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111.
L'abbé C Meersschaut J Sturhahn W Jiang JS Toellner TS Alp EE Bader SD 《Physical review letters》2004,93(3):037201
We introduce nuclear resonant magnetometry as a means to record the magnetization curve of isotopically enhanced regions of a sample. It is based on nuclear resonant scattering with circularly polarized synchrotron radiation and the use of a nuclear resonant reference sample. We apply this approach to study the interlayer coupling in Fe/Cr(100) multilayers and to obtain a layer-specific magnetization curve. Our measurements provide experimental evidence for the existence of a nontrivial interlayer-coupling angle in Fe/Cr/Fe. 相似文献
112.
Hasan K. M. Faridul Horváth Péter György Bak Miklós Le Duong Hung Anh Mucsi Zsuzsanna Mária Alpár Tibor 《Cellulose (London, England)》2021,28(12):7859-7875
Cellulose - Herein, natural fiber (energy reeds and rice straw) reinforced with phenol formaldehyde (PF) polymeric resin biocomposites are developed and reported in this study. The dimensions of... 相似文献
113.
González-San Miguel HM Alpízar-Lorenzo JM Cerdà V 《Analytical and bioanalytical chemistry》2007,387(2):663-671
A technique based on multisyringe chromatography (MSC) was developed to determine three beta-lactamic antibiotics. Amoxicillin (AMOXI), ampicillin (AMPI) and cephalexin (CEPHA) were analyzed using a system with a very simple design and very low-cost equipment consisting of a multisyringe module, three low-pressure solenoid valves, a monolithic Chromolith Flash RP-18e column and a diode array spectrophotometric detector monitoring at 250 nm. Mobile phases containing methanol:acetic acid (0.1 M)-sodium acetate (0.1 M), pH 6.2, were tested for various ratios of methanol:acetic acid-sodium acetate, but a ratio of 10:90 gave optimum results with a flow rate of 2 ml min(-1). Validation parameters were evaluated for amoxicillin. The response to amoxicillin was linear over the range 0.04-0.4 mg/mL, with a correlation coefficient of 0.9996; precisions, evaluated as the repeatability for 0.04, 0.16 and 0.4 mg/mL amoxicillin, were 0.6%, 0.1% and 0.6%, respectively. Recovery from a generic formulation of amoxicillin was evaluated. The method showed selectivity in the presence of excipients commonly used in capsules, and satisfactory specificity was observed for amoxicillin and hydrolytic degradation products. The linearity was also evaluated for cephalexin and ampicillin. The conditions selected for MSC separation were compared with those for a HPLC system, and similar results were obtained in terms of chromatographic parameters but a difference in retention times was observed. 相似文献
114.
Synthesis,Spectral, Thermal Studies of Co(II), Ni(II), Cu(II) and Zn(II)‐arginato Complexes. Crystal Structure of Monoaquabis(arginato‐κO,κN)copper(II). [Cu(arg)2(H2O)].NaNO3 下载免费PDF全文
Dursun Ali Köse Emre Toprak Emre Avcı Gülçin Alp Avcı Onur Şahin Orhan Büyükgüngör 《中国化学会会志》2014,61(8):881-890
Transition metal complexes of arginine (using Co(II), Ni(II), Cu(II) and Zn(II) cations separately) were synthesized and characterized by FTIR, TG/DTA‐DrTG, UV‐Vis spectroscopy and elemental analysis methods. Cu(II)‐Arg complex crystals was found suitable for x‐ray diffraction studies. It was contained, one mole CuII and Na+ ions, two arginate ligands, one coordinated aqua ligand and one solvent NO3? group in the asymmetric unit. The principle coordination sites of metal atom have been occupied by two N atoms of arginate ligands, two carboxylate O atoms, while the apical site was occupied by one O atom for CuII cation and two O atoms for CoII, NiII, ZnII atoms of aqua ligands. Although CuII ion adopts a square pyramidal geometry of the structure. CoII, NiII, ZnII cations have octahedral due to coordination number of these metals. Neighbouring chains were linked together to form a three‐dimensional network via hydrogen‐bonding between coordinated water molecule, amino atoms and O atoms of the bridging carboxylate groups. CuII complex was crystallized in the monoclinic space group P21, a = 8.4407(5) Å, b = 12.0976(5) Å, c = 10.2448(6) Å, V = 1041.03(10) Å3, Z = 2. Structures of the other metal complexes were similar to CuII complex, because of their spectroscopic studies have in agreement with each other. Copper complex has shown DNA like helix chain structure. Lastly, anti‐bacterial, anti‐microbial and anti‐fungal biological activities of complexes were investigated. 相似文献
115.
Aysel Ba?o?lu Semanur Parlayan Mira? Ocak Hakan Alp Halit Kantekin Mustafa ?zdemir ümmühan Ocak 《Journal of fluorescence》2009,19(4):655-662
A new cryptand compound carrying 2-hydroxy-1-naphthylidene Schiff base moiety (3) was designed and synthesized by reaction of the corresponding macrobicyclic amine compound (1) and 2-hydroxy-1-naphthaldehyde (2). The influence of metal cations such as Mg2+, Ca2+, Sr2+, Fe2+,Co2+, Mn2+, Zn2+, Cd2+, Hg2+, Al3+ and Pb2+ on the spectroscopic properties of the new fluoroionophore was investigated in acetonitrile-dichloromethane solution (9.5/0.5)
by means of absorption and emission spectrometry. The blue shifts on the fluorescence spectrum were observed for all metal
cations at 504nm. At the same time the fluorescence spectrum of the ligand showed quenching in the intensity of the signal
at 504 nm for all metal cations except for Zn2+. Interaction of Co2+ with the ligand caused quenching of naphtyl fluorescence higher than 84%. The method showed good selectivity and sensitivity
for Co2+ with respect to other metal cations with linear range and detection limit of 1.5 × 10−7 to 3.3 × 10−6M and 4.8 × 10−8M respectively. 相似文献
116.
Resul Sevinçek Muhittin Aygün Serap Alp Canan Kazak 《Journal of chemical crystallography》2011,41(8):1140-1144
Abstract
Molecular and crystal structure of 4-[(p-N,N-dimethylamino)benzylidene]-2-phenyloxazol-5-one, C18H16N2O2, have been determined by single crystal X-ray diffraction study. The title compound is monoclinic, with a = 12.1704(23) ?, b = 3.9810(5) ?, c = 30.9603(56) ?, β = 101.176(15)°, Z = 4, D x = 1.32 g/cm3, μ(Mo Kα) = 0.087 mm−1, and space group is P121/c1. The structure was solved by direct methods and refined to a final R = 0.047 for 3166 reflections with I > 2σ(I). The crystal structure is stabilized by C–H⋯O and C–H⋯N type intra-molecular, C–H⋯O type inter-molecular interactions. To enlighten the flexibility and the geometric isomerism (E or Z) of the title compound, the selected torsion angle is varied from −180 to 180° in every 10° separately and molecular energy profile is calculated and analyzed. 相似文献117.
We describe the characterization of a new optical CO2 sensor based on the change in the fluorescence signal intensity of 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt
(HPTS) in green chemistry reagents—room-temperature ionic liquids (RTILs). As far as we are aware, this is the first time
RTILs, 1-methyl-3-butylimidazolium tetrafluoroborate (RTIL-I) and 1-methyl-3-butylimidazolium bromide (RTIL-II), have been
used as matrix materials with HPTS in an optical CO2 sensor. It should be noted that the solubility of CO2 in water-miscible ionic liquids is approximately 10 to 20 times that in conventional solvents, polymer matrices, or water.
The response of the sensor to gaseous and dissolved CO2 has been evaluated. The luminescence intensity of HPTS at 519 and 521 nm decreased with the increasing concentrations of
CO2 by 90 and 75% in RTIL-I and RTIL-II, respectively. The response times of the sensing reagents were in the range 1–2 min for
switching from nitrogen to CO2, and 7–10 min for switching from CO2 to nitrogen. The signal changes were fully reversible and no significant hysteresis was observed during the measurements.
The stability of HPTS in RTILs was excellent and when stored in the ambient air of the laboratory there was no significant
drift in signal intensity after 7 months. Our stability tests are still in progress.
相似文献
118.
Esen Ercan Alp Tuğrul Hakioğlu Süheyla Özbey Zehra Sayers Ömer Yavaş 《Synchrotron Radiation News》2013,26(2):42-43
Under the glowing southern Turkish sun, a group of 54 students from eight different countries and 18 teachers from all over the world gathered for 10 days to learn about and discuss the latest developments in the applications of X-rays in different branches of science. The International Henry Moseley School and Workshop on X-ray Science was held at the Institute of Theoretical and Applied Physics in Turunç, Turkey, from June 14 to 23, 2012. 相似文献
119.
120.