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71.
72.
Caterina Gattuso Philomène Gattuso Jolanda Mastroianni Valentina Roviello Luigi Campanella 《Natural product research》2019,33(7):1078-1084
AbstractTo achieve adequate restoration project, the moment of choice of the type of intervention is a very delicate phase that necessarily involves a thorough understanding of the asset in all its aspects, as the location, the history, the architecture, the state of preservation, the pathologies causing the degradation, the degradation in itself, the analysis of constituent materials. The set of all that can be investigated on a product (cultural), to obtaining important information for subsequent maintenance, conservation and/or restoration actions, is what is called a diagnostic plan. In this case it was applied directly on a monument of national importance: the Royal Villa in Naples (today the Municipal Villa). The analysis were performed in situ and in the laboratory (SEM-EDS) on samples taken directly at the Villa, which allowed the creation of a series of analytical cards, containing digital data, required for the selection of expense future of intervention. 相似文献
73.
Summary
In this paper, using the theory of henselian rings and in particular the notion of henselian and strict henselian couples, we study the behaviour of analytic branches of an affine algebraic variety at a point x, when x varies along a singular subvariety; moreover we construct an algebraic and canonical procedure, which parametrises the branches.
Lavoro eseguito nell'ambito della sez. 3 del G.N.S.A.G.A. del C.N.R. e con il supporto finanziario del Ministero della Pubblica Istruzione. 相似文献
Lavoro eseguito nell'ambito della sez. 3 del G.N.S.A.G.A. del C.N.R. e con il supporto finanziario del Ministero della Pubblica Istruzione. 相似文献
74.
Sandra Gemma Gagan Kukreja Pierangela Tripaldi Maria Altarelli Matteo Bernetti Silvia Franceschini Luisa Savini Giuseppe Campiani Caterina Fattorusso 《Tetrahedron letters》2008,49(13):2074-2077
Nickel(II) chloride/sodium borohydride combination was employed for the reduction of 4-hydrazinoquinoline derivatives to the corresponding anilines. This reductive protocol was efficiently applied for the reductive cleavage of monosubstituted hydrazines. We described herein the microwave-assisted synthesis of 4-hydrazinoquinolines, which furnished a high yielding and rapid two-step procedure for the synthesis, under mild conditions, of 4-aminoquinolines as antimalarial precursors. 相似文献
75.
Summary A general construction of rational finite elements of serendip type on convex quadrilaterals is described in this paper. A first technique consists in eliminating formerly introduced nodes; a second possibility is to use the transformation of Coxeter-Wachspress. Error bounds are given for the associate interpolation. 相似文献
76.
We consider two categories with one object, namely the set of all partial functions of one variable from the set of natural numbers into itself; the morphisms are the partial recursive operators in one case, and certain continuous partial mappings in the other case. We show that these categories are recursion categories and we characterize the domains and the complete domains. Some observations are made on a notion of reducibility obtained by using the total morphisms of these categories, and, subsequently, the general recursive operators. 相似文献
77.
We present two convergence theorems for Hamilton-Jacobi equations and we apply them to the convergence of approximations and perturbations of optimal control problems and of two-players zero-sum differential games. One of our results is, for instance, the following. LetT andT
h be the minimal time functions to reach the origin of two control systemsy = f(y, a) andy = f
h
(y, a), both locally controllable in the origin, and letK be any compact set of points controllable to the origin. If f
h –f Ch, then |T(x) – T
h
(x)| C
K
h
, for all x K, where is the exponent of Hölder continuity ofT(x). 相似文献
78.
The interaction energy between an incoming group X– and the substrate CRH2Y at the geometry of the transition state (TS) for bimolecular nucleophilic substitution reactions (with X, Y, and R equal to H and F) has been subjected to decomposition according to the Morokuma scheme. The influence of the basis set and of the geometry chosen for the TS is examined. The results bring out regular trends in the different terms of the decomposition along the whole set of reactions, but they are not sufficient to give a rationale of the energetic factors involved in these reactions. 相似文献
79.
Caterina Riccardi Shelby McCormick Rajeswari Kasi Challa Kumar 《Angewandte Chemie (International ed. in English)》2018,57(32):10158-10162
A potentially universal approach is presented for enzyme attachment to cellulose that significantly enhances enzyme stability while retaining high activity, and involves no chemical functionalization of cellulose. Bovine serum albumin (BSA) was interlocked in cellulose to form a protein‐friendly surface (named BSA‐Paper), while also providing COOH and NH2 groups for subsequent attachment of enzymes. The desired enzyme is then mixed with additional BSA and interlocked on BSA‐Paper. The second BSA layer dilutes and crosslinks the enzyme for improved stability. Laccase was tested as a model enzyme for interlocking on BSA‐Paper, and was found to retain over 100 % activity and was 240 times more stable at 25 °C (half life=180 d) than laccase. This new approach was also tested with a few other enzymes with encouraging results, thus providing a potentially universal method for stabilization of enzymes on cellulose with retention of high activities. 相似文献
80.
The protonation processes for eight three-membered ring molecules have been investigated using the SCF LCAO MO method with Gaussian basis sets and the results are compared with those obtained at the first order approximation, i.e. the electrostatic approximation. The electrostatic results are linearly connected with the SCF ones and are sufficient to get an ordering of the protonation energies in different chemical sites and to obtain reliable representations of the proton approaching paths. 相似文献