动频率一致的振动信号,并且该频率成分的信号幅值很高,对过载信号影响很大。     

UVB Irradiation Enhances TiO2 Nanoparticle‐induced Disruption of Calcium Homeostasis in Human Lens Epithelial Cells

Currently, titanium dioxide nanoparticles (TiO₂ NPs) have been widely used in various applications including cosmetics, food additives and biomedicine. However, there are few reports available using TiO₂ NPs to treat ocular diseases. Posterior capsular opacification (PCO) is the most frequent complication after cataract surgery, which is induced by the proliferation and migration of lens epithelial cells. Thus, inhibiting the proliferation of lens epithelial cells will efficiently reduce the occurrence of PCO. In this study, we investigated the effects of TiO₂ NPs on HLE B‐3 cells with or without ultraviolet B (UVB) irradiation in vitro. We found that TiO₂ NPs can inhibit HLE B‐3 cell growth, cause the elevation of intracellular [Ca²⁺], produce excessive reactive oxygen species (ROS), further reduce Ca²⁺‐ATPase activity and decrease the expression of plasma membrane calcium ATPase 1 (PMCA1), finally disrupt the intracellular calcium homeostasis and induce cell damage. Importantly, UVB irradiation can apparently enhance these effects on HLE B‐3 cells in the presence of TiO₂ NPs. Taken together, the generation of excessive ROS and the disruption of intracellular calcium homeostasis may be both involved in TiO₂ nanoparticle‐induced HLE B‐3 cell damage under UVB irradiation.     

关于有限论域上模糊度定理的一个注记

设F（U）为有限论域U={u1,u2,…,un}上的模糊幂集.令D：F（U）→[0,1],AaD（A）=g（∑i=1^n ci fi（A（ui）））,其中ci〉0,fi：[0,1]→[0,＋∞）满足（1）fi（x）=fi（1-x）,（2）fi（0）=0,（3）fi在[0,0.5]上严格递增.又设a=∑i=1^n ci fi（0,5）,且g：[0,a]→[0,1]严格递增,g（0）=0,g（a）=1.某教材中的定理断定具有上述性质的映射D为F（U）上的模糊度函数.本文构造出具有上述性质的D,但D不满足模糊度函数定义中的可加性条件,故不为F（U）上的模糊度函数.本文进一步指出,若将g的定义域扩展为[0,2a],并再假定g是可加的,则可使D为F（U）上的模糊度函数.     

The diffusive logistic model with a free boundary in heterogeneous environment

In this paper, we study the population dynamics of an invasive species in heterogeneous environment which is modeled by a diffusive logistic equation with free boundary condition. To understand the effect of the dispersal rate D and the parameter μ (the ratio of the expansion speed of the free boundary and the population gradient at the expanding front) on the dynamics of this model, we divide the heterogeneous environment into two cases: strong heterogeneous environment and weak heterogeneous environment. By choosing D and μ as variable parameters, we derive sufficient conditions for species spreading (resp. vanishing) in the strong heterogeneous environment; while in the weak heterogeneous environment, we obtain sharp criteria for the spreading and vanishing. Moreover, when spreading happens, we give an estimate for the asymptotic spreading speed of the free boundary. These theoretical results may have important implications for prediction and prevention of biological invasions.     

Novel alkoxyanthracene donor and benzothiadiazole acceptor for organic thin film transistor and bulk heterojunction organic photovoltaic cells

Novel alkoxy anthracene (ODA)‐based polymeric semiconductors were designed for polymer solar cell applications. Alkoxyanthracene, which contains many π electrons and electron donating group, was easily synthesized. The copolymers, poly(alkoxy anthracene‐alt‐thiophene benzothiadiazole thiophene) poly(ODA‐TBT) and poly(alkoxy anthracene‐alt‐benzothiadiazole) poly(ODA‐BT), have been obtained by Suzuki coupling polymerization. Both polymers have ODA unit as a donor and benzothiadiazole as an acceptor. ODA‐TBT has thiophene linkages between ODA and benzothiadiazole. The optical, thermal, and electrochemical properties have been investigated by UV–visible absorption, thermal gravimetric analysis, differential scanning calorimetry, and CV. Organic thin‐film transistor using polymers showed that the hole mobility of poly(ODA‐alt‐TBT) was around 3.6 × 10^?3 cm²/Vs with on/off ratio of 9.91 × 10⁵ while that of poly(ODA‐alt‐BT) was around 1.21 × 10^?2 cm²/Vs with on/off ratio of 2.64 × 10⁶. Organic photovoltaic performance based on polymers were evaluated with a configuration of ITO/PEDOT:PSS/active layer/LiF/Al. Poly(ODA‐TBT) exhibits a short circuit current (J_sc) of 3.9 mA/cm² and power conversion efficiency (PCE) of 1.4%, and poly(ODA‐BT) exhibits the J_sc of 6.4 mA/cm² and PCE of 2.2%. The better device performance of poly(ODA‐BT) is attributed to its charge transfer ability and enhanced mobility and crystallinity although poly(ODA‐BT) does not have extended π‐conjugation due to twisted structure compared with poly(ODA‐TBT). © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 1306–1314     

纳秒强光场下呋喃的激光电离中高价离子的产生

利用 2 5ns脉冲Nd :YAG 5 32nm的激光 ,在 10 11W/cm2 的光场强度下 ,用飞行时间质谱对不同条件下呋喃的激光电离过程进行了研究 .当利用氩作为载气时 ,首次观察到了较强的Cn + (n =2～ 4 )和Om + (m =2～ 3)离子信号 .通过测定峰分裂和数值模拟计算的方法可以确定其中C2 + 、C3 + 和C4+ 的最可几平动能分别为 2 1、6 3和 10 0eV ,O2 + 和O3 + 的最可几平动能分别为 2 0和 4 0eV .质谱峰型的分裂现象和激光延迟实验结果表明 ,这些高价离子可能来源于呋喃团簇的库仑爆炸过程 .