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701.
Antimony(V) is volatilized by reaction with potassium bromide in concentrated sulfuric acid media. After volatilization, the gases can be transported to an inductively coupled plasma spectrometer for atomic emission of antimony and its analytical determination. The influent factors, concentrated sulfuric acid volume, concentration and volume of the potassium bromide aqueous solution and carrier gas flow were investigated and optimized using different alternatives. A detection limit of 48 ng ml−1 of Sb was achieved under the optimized conditions with a precision of 7.6% and the calibration graph was linear from 0.10 to 10.0 μg ml−1 for a sample injection of 130 μl.The study of interferences from common cations and anions revealed a good tolerance for most ions, although there was a significant improvement in Sb(V) volatility when As(III) was present. Furthermore, the As(III) sensitization was only produced with Sb(V) species, while the volatility of the Sb(III) bromide species was unaltered.The method was applied to the determination of Sb in real river waters. The results were checked using alternative atomic spectroscopy methods. 相似文献
702.
Naohisa Yanagihara S. Eduardo del Castillo Tetsuya Ogura 《Transition Metal Chemistry》1987,12(1):12-14
Summary Volumetric measurements of ethylene and simple EDTA titration of copper(I) and copper(II) ions confirm that [CuL]+ and [CuL2]+ are formed when an aqueous solution of copper(II) is reduced by copper metal in the presence of ethylene, (L). The formation constants,K
1=[CuL+]2[Cu2+]–1[L]–2 andK
2=[CuL
2
+
]–1[L]–1, have been estimated. The formation of [CuL]+ is accompanied by an enthalpy change, H, of –25 kJ mol–1, and a positive entropy change, S, of 13 J mol–1 K–1. 相似文献
703.
A González-Pérez J. Czapkiewicz J. L. Del Castillo J. R. Rodríguez 《Colloid and polymer science》2004,282(12):1359-1364
The micellar properties of tetradecyltrimethylammonium nitrate (C14TANO3) in aqueous solutions in the temperature range of 10 to 35 °C and in aqueous solutions of benzyl alcohol (BzOH) at 25 °C were studied conductometrically. The specific conductivity data served for the evaluation of critical micelle concentration, cmc, and the degree of ionization of the micelles, , of the surfactant. From the temperature dependence of the cmc the thermodynamic parameters for micellization of C14TANO3 were calculated by applying Mullers modified equation. BzOH was found to affect strongly the cmc and values of the surfactant. The plot of the cmc/cmco ratio (where cmco is for pure water) as a function of BzOH molality, exhibits a characteristic break, which was attributed to the commencement of self-association of BzOH in aqueous solution at a molality of ca. 0.05. By applying the theoretical treatment suggested by Motomura for binary surfactant systems, the molar fraction of BzOH in the micelles at cmc, was estimated as a function of molality of the alcohol. C14TANO3 appears to be slightly more hydrophobic compared to the corresponding bromide. 相似文献
704.
García-Terán JP Castillo O Luque A García-Couceiro U Román P Lloret F 《Inorganic chemistry》2004,43(18):5761-5770
The reaction of nucleobases (adenine or purine) with a metallic salt in the presence of potassium oxalate in an aqueous solution yields one-dimensional complexes of formulas [M(mu-ox)(H(2)O)(pur)](n) (pur = purine, ox = oxalato ligand (2-); M = Cu(II) [1], Co(II) [2], and Zn(II) [3]), [Co(mu-ox)(H(2)O)(pur)(0.76)(ade)(0.24)](n)(4) and ([M(mu-ox)(H(2)O)(ade)].2(ade).(H(2)O))(n) (ade = adenine; M = Co(II) [5] and Zn(II) [6]). Their X-ray single-crystal structures, variable-temperature magnetic measurements, thermal behavior, and FT-IR spectroscopy are reported. The complexes 1-4 crystallize in the monoclinic space group P2(1)/a (No. 14) with similar crystallographic parameters. The compounds 5 and 6 are also isomorphous but crystallize in the triclinic space group P (No. 2). All compounds contain one-dimensional chains in which cis-[M(H(2)O)(L)](2+) units are bridged by bis-bidentate oxalato ligands with M(.)M intrachain distances in the range 5.23-5.57 A. In all cases, the metal atoms are six-coordinated by four oxalato oxygen atoms, one water molecule, and one nitrogen atom from a terminal nucleobase, building distorted octahedral MO(4)O(w)N surroundings. The purine ligand is bound to the metal atom through the most basic imidazole N9 atom in 1-4, whereas in 5 and 6 the minor groove site N3 of the adenine nucleobase is the donor atom. The crystal packing of compounds 5 and 6 shows the presence of uncoordinated adenine and water crystallization molecules. The cohesiveness of the supramolecular 3D structure of the compounds is achieved by means of an extensive network of noncovalent interactions (hydrogen bonds and pi-pi stacking interactions). Variable-temperature magnetic susceptibility measurements of the Cu(II) and Co(II) complexes in the range 2-300 K show the occurrence of antiferromagnetic intrachain interactions. 相似文献
705.
The influence of HCI concentration (6M, 8M, and 10M) and the ratio of sample protein to acid (1 or 5 mg of protein per mL of acid) on furosine formation during sample hydrolysis is studied. The conditions that maximize furosine formation are 10M HCI in the ratio of 1 mg of protein to 1 mL of acid. Purification of the hydrolysate by solid-phase extraction is also considered by examining the effect of hydrolysate volume and volume of 3M HCI used to elute the furosine. Furosine quantitation is carried out using the standard additions and external standard methods. The results indicate that there is no interference by the sample matrix and that external calibration is adequate. 相似文献
706.
A bond path linking two saturated fluorine atoms is found to be ubiquitous in crowded difluorinated aromatic compounds. The bond path is shown to persist for a range of internuclear distances (2.3-2.8 A) and a range of relative orientations of the two C-F internuclear axes. The F. . .F bonding is shown to exhibit all the hallmarks of a closed-shell weak interaction. The presence of such a bond path can impart as much as 14 kcal/mol of local stabilization to the molecule in which it exists, a stabilization that can be offset or even overwhelmed by destabilization of other regions in the molecule. Several other weak closed-shell interactions were also found and characterized including F. . .C, F. . .O, and C. . .C interactions, hydrogen bonding, dihydrogen bonding, and hydrogen-hydrogen bonding. This study represents another example of the usefulness and richness of the bond path concept and of the theory of atoms in molecules in general. 相似文献
707.
708.
Belz JE Potterveld DH Anthony P Arnold RG Arrington J Beck D Beise EJ Bosted PE Bulten H Chapman MS Coulter KP Dietrich F Ent R Epstein M Filippone BW Gao H Gearhart RA Geesaman DF Hansen J Holt RJ Jackson HE Jones CE Keppel CE Kinney ER Kuhn S Lee K Lorenzon W Lung A Makins NC Margaziotis DJ McKeown RD Meziani ZE Milner RG Mueller B Napolitano J Nelson J O'Neill TG Papavassiliou V Petratos GG Rock SE Segel RE Spengos M Szalata ZM Tao LH van Bibber K van den Brand JF White JL Zeidman B 《Physical review letters》1995,74(5):646-649
709.
, . , - . , , , . 相似文献
710.
Lee K Miller MA Smith A Hansen J Bloch C van den Brand JF Bulten HJ Ent R Goodman CD Jacobs WW Jones CE Korsch W Leuschner M Lorenzon W Marchlenski D Meyer HO Milner RG Neal JS Pancella PV Pate SF Pitts WK von Przewoski B Rinckel T Sowinski J Sperisen F Sugarbaker E Tschalär C Unal O Zhou ZL 《Physical review letters》1993,70(6):738-741