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141.
S. Angelis A. C. Novak E. B. Sydney V. T. Soccol J. C. Carvalho A. Pandey M. D. Noseda J. L. Tholozan J. Lorquin C. R. Soccol 《Applied biochemistry and biotechnology》2012,167(5):1092-1106
In this study, the biomass and exopolysaccharides (EPS) production in co-cultures of microalgae/cyanobacteria and macromycetes was evaluated as a technology for producing new polysaccharides for medical and/or industrial application. Based on biomass and EPS productivity of monocultures, two algae and two fungi were selected and cultured in different co-culture arrangements. The hydrosoluble EPS fractions from mono- and co-cultures were characterized by 13C NMR spectroscopy and gas chromatography coupled to mass spectrometry and compared. It was found that co-cultures resulted in the production of an EPS different from those produced by monocultures, showing fungal predominance with microalgal/cyanobacterial traces. Co-cultures conditions were screened (temperature, agitation speed, fungal and microalgae inoculation rate, initial pH, illumination rate, and glucose concentration) in order to achieve maximum biomass and EPS production, resulting in an increase of 33 and 61% in exopolysaccharides and biomass productions, respectively (patent pending). 相似文献
142.
M. Coquery F. P. Carvalho S. Azemard M. Bachelez M. Horvat 《Analytical and bioanalytical chemistry》2000,366(8):792-801
A marine reference material, IAEA-140, prepared with a macroalgae (Fucus sp.) was recently produced by the International Atomic Energy Agency and certified for trace and major elements and for methylmercury (MeHg). Certification of this material was achieved as an outcome of an international analytical intercomparison study which resulted in 116 independent sets of results reported by participants from 54 countries. The statistical evaluation of the collected data and the criteria used for assignment of the mean and uncertainty values are described. The analysis of data allowed to certify concentration values for 24 elements and MeHg, and to provide information values for another 10 elements. Regarding the elements which could be given certified values, between two and eight different instrumental methods were used to measure metal concentrations, and four independent analytical procedures were used to measure MeHg concentrations. In order to assess the results of the certification procedure, a comparison was made between the certified values obtained from the world-wide intercomparison results and the values obtained from a small subgroup of well-qualified laboratories. The means and 95% confidence intervals for reference values obtained by the two methods are similar for most elements showing that the usual method of certification used by the IAEA, based on large groups of participants, is indeed pertinent. 相似文献
143.
Mónica S. EstevãoLuísa C. Carvalho Luísa M. FerreiraEduarda Fernandes M. Manuel B. Marques 《Tetrahedron letters》2011,52(1):101-106
The electrochemical behavior of an indole library of compounds, including several tryptophan and tryptamine derivatives previously demonstrated to be active against several reactive oxygen species (ROS), was investigated. For this purpose, a voltammetry study was undertaken and the oxidation potential was correlated to the scavenging activity reported for the studied indoles. All the compounds showed an oxidation potential peak lower than that observed for indole (Epox = 1.035 V), but higher than that described for the antioxidant melatonin (Epox = 0.715 V). The electrochemical behavior showed a high correlation with the scavenging activity of peroxyl radical, for selected compounds. 相似文献
144.
Sofia Pessanha Maria Luisa Carvalho Maria Becker Alex von Bohlen 《Spectrochimica Acta Part B: Atomic Spectroscopy》2010
The purpose of this study is to determine the elemental content, namely heavy metals, of samples of vine-leaves, grapes must and wine. In order to assess the influence of the vineyard age on the elemental content throughout the several stages of wine production, elemental determinations of trace elements were made on products obtained from two vineyards aged 6 and 14 years from Douro region. The elemental content of vine-leaves and grapes was determined by Energy Dispersive X-Ray Fluorescence (EDXRF), while analysis of the must and wine was performed by Total Reflection X-ray Fluorescence (TXRF). 相似文献
145.
M. Manso S. Pessanha F. Figueira S. Valadas A. Guilherme M. Afonso A. C. Rocha M. J. Oliveira I. Ribeiro M. L. Carvalho 《Analytical and bioanalytical chemistry》2009,395(7):2029-2036
The reddish-brown, brown or yellowish stains of circular or irregular shape known as foxing spots have been fully described
in conservation literature but still, this phenomenon does not find any scientific agreement since many hypotheses have been
raised concerning their origin. In this work a contribution to foxing definition not only focussed on its appearance but also
reported on its chemical information. For this purpose foxing stains present in drawings from two Portuguese artists dated
from the eighteenth to nineteenth centuries were observed under ultra-violet light and optical microscope and analysed by
three non-invasive spectroscopy techniques. The observations carried out on the stains provided information on their surface
morphology. The use of energy-dispersive X-ray fluorescence revealed a variation on the elemental content between foxing and
paper region. Although the results from X-ray diffraction analysis showed no signs of cellulose degradation in foxing stains,
Fourier-transformed infrared analysis revealed the presence of oxide groups. Both the information on the chemical nature and
surface morphology of the stains achieved in this study will contribute to increase foxing formation information and develop
future protocols for conservation purposes. 相似文献
146.
C. Carvalho 《Integral Equations and Operator Theory》1991,14(3):342-358
We study the relation between two methods for defining self-adjoint Schrodinger operators with point interactions, and prove several new results which extend and unify previous work on the subject. 相似文献
147.
Luís F. Guido Daniel O. Carvalho Jakub Taborsky Jana Skopalova Helena M. E. B. Saldanha Petr Bednar 《Chromatographia》2015,78(19-20):1233-1243
148.
Ana R. M. Carvalho Carla M. A. Pinto 《Mathematical Methods in the Applied Sciences》2017,40(4):1231-1264
We study the contributions of within‐host (virus‐to‐cell) and synaptic (cell‐to‐cell) transmissions in a mathematical model for human immunodeficiency virus epidemics. The model also includes drug resistance. We prove the local and global stability of the disease‐free equilibrium and the local stability of the endemic equilibrium. We analyse the effect of the cell‐to‐cell transmission rate on the value of the reproduction number, R0. Moreover, we show evidence of a qualitative change in the models' dynamics, subjected to the value of the drug efficacy. In the end, important inferences are drawn. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
149.
Thayana da C. Alves Mariele R. S. Gonçalves Francyne C. S. Correia Virgínia C. da Silva Paulo T. de Sousa Jr. Mário G. de Carvalho Raimundo Braz‐Filho Evandro L. Dall'Oglio 《Helvetica chimica acta》2014,97(11):1469-1474
From the hexane and MeOH extracts of Annona coriacea Mart . (Annonaceae) seeds, two novel acetogenins, coriapentocins A and B ( 1 and 2 , resp.) were isolated. The known acetogenin bullacin ( 3 ) was also isolated from the hexane extract. The structures of compounds 1 – 3 were elucidated by NMR and MS analysis, and relative configurations were established by comparison with literature data. 相似文献
150.
Bar adsorptive micro-extraction using three powdered activated carbons (ACs) as adsorbent phases followed by liquid desorption and high performance liquid chromatography with diode array detection (BAμE(ACs)-LD/HPLC-DAD), was developed to monitor triazinic herbicides (atrazine, simazine and terbutylazine) in environmental water matrices. ACs used present apparent surface areas around 1000 m2 g−1 with an important mesoporous volume and distinct surface chemistry characteristics (pHPZC ranging from 6.5 to 10.4). The textural and surface chemistry properties of the ACs adsorbent phases were correlated with the analytical data for a better understanding of the overall enrichment process. Assays performed on 10 mL water samples spiked at the 10.0 μg L−1 levels under optimized experimental conditions yielded recoveries around 100% for the three herbicides under study. The analytical performance showed good precision (RSD < 15.0%), convenient detection limits (≈0.1 μg L−1) and suitable linearity (1.0-12.0 μg L−1) with good correlation coefficients (r2 > 0.9914). By using the standard addition method, the application of the present method on real water matrices, such as surface water and wastewater, allowed very good performances at the trace level. The proposed methodology proved to be a suitable sorptive extraction alternative for the analysis of priority pollutants with polar characteristics, showing to be easy to implement, reliable, sensitive and requiring a low sample volume to monitor triazinic compounds in water matrices. 相似文献