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941.
Ugur Güven 《Acta Mechanica Sinica》2012,28(3):911-912
Allam and Tantawy [1] presented an analytical solution for stress distribution and perturbations of the magnetic field vector in FGM hollow structures made from viscoelastic composite materials .While studying this article, the discusser noticed a confusion in 相似文献
942.
Dr. Çiğdem Hopa Raif Kurtaran Akın Azizoğlu Mahir Alkan N. Burcu Arslan Canan Kazak 《无机化学与普通化学杂志》2011,637(9):1238-1245
Monomeric zinc(II) and mercury(II) complexes containing tripodal nitrogen donor ligand 2,6‐bis(3,4,5‐trimethyl‐N‐pyrazolyl)pyridine (btmpp) were synthesized, and characterized by elemental and spectroscopic (IR, UV/Vis) analyses, TG‐DTA and single‐crystal X‐ray diffraction studies. X‐ray analyses of the complexes [Zn(btmpp)Cl2] ( 2 ) and [Hg(btmpp)(SCN)2] ( 3 ) showed that both structures crystallize in space group P21/c with a = 7.9722(6), b = 18.3084(13), c = 13.3117(9) Å and Z = 4 for 2 and a = 8.7830(3), b = 21.1489(7), c = 12.0682(4) Å and Z = 4 for 3 . Both monomeric units contain pentacoordinate metal ions in distorted square‐pyramidal arrangement. The structures of complexes 2 and 3 were also computed with DFT methods at B3LYP/LanL2DZ level and are in good agreement with the experimental values obtained from X‐ray analysis. The NPa charge distributions, HOMO–LUMO gaps, and dipole moments for 1 , 2 , and 3 were also reported. Natural bond orbital analyses were performed to reveal local charges and charge transfers in 1 , 2 , and 3 . 相似文献
943.
In this study, antimicrobial polycaprolactone composite films containing 12.5% silica and 0.15% silver nanorods were prepared using the roll‐milling method. The destruction of E. coli and S. aureus on the surface of the composite films was evaluated after 6 hr of incubation at 37°C. For the E. Coli, no bacterial contamination was detected after 6 hr and the film surface was completely disinfected with 100% reduction of the microbial contamination. For the S. aureus, 94% reduction of the bacterial contamination was observed after 6 hr. The results were compared with the composite films containing triclosan, a broad‐spectrum antimicrobial agent. The antimicrobial activity tests with 0.25% triclosan incorporated polycaprolactone‐silica composite films showed only 70% reduction of E. coli and 95% reduction of S. aureus after 6 hr. The results demonstrated that the use of silver nanoparticles in the biopolymer industry has huge potential for the self‐cleaning applications. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
944.
945.
946.
Carboxymethyl cellulose (CMC) has been used widely to enhance dry strength of paper and uniformity of sheet in the papermaking
industry. Besides these positive effects, it may affect the fines retention and dewatering processes negatively. These negative
effects are mainly seen when fiber modifications with high CMC dosages are studied in laboratory scale. In this paper, the
effect of fiber modification with CMC on the deposition of precipitated calcium carbonate (PCC) and on the dewatering process
in the presence of cationic polyacrylamide (CPAM)/bentonite microparticle flocculation system is examined. It was determined
that fiber modification with 10 mg g−1 of CMC decreased PCC deposition at the initial addition of CPAM and gave better PCC deposition at 2 mg g−1 of CPAM. It was also observed that PCC deposition on unmodified fibers is higher at lower CPAM concentration. PCC deposition
was found as almost stable after a maximum value obtained at 0.5 mg g−1 of bentonite concentration for fiber modified with 40 mg g−1 of CMC. This indicates that interaction between CPAM and bentonite particles changed due to higher surface charge and CMC
conformation on fibers. Results of the dewatering experiments showed that CMC modification increased the drainage time due
to a denser and more plugged sheet. This negative effect was compensated with higher concentrations of CPAM and bentonite.
On the other hand, dewatering is also affected by the mass ratio of CMC and CPAM, which was not the optimum one in this study
at lower of CPAM. Thus, the increase in the drainage time in the presence of CMC on the fiber surface could be also caused
by incorrect ratios of chemicals because the effect of CMC on the drainage time was not observed at higher concentrations
of CPAM. 相似文献
947.
Serpil Demir Yasemin Gökçe Nazan Kaloğlu Jean‐Baptiste Sortais Christophe Darcel İsmail Özdemir 《应用有机金属化学》2013,27(8):459-464
A series of new piano‐stool iron(II) complexes comprising N‐heterocyclic carbene ligands [Fe(Cp)(CO)2(NHC)]I (NHC = 1,3‐disubstituted imidazolidin‐2‐ylidene) have been synthesized and analyzed by 1H NMR, 13C NMR, IR, elemental analysis and mass spectrometric techniques. These compounds were easily prepared from the reaction of disubstituted imidazolidin‐2‐ylidene with [FeI(Cp)(CO)2] in toluene at room temperature. These complexes were tested in the catalytic hydrosilylation reaction of aldehydes and ketones with phenylsilane in solvent‐free conditions. After a basic hydrolysis step, the corresponding alcohols were obtained in good yields. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
948.
This study reports the development of a novel sensing material that reports on analyte concentrations via diffraction of visible
light from polymerized crystalline colloidal arrays (PCCA). The PCCA contains periodic crystalline colloidal array (CCA) of spherical polystyrene colloids. This new method permanently locks the order of the CCA by embedding the CCA into a polymer
network. These materials are mostly used in the development of novel materials which are basically called sensors for metal
ions and all kinds of organic molecules. The polymer around the crystalline colloid can be functionalized with some recognition
molecule, making these materials useful as optical sensors. We developed a sensor, utilizing crown ether, 2-aminomethyl-18-crown-6
(2A18C6) as the recognition agent, that detects K+ in the concentration range from 5 to 160 ppm. 相似文献
949.
Cranes employed for load transfer are large volume machines and canbe designed to accomplish linear, planar or spatial motions dependingon the intended use. Understanding the dynamic behavior of thesesystems, which have a load-carrying capacity of hundreds of tonnes, ishighly noteworthy for system design, control, and work safety. Inthis study, a theoretical model of a spatially actuated telescopic rotarycrane is obtained with provided assumptions using Bond Graph techniques.Following the modeling of an actuation system and of a main structure,unification of these two is accomplished. Since the overall system consistsof high nonlinearity originating from geometric nonlinearity, gyroscopicforces, hydraulic compressibility, and elastic boom structure, the resultingderivative causality problem caused by rigidly coupled inertia elementsis addressed for this highly nonlinear system and consequential systemstate-space equations are presented. 相似文献
950.
Celal Tuğrul Zeyrek Nefise Dilek Mustafa Yıldız Hüseyin Ünver 《Molecular physics》2014,112(19):2557-2574
Synthesis, crystallographic characterisation, spectroscopic (Fourier transform infrared spectroscopy [FT-IR]) and density functional modelling studies of the Schiff base 1-[(4-ethoxyphenylimino)methyl]napthalene-2-ol (C19H17NO2) have been reported. The molecular structure obtained from X-ray single-crystal analysis of the investigated compound in the ground state has been compared using Hartree–Fock and density functional theory (DFT) with the 6-311++G(d,p) basis set. In addition to the optimised geometrical structures, atomic charges, molecular electrostatic potential, natural bond orbital, non-linear optical (NLO) effects and thermodynamic properties of the compound have been investigated by using DFT. The experimental (FT-IR) and calculated vibrational frequencies (using DFT) of the title compound have been compared. The solvent effect was also investigated for obtained molecular energies and the atomic charge distributions of the compound. There exists a good correlation between experimental and theoretical data for enol-imine form of the compound. The total molecular dipole moment (µ), linear polarisability (α), and the first-order hyperpolarisability (β) were predicted by the B3LYP method with different basis sets 6-31G(d), 6-31+G(d,p), 6-31++G(d,p), 6-311+G(d) 150 and 6-311++G(d,p) for investigating the effects of basis sets on the NLO properties. Our computational results yield that βtot for the title compound is greater than those of urea. 相似文献