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Y. Z. Luo C. V. Nicholas D. Attwood J. H. Collett C. Price C. Booth 《Colloid and polymer science》1992,270(11):1094-1105
A triblock-copoly(oxybutylene/oxyethylene), denoted E58 B17 E58 (80 wt-% E), was prepared by sequential anionic copolymerisation and its micellar and gelation properties in aqueous solution were determined. The oxybutylene/oxyethylene copolymer had the advantage over comparable oxypropylene/oxyethylene copolymers of greater uniformity of composition and chain length. The methods generally used were surface tension, light scattering intensity, photon correlation spectroscopy, together with observation of gelation. Measurements were made at 30°, 40° and 55° C over a full concentration range from dilute solution into the gel (>200 g dm–3) and at specified concentrations, including the gel, over the temperature range from 10° to 70° C. The lower and upper temperature boundaries of the gel region were identified, and the occurrence of syneresis was noted. The properties investigated and discussed include critical micelle and gel concentrations, micellar weights and sizes, and structures and mobilities in the gel. 相似文献
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The spectral squeezing in resonance fluorescence from a two-level atom is calculated. It is shown that for resonance excitation optimum squeezing is obtained for near resonant frequencies of the fluorescent light. An operational definition of the spectrum of squeezing is given based on a discussion of possible experimental configurations. 相似文献
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Thermogravimetric measurements of weight loss accompanying the pyrolysis of four pitches have been made over a range of linear heating rates. For three of the samples, the data at each heating rate could be described by an integral and a differential method of analysis, assuming a simple order function for f(α), with the result that the apparent activation energy increased with heating rate. The data for all four samples could also be satisfactorily described by the Ozawa or Friedman multiple heating rate methods, and these resulted in apparent activation energies (Ea) which increased with the value of β at which they were determined. It is suggested that this tendency for the apparent activation energy to increase, as the temperature is raised, is due to a change in the relative importance of the different reactions which lead to weight loss in this system. The apparent kinetic parameters all fall on a common compensation plot which is used to explain the relative magnitude of Ea values from Ozawa and Doyle methods of analysis. The higher values of Ea from Friedman than from Ozawa analyses are also explained. 相似文献
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Dorian Sonet Mattéo Cayla Dr. Raphaël Méreau Estelle Morvan Aline Lacoudre Dr. Nicolas Vanthuyne Muriel Albalat Dr. Dario M. Bassani Dr. Antoine Scalabre Dr. Emilie Pouget Prof. Dr. Brigitte Bibal 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(72):e202202695
Chiral trifluoromethyl alcohol groups were introduced at the hindered ortho positions of 9,10-diphenylanthracenes to investigate their effects on the physical properties and reactivity towards oxidative dearomatization. In such compact structures, the position in different quadrants and the preferred orientation of the −CH(OH)CF3 groups were determined by the relative and absolute configurations of each stereoisomer, respectively. As a consequence, the stereochemistry governs the organization of the H-bonded molecules in single crystals (homochiral dimers vs ribbon), whereas in chlorinated solvents, they all behave as discrete compounds. Concerning their reactivity, the stereospecific dearomative oxidation of these molecules leads to 9,10-bis-spiro-isobenzofuran-anthracenes, when using organic single-electron transfer oxidants. The chiroptical properties of the alcohols and the corresponding dearomatized products were compared and showed an important modulation of the intensity. 相似文献
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Carlson EC Rathbone LK Yang H Collett ND Carter RG 《The Journal of organic chemistry》2008,73(13):5155-5158
An improved protocol for the construction of enantioenriched pyrrolidine, indoline, and piperidine rings using an organocatalyzed, intramolecular heteroatom Michael addition is described. Application to the enantioselective synthesis of homoproline, homopipecolic acid, and pelletierine has been accomplished. 相似文献
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K.S. Bond N.D. Collett E.P. Fuller J.L. Hardwick E.E. Hinds T.W. Keiber I.S.G. Kelly-Morgan C.M. Matthys M.J. Pilkenton K.W. Sinclair A.A. Taylor 《Applied physics. B, Lasers and optics》2008,90(2):255-262
Pressure broadening and shift coefficients for the ν1+ν3 band of 12C2H2 have been measured for He, Ne, and Ar at a temperature of 195 K using high resolution diode laser spectroscopy. The pressure
broadening and shifts follow patterns with rotational assignment that are similar to those at room temperature but are generally
larger in magnitude. The change in magnitude is qualitatively described by assuming, for each transition, a constant cross
section for pressure broadening or shifting. Better agreement may be obtained for pressure broadening coefficients by using
empirically determined temperature exponents; better agreement still is obtained from close coupling calculations of the pressure
broadening cross sections.
PACS 33.70.Jg 相似文献