全文获取类型
收费全文 | 728篇 |
免费 | 33篇 |
国内免费 | 1篇 |
专业分类
化学 | 595篇 |
晶体学 | 13篇 |
力学 | 8篇 |
数学 | 56篇 |
物理学 | 90篇 |
出版年
2024年 | 1篇 |
2023年 | 10篇 |
2022年 | 16篇 |
2021年 | 33篇 |
2020年 | 19篇 |
2019年 | 16篇 |
2018年 | 15篇 |
2017年 | 12篇 |
2016年 | 22篇 |
2015年 | 17篇 |
2014年 | 22篇 |
2013年 | 48篇 |
2012年 | 29篇 |
2011年 | 61篇 |
2010年 | 32篇 |
2009年 | 28篇 |
2008年 | 42篇 |
2007年 | 41篇 |
2006年 | 38篇 |
2005年 | 31篇 |
2004年 | 43篇 |
2003年 | 37篇 |
2002年 | 35篇 |
2001年 | 8篇 |
2000年 | 5篇 |
1999年 | 1篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 9篇 |
1995年 | 8篇 |
1994年 | 3篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 7篇 |
1989年 | 2篇 |
1987年 | 3篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 4篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 2篇 |
1972年 | 2篇 |
排序方式: 共有762条查询结果,搜索用时 115 毫秒
31.
Mihir Upadhyaya Yudhishthir Kandel Gregory Denbeaux Cecilia Montgomery Yu‐Jen Fan 《X射线光谱测定》2014,43(2):102-107
X‐ray photoelectron spectroscopy (XPS) is used for elemental identification and quantification in a number of fields, and the optimization of XPS performance can help in making better use of the limited XPS tool availability. In the field of extreme ultraviolet (EUV) lithography, one of the requirements is having a clean vacuum environment to minimize contamination of the EUV optics. EUV resist outgassing is viewed as one of the main issues that could affect the vacuum environment. There is a program underway to measure the relative contamination rates from different resists following the ASML (provider of lithography systems) approved protocols for witness plate testing. One of the key steps is the XPS measurement of residue on the optics after cleaning. The role of XPS in quantification of species that adhere to the ruthenium‐coated silicon witness plate sample is discussed. The various XPS tool parameters like the pass energy and source setting were optimized for our application of witness plate analysis. The statistics of our XPS tool were studied, and combined with the fundamental XPS equations, a simple mathematical model was developed to optimize the number of scans for the various elements of interest in our witness plate study. Using the optimized number of scans, the acquisition time to measure the contaminant elements to a precision better than 0.1 at.% was minimized. The model devised in the paper can be adapted to other XPS measurements requiring different levels of precision. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
32.
Jean Guillon Jean-Michel Leger Cecilia Dapremont Lou Apollonia Denis Pascal Sonnet Stéphane Massip 《Supramolecular chemistry》2013,25(5):319-329
The synthesis of new 25,27-dialkyloxy-5,17-diarylcalix[4]arenes-crown-6 1a–f in 1,3-alternate conformation by Suzuki cross-coupling reaction is reported. Their conformation was determined using 1H, 13C, 2D NMR and ROESY analysis, and X-ray crystallography. Extraction experiments using a two-phase solvent method involving sodium, potassium or cesium picrate showed good extraction of the cesium cation. The X-ray crystal structures of 1,3-alternate 25,27-dipropoxy-5,17-diphenylcalix[4]arene-crown-6 ether 1a and its cesium picrate complex were established. Solid-state data were used to determine the complexation behavior of these new ligands. The efficiency of calixarenes 1a–f for cesium ion extraction could be ascribed to the rigidity and flatness linkages caused by the aryl groups at the lower rim of the aromatic moieties in the calixarene skeleton. In addition, the introduction of these aromatic moieties in positions 5 and 17 enhanced the solubility of the metal complexes in organic media. 相似文献
33.
Natalia Ríos Cecilia Chavarría Carmen Gil Williams Porcal 《Journal of heterocyclic chemistry》2013,50(3):720-726
An efficient and rapid microwave‐assisted solid‐phase method for the synthesis of 5‐methyl‐1,2‐disubstituted benzimidazoles derivatives has been developed. The phosphonium linker, obtained by reaction between polymer‐supported triphenylphosphine and 4‐fluoro‐3‐nitrobenzyl iodide, underwent aromatic substitution with primary amines, followed by one‐pot reaction with aldehydes in the presence of SnCl2·2H2O, yielded the benzimidazole system under microwave irradiation. The final products were released from the resin with NaOH under microwave irradiation and were obtained in high purity and good overall yield. 相似文献
34.
Mihaela Tertis Oana Hosu Bogdan Feier Andreea Cernat Anca Florea Cecilia Cristea 《Molecules (Basel, Switzerland)》2021,26(11)
Food safety and quality control pose serious issues to food industry and public health domains, in general, with direct effects on consumers. Any physical, chemical, or biological unexpected or unidentified food constituent may exhibit harmful effects on people and animals from mild to severe reactions. According to the World Health Organization (WHO), unsafe foodstuffs are especially dangerous for infants, young children, elderly, and chronic patients. It is imperative to continuously develop new technologies to detect foodborne pathogens and contaminants in order to aid the strengthening of healthcare and economic systems. In recent years, peptide-based sensors gained much attention in the field of food research as an alternative to immuno-, apta-, or DNA-based sensors. This review presents an overview of the electrochemical biosensors using peptides as molecular bio-recognition elements published mainly in the last decade, highlighting their possible application for rapid, non-destructive, and in situ analysis of food samples. Comparison with peptide-based optical and piezoelectrical sensors in terms of analytical performance is presented. Methods of foodstuffs pretreatment are also discussed. 相似文献
35.
Franciele Maria Pelissari Paulo José do Amaral Sobral Florencia Cecilia Menegalli 《Cellulose (London, England)》2014,21(1):417-432
Cellulose nanofibers were isolated from banana peel using a combination of chemical treatments, such as alkaline treatment, bleaching, and acid hydrolysis. The suspensions of chemically treated fibers were then passed through a high-pressure homogenizer 3, 5, and 7 times, to investigate the effect of the number of passages on the properties of the resulting cellulose nanofibers. The cellulose nanofibers isolated in this study had a dry basis yield of 5.1 %. Transmission electron microscopy showed that all treatments effectively isolated banana fibers in the nanometer scale. The micrographs of the process steps used to isolate the nanofibers revealed gradual removal of amorphous components. Increasing number of passages in the homogenizer shortened the cellulose nanofibers while furnishing more stable aqueous suspensions with zeta potential values ranging from ?16.1 to ?44.1 mV. All the samples presented aspect ratio in the range of long nanofibers, hence being potentially applicable as reinforcing agents in composites. X-ray diffraction studies revealed that homogenized nanofiber suspensions were more crystalline than non-homogenized suspensions. Fourier transform infrared spectroscopy confirmed that alkaline treatment and bleaching removed most of the hemicellulose and lignin components present in the banana fibers. Thermal analyses revealed that the developed nanofibers exhibit enhanced thermal properties. In general, the nanoparticles isolated from the banana peel have potential application as reinforcing elements in a variety of polymer composite systems. 相似文献
36.
Kepka C Rhodin J Lemmens R Tjerneld F Gustavsson PE 《Journal of chromatography. A》2004,1024(1-2):95-104
The primary purification of a 6.1 kilo base pair (kbp) plasmid from a desalted alkaline lysate has been accomplished by a thermoseparating aqueous two-phase system [(50% ethylene oxide-50% propylene oxide)-Dextran T 500]. The partitioning of the different nucleic acids (plasmid DNA, RNA, genomic DNA) in the thermoseparating aqueous two-phase system was followed both qualitatively by agarose gel electrophoresis and quantitatively by analytical chromatography (size exclusion- and anion-exchange mode) and PicoGreen fluorescence analysis. The experimental results showed a complete recovery of the plasmid DNA to the top phase, while 80% of total RNA and 58% of total protein was discarded to the bottom phase. Moreover, a 3.8-fold volume reduction of the plasmid DNA solution was achieved. By using a final thermoseparating step, the EO50PO50 polymer could be efficiently recycled, resulting in plasmid solution containing less than 1% polymer. The developed thermoseparating aqueous two-phase system shows great potential for the large-scale processing of plasmid DNA. 相似文献
37.
Cecilia Devi Wilfred 《合成通讯》2013,43(22):2859-2867
A tandem oxidation reaction has been utilized to prepare ethyl (E)‐4,5‐dioxo‐2‐hexadecenoate, the immediate precusor to the antiviral fungal metabolite podoscyphic acid. 相似文献
38.
Mauricio H. Cornejo Jan Elsen Cecilia Paredes Haci Baykara 《Journal of Thermal Analysis and Calorimetry》2014,115(1):309-321
Two Ecuadorian zeolite-rich tuffs, coded as Zeo1 (Mordenite) and Zeo2 (Clinoptilolite–Heulandite–Mordenite), were treated and used as supplementary cementitious materials (SCM) so as to study the effect of the thermal and mechanical treatments on pozzolanic reaction in mortars. The treatment was carried out by means of thermomechanical process according to a central composite-blocked cube-star experimental design. In this experimental design as independent factors the milling time (48, 60, 90, 120 and 132 min) and the heating temperatures (559, 600, 700, 800 and 841 °C) were used but keeping a constant heating time (5 h), and zeolite-rich tuffs as experimental blocks. The proportion of SCM was kept constant i.e. 15 %. On the other hand, the compressive strength, fixed lime, normalized water in hydrates and mg Ca(OH)2 per mg Cement at 7, 28 and 45 days, as well as hydration products related to dehydration degree of the zeolitic tuffs (DOD) were used as dependent factors. In addition, Quantitative and High-temperature chamber XRD, TG-DSC, particle size distribution and SEM-EDS were also carried out. The most significant factor was calcination leading to increase in the compressive strength compared to control, but just up to 800 °C because of recrystallization. As a conclusion, a meaningful loss of crystal structure of zeolites was not observed; but instead, the treatment could only lead to removing the water in cages and voids, thus improving the reaction with Ca(OH)2, producing more hydrates. In addition, lime was not only fixed by pozzolanic reaction, but also by carbonation. 相似文献
39.
Pierluigi?Contucci Cristian?Giardinà Claudio?GibertiEmail author Giorgio?Parisi Cecilia?Vernia 《Journal of statistical physics》2011,143(1):1-10
We numerically investigate the spin glass energy interface problem in three dimensions. We analyze the energy cost of changing
the overlap from −1 to +1 at one boundary of two coupled systems (in the other boundary the overlap is kept fixed to +1).
We implement a parallel tempering algorithm that simulates finite temperature systems and works with both cubic lattices and
parallelepiped with fixed aspect ratio. We find results consistent with a lower critical dimension D
c
=2.5. The results show a good agreement with the mean field theory predictions. 相似文献
40.