Effect of nonlinear strain paths on forming limits under isotropic and anisotropic hardening

The path-dependence of the conventional Forming Limit Diagram (FLD) is an important issue for its applications in industry. Great efforts have been made to understand the nature of the path-dependence with both experimental and theoretical approaches, many of them attempting to find a path-independent way for the application of forming limits. In this paper, we focus on the nonlinear strain path effect on forming limit predictions using both isotropic and anisotropic hardening models. The Forming Limit Diagram (FLD), Forming Limit Stress Diagram (FLSD) and Forming Limit Effective Strain Diagram (epFLD) of sheet metals subject to linear and nonlinear strain paths are analyzed and compared using the Marciniak–Kuczynski approach. An anisotropic hardening model based on Yoshida and Uemori development is adopted in this study, and it is coupled with the traditional Hill’48 yield surface. This model is capable of describing the complex Bauschinger phenomenon after the material undergoes the reverse loading process such as the early re-yielding, work-hardening stagnation and permanent softening. Two different scenarios for the change of strain paths are also investigated. In the first scenario, the sheet material is initially loaded with a fixed strain increment ratio, unloaded to the free stress state, and then reloaded with a different strain increment ratio until the forming limit is reached. In the second scenario, the material does not undergo elastic unloading. Instead, the strain path is abruptly changed to a different strain increment ratio and the material undergoes continuous loading until the forming limit is reached. It is found that the work-hardening behavior after the pre-straining and the loading scenario plays an important role in the path dependent behavior of forming limits. Detailed analysis reveals that the M–K approach may have contributed to the significance of path-dependence observed in this study, especially at high pre-strain levels.     

14-Hydroxy-14-phenyldibenzo[a,j]xanthene as a lattice host: crystal and molecular structure of its (1:1) complex with diethyl ether

The title compound 14-hydroxy-14-phenyldibenzo[a,j]xanthene 1 formed a (1:1) complex with diethyl ether. 1,4-Dioxane was also enclathrated, but with a variable stoichiometric ratio. Single crystal X-ray crystallography was used to elucidate the crystal structure of the 1·diethyl ether complex. Crystals are orthorhombic with space group P2₁2₁2₁, a = 8.532(3), b = 15.040(4), c = 18.491(5) Å, V = 2373(1) ų, d_c = 1.256 g/cm³, and Z = 4. Host and guest molecules were found to associate via hydrogen bonds, with the guest molecules residing in undulating channels lined by host molecules.     

Modification of membrane heterogeneity by antipsychotic drugs: an X-ray diffraction comparative study

Lipid mixtures are used to mimic biological membranes as they allow characterization of lipid lateral domains defined by their specific lipid molecular organization. Therapeutic agents such as antipsychotic drugs (AP) that may interact with lipids arrangement are likely to modify membrane biological properties. The present study describes the effect of 2 typical and 5 atypical antipsychotic drugs on an aqueous co-dispersion of a lipid mixture made of egg phosphatidylcholine (PC)/brain sphingomyelin (SM)/cholesterol (1/1/1 mol/mol/mol). Lamellar liquid-ordered (Lo) and liquid-disordered (Ld) phase coexistence was identified in the control and antipsychotic-added mixtures at 37 degrees C using synchrotron small-angle X-ray scattering methods (XRD). Intensity of the Bragg peaks was used to generate electron density profiles (EDP) allowing bilayer thickness calculation. All antipsychotic except from amisulpride induced a Lo phase bilayer thickness (d(pp)) decrease. Chlorpromazine, haloperidol, amisulpride and 9-0H-risperidone induced a Ld d(pp) increase while ziprazidone, risperidone and clozapine induced a Ld d(pp) decrease, indicating that antipsychotic atypicality is not associated with a specific d(pp) modification on our lipid model mixture. Results are discussed in terms of competition of antipsychotic compounds with cholesterol and mode of reorganization of lateral domains. A pharmacological relevance of these changes is also discussed.     

A supercooled imidazolium iodide ionic liquid as a low-viscosity electrolyte for dye-sensitized solar cells

A series of allyl-functionalized imidazolium salts are reported, including 1-allyl-3-ethylimidazolium iodide and 1-allyl-3-propylimidazolium iodide, which have melting points close to room temperature and show typical properties of supercooled fluids if heated above their melting points. Their viscosities in the liquid state are considerably lower than the benchmark ionic liquid used in solar cells, viz., 1-propyl-3-methylimidazolium iodide. Electrolytes containing these new liquids provide excellent efficiencies and good stability in dye-sensitized solar cells when subjected to an accelerated-light soaking test at 60 degrees C. The structures of three of the new salts have been established in the solid state by single-crystal X-ray analysis.     

High molar extinction coefficient heteroleptic ruthenium complexes for thin film dye-sensitized solar cells

Two novel heteroleptic sensitizers, Ru((4,4-dicarboxylic acid-2,2'-bipyridine)(4,4'-bis(p-hexyloxystyryl)-2,2-bipyridine)(NCS)2 and Ru((4,4-dicarboxylic acid-2,2'-bipyridine)(4,4'-bis(p-methoxystyryl)-2,2'-bipyridine) (NCS)2, coded as K-19 and K-73, respectively, have been synthesized and characterized by 1H NMR, FTIR, UV-vis absorption, and emission spectroscopy and excited-state lifetime and spectroelectrochemical measurements. The introduction of the alkoxystyryl group extends the conjugation of the bipyridine donor ligand increasing markedly their molar extinction coefficient and solar light harvesting capacity. The dynamics of photoinduced charge separation following electronic excitation of the K-19 dye was scrutinized by time-resolved laser spectroscopy. The electron transfer from K-19 to the conduction band of TiO2 is completed within 20 fs while charge recombination has a half-life time of 800 s. The high extinction coefficients of these sensitizers enable realization of a new generation of a thin film dye sensitized solar cell (DSC) yielding high conversion efficiency at full sunlight even with viscous electrolytes based on ionic liquids or nonvolatile solvents. An unprecedented yield of over 9% was obtained under standard reporting conditions (simulated global air mass 1.5 sunlight at 1000 W/m2 intensity) when the K-73 sensitizer was combined with a nonvolatile "robust" electrolyte. The K-19 dye gave a conversion yield of 7.1% when used in conjunction with the binary ionic liquid electrolyte. These devices exhibit excellent stability under light soaking at 60 degrees C. The effect of the mesoscopic TiO2 film thickness on photovoltaic performance has been analyzed by electrochemical impedance spectroscopy (EIS).     

时间分辨全反射红外光谱对醋酸诱导丝蛋白构象转变的研究

采用时间分辨全反射红外光谱为主要分析手段, 对醋酸在丝蛋白膜中的扩散过程及其对丝蛋白构象转变机理进行了研究. 结果表明, 醋酸能够诱导丝蛋白构象转变为β-折叠. 醋酸的扩散速率和β-折叠构象的生成速率较为相似, 表明醋酸分子渗透到丝蛋白聚集体中是破坏丝蛋白原有氢键并诱导肽链重排, 进而实现构象转变的一个先决条件. 同时, 通过比较真空干燥处理前后丝蛋白膜的实验结果, 证实了丝蛋白中的水含量是影响醋酸的扩散速度以及丝蛋白多肽链重排速度的一个重要因素.