Allelopathic agents from Cyrtocymura cincta

The sesquiterpenoid fractions from the chloroform extracts of roots and aerial parts of the weed Cyrtocymura cincta (Griseb.) H. Robinson (Compositae) were tested to observe the effects on seed germination and growth of three dicot and four monocot species. Promotion and inhibition effects were observed according to the examined compound, specific seed or cultivar, and concentration.     

Delayed crossing in the \pi h_{9/2} 1/2-[541] band of 173 Lu

High-spin states in the odd-proton nucleus ¹⁷³Lu have been populated in a ¹⁷⁰Er(⁷Li,4n) reaction and the emitted -radiation was detected with the GASP array. The favoured and unfavoured sequences of the band have been considerably extended. The favoured sequence does not show any indication of a band crossing up to a rotational frequency of 0.45 MeV. This is the largest crossing frequency ever observed for 1/2^- [541] bands of odd-proton nuclei with and . Previous Cranked Shell Model (CSM) calculations underestimate the crossing frequency by 100 keV.Received: 19 May 2003, Published online: 11 November 2003PACS: 21.10.-k Properties of nuclei; nuclear energy levels - 21.10.Re Collective levels - 23.20.Lv transitions and level energies - 27.70. + q      

Persistence of well-defined collective excitations in a molten transition metal

Well-defined microscopic collective excitations are found in liquid Ni at 1763 K by means of inelastic neutron scattering. Such excitations are supported by the liquid despite an anharmonic character of its thermodynamic functions. Consideration of the detailed shape of the interionic pair potential provides a way to understand why atomic motions at microscopic scales behave in a way much closer to the alkali metals than to the liquefied rare gases.     

Study of N = 16 for Ne isotopes

²⁷Ne has been investigated through the one neutron transfer reaction ²⁶Ne(d,p)²⁷Ne in inverse kinematics at 9.7 MeV/nucleon. The results support the existence of a low lying negative parity state in ²⁷Ne which is a signature of a reduced sd-fp shell gap in the N = 16 neutron rich region, at variance with stable nuclei.     

(2 + 1)D exotic Newton-Hooke symmetry, duality and projective phase

A particle system with a (2 + 1)D exotic Newton-Hooke symmetry is constructed by the method of nonlinear realization. It has three essentially different phases depending on the values of the two central charges. The subcritical and supercritical phases (describing 2D isotropic ordinary and exotic oscillators) are separated by the critical phase (one-mode oscillator), and are related by a duality transformation. In the flat limit, the system transforms into a free Galilean exotic particle on the noncommutative plane. The wave equations carrying projective representations of the exotic Newton-Hooke symmetry are constructed.     

Research into conditions of quantitivity in the determination of carboniles in complex air matrices by adsorptive solid phase microextraction

This study focuses on certain aspects of the quantitivity of adsorptive solid phase microextraction when applied in the form of on-fibre derivatisation with O-(2,3,4,5,6)-pentafluorobenzyl-hydroxylamine hydrochloride (PFBHA) for the determination of carboniles in air samples of relevance in the atmosphere. The study was performed in the high-volume outdoor atmospheric simulation chambers (EUPHORE) located in Valencia (Spain). At short sampling times, the adsorption profiles obtained when only benzaldehyde was inserted in the chamber coincided with those obtained when other carbonylic compounds were also introduced at the same concentration, and this was also the case when the concentration of all the gaseous mixture components was increased considerably from one experiment to another. In a number of experiments applying different conditions, it was proven that all the extraction profiles belonged to the same regression when the fibre responses were plotted against the concentration-time product. A number of calibrations were obtained for benzaldehyde introduced in the chamber alone and in a mixture with three other carboniles at similar concentration values. A statistical test is applied to confirm that they all belonged to the same regression since they shared homogeneous variances. After these tests, the method of SPME on-fibre derivatisation for the determination of carboniles was considered to be safely applicable to quantification. Moreover, the concentration levels at which certain unwanted effects, i.e., displacement, saturation and competition, were observed are a few orders of magnitude higher than their occurrence levels in atmospheric processes.     

Theoretical prediction of the mass transfer coefficients in bubble columns operating in churn-turbulent flow regime. Study in Newtonian and non-Newtonian fluids under different operation conditions

 A comprehensive experimental study of the volumetric transfer coefficient k _L a with Newtonian and non-Newtonian fluids in bubble columns using CO₂ as gas phase is the objective of this work. The evaluation of the hydrodynamic characteristics of the bubble columns and delineated the different hydrodynamic regimes considering column geometry, gas flow, liquid height and type of fluid (Newtonian and non-Newtonian) suggest a general applicability of the proposed model. An explanation about of the k _L a values in non-Newtonian fluid is offered take into account shear rate, column geometry, viscosity and results reported in the literature previously. Received on 31 July 1999     

A tabu search algorithm for the periodic vehicle routing problem with multiple vehicle trips and accessibility restrictions

In this paper, we consider a periodic vehicle routing problem that includes, in addition to the classical constraints, the possibility of a vehicle doing more than one route per day, as long as the maximum daily operation time for the vehicle is not exceeded. In addition, some constraints relating to accessibility of the vehicles to the customers, in the sense that not every vehicle can visit every customer, must be observed. We refer to the problem we consider here as the site-dependent multi-trip periodic vehicle routing problem. An algorithm based on tabu search is presented for the problem and computational results presented on randomly generated test problems that are made publicly available. Our algorithm is also tested on a number of routing problems from the literature that constitute particular cases of the proposed problem. Specifically we consider the periodic vehicle routing problem; the site-dependent vehicle routing problem; the multi-trip vehicle routing problem; and the classical vehicle routing problem. Computational results for our tabu search algorithm on test problems taken from the literature for all of these problems are presented.     

Knowledge‐based choice of the initiator type for monomer removal by postpolymerization

The mechanisms involved in monomer removal by postpolymerization were investigated to establish a criterion to select the most effective initiator systems. Three redox systems yielding radicals of different hydrophobicities were studied. Efficiency in monomer removal by postpolymerization increased with the hydrophobicity of the radical formed from the initiator system. This result was independent of the water solubility of the residual monomer. The mechanistic reasons for this finding are discussed. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 40: 4245–4249, 2002