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161.
162.
Measurement of emerging dechloranes in human serum using modulated gas chromatography coupled to electron capture negative ionization time‐of‐flight mass spectrometry
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Marie-Pierre Oury Rollande Dumont Catherine Jurie Jean-François Hocquette Brigitte Picard 《BMC biochemistry》2010,11(1):12
Background
An important variability of contractile and metabolic properties between muscles has been highlighted. In the literature, the majority of studies on beef sensorial quality concerns M. longissimus thoracis. M. rectus abdominis (RA) is easy to sample without huge carcass depreciation and may appear as an alternative to M. longissimus thoracis for fast and routine physicochemical analysis. It was considered interesting to assess the muscle fibres of M. rectus abdominis in comparison with M. longissimus thoracis (LT) and M. triceps brachii (TB) on the basis of metabolic and contractile properties, area and myosin heavy chain isoforms (MyHC) proportions. Immuno-histochemical, histochemical, histological and enzymological techniques were used. This research concerned two populations of Charolais cattle: RA was compared to TB in a population of 19 steers while RA was compared to LT in a population of 153 heifers. 相似文献165.
Thomas Pü ttmann Catherine Searle 《Proceedings of the American Mathematical Society》2002,130(1):163-166
We prove that the Euler characteristic of an even-dimensional compact manifold with positive (nonnegative) sectional curvature is positive (nonnegative) provided that the manifold admits an isometric action of a compact Lie group with principal isotropy group and cohomogeneity such that . Moreover, we prove that the Euler characteristic of a compact Riemannian manifold or with positive sectional curvature is positive if admits an effective isometric action of a torus , i.e., if the symmetry rank of is .
166.
Krief A Destree A Durisotti V Moreau N Smal C Colaux-Castillo C 《Chemical communications (Cambridge, England)》2002,(6):558-559
Driving the equilibrium between selenides and osmium(VIII) reagents with selenoxides and osmium(VI) by a subsequent reaction (rearrangement of allyl selenoxides to allyl alcohols or addition of osmium(VIII) species on C=C double bonds) to one side, allows the transformation of methyl geranyl selenides to linalool and of methyl citronellyl selenoxide to 6,7-dihydroxy citronellyl selenide. 相似文献
167.
Lormann ME Walker CH Es-Sayed M Bräse S 《Chemical communications (Cambridge, England)》2002,(12):1296-1297
Synthesis of novel fluoronitroaryl triazenes in liquid phase and on solid support have been described; mild displacement of the fluoride ion with various nucleophiles provides access to substituted arenes which in turn can be cleaved to provide a unique access to 1-alkyl-5-nitro-1H-benzotriazole. 相似文献
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[reaction: see text] Computer-aided design protocols to identify new chiral ligands for reactions proceeding through well-defined transition states are outlined. Ligand families are discovered via computational screening of large structural databases such as the Cambridge Structural Database. Using this method, a novel cis-decalin ligand has been identified as a chiral auxiliary for the allylboration of aldehydes. Synthesis, resolution, and evaluation revealed that this new auxiliary provided the aldehyde facial approach upon which the design was predicated. 相似文献
170.
Dearden MJ Firkin CR Hermet JP O'Brien P 《Journal of the American Chemical Society》2002,124(40):11870-11871
A "(+)-sparteine-like" chiral diamine, readily synthesized in three steps from (-)-cytisine, has been evaluated in four different asymmetric transformations; in each case, selectivity in an enantiocomplementary fashion to (-)-sparteine was observed. 相似文献