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Castelijns HJ Huinink HP Pel L Zitha PL 《The journal of physical chemistry. B》2007,111(43):12383-12388
The coupled mass transfer and chemical reactions of a gel-forming compound in a two-phase system were recently analyzed in detail [Castelijns et al. J. Appl. Phys. 2006, 100, 024916]. In this successive work, the gel-forming chemical tetramethylorthosilicate (TMOS) was dissolved in a mineral oil and placed together with heavy water (D2O) in small cylinders. The transfer of TMOS from the oleic phase to the aqueous phase was monitored through nuclear magnetic resonance (NMR) relaxation time measurements of hydrogen in the oleic phase. The rate of gelation was measured through NMR relaxation time measurements of deuterium in the aqueous phase. The temperature, the initial concentration of TMOS, and the type of buffer in the aqueous phase were varied in the experiments. The mass transfer is driven by the rate of hydrolysis, which increases with temperature. The hydrolysis rate is the lowest at a neutral pH and is the highest at a low pH. In the aqueous phase, a sharp decrease in the transverse relaxation time (T2) of 2H is observed, which is attributed to the gel reaction. The plateau in T2 indicates the gel transition point. The gel rates increase with increasing temperature and increasing concentration, and are the highest at a neutral pH. 相似文献
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HJ. Mellin 《Acta Mathematica》1887,9(1):137-166
Ohne Zusammenfassung 相似文献
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D. Elsner B. Bantes O. Bartholomy D. E. Bayadilov R. Beck Y. A. Beloglazov R. Castelijns V. Crede A. Ehmanns K. Essig R. Ewald I. Fabry F. Frommberger K. Fornet-Ponse M. Fuchs C. Funke A. B. Gridnev E. Gutz W. Hillert S. H?ffgen P. Hoffmeister I. Horn I. Jaegle J. Junkersfeld H. Kalinowsky Frank Klein Friedrich Klein E. Klempt M. Konrad M. Kotulla B. Krusche H. L?hner I. V. Lopatin J. Lotz S. Lugert D. Menze T. Mertens J. G. Messchendorp V. Metag C. Morales M. Nanova D. V. Novinski R. Novotny M. Ostrick L. M. Pant H. van Pee M. Pfeiffer A. V. Sarantsev C. Schmidt H. Schmieden B. Schoch S. Shende A. Süle V. V. Sumachev T. Szczepanek U. Thoma D. Trnka D. Walther C. Weinheimer C. Wendel 《The European Physical Journal A - Hadrons and Nuclei》2009,39(3):373-381
At the electron accelerator ELSA a linearly polarised tagged photon beam is produced by coherent bremsstrahlung off a diamond
crystal. Orientation and energy range of the linear polarisation can be deliberately chosen by accurate positioning of the
crystal with a goniometer. The degree of polarisation is determined by the form of the scattered electron spectrum. Good agreement
between experiment and expectations on the basis of the experimental conditions is obtained. Polarisation degrees of % are typically achieved at half of the primary electron energy. The determination of is confirmed by measuring the beam asymmetry, , in photoproduction and by a comparison of the results to independent measurements using laser backscattering. 相似文献
66.
The strange meson production on a proton target in theK
0Σ+ channel is sensitive to nucleon resonance contributions. TheK
0 production on a deuteron target can provide information on the hyperon-nucleon final-state interaction. The experiments γp →K
0Σ+ andγd →
K
0Σ+n have been carried out at the ELSA facility at Bonn. In this paper, we report the preliminary results of both experiments 相似文献
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Values for the specific rates of solvolysis of the benzhydryldimethylsulfonium ion in 34 solvents have been analyzed using various forms of the extended Grunwald-Winstein equation. The specific rates are insensitive toward changes in solvent nucleophilicity (N(T)) values, and they correlate best against a combination of Y(+) values (based on the solvolyses of the 1-adamantyldimethylsulfonium ion) and aromatic ring parameter (I) values. Common-molecule return is observed, being especially powerful in solvents rich in fluoro alcohol; the logarithm of the associated mass law constant correlates inversely with the solvent N(T) values. The product selectivities in ethanol-water mixtures are also consistent with an S(N)1 mechanism for the solvolyses. 相似文献
70.