Evidence for a contribution to the extrinsic photoconductive signal by hopping through excited states of the donors in silicon and CdTe

The intensities of the bound to bound transitions of the shallow donors in silicon and CdTe are found to be strongly electric field dependent when observed by photoconductivity techniques at low temperatures. Under these conditions significant differences can be detected between the photoconductive spectrum and the same transitions observed in absorption. The photoconductive peaks are shifted consistently to lower frequency compared with the absorption spectrum and additional peaks appear which are not significant features in absorption. These additional peaks are believed to result from the formation of molecular complexes of donors. The strong electric field dependence of the bound transitions observed in photoconductivity, the shift to lower frequency of the peaks and the enhancement of the additional lines can all be explained qualitatively on the assumption that the mechanism responsible for the generation of the photosignal involves hopping between the excited states of the molecular complexes     

Diffraction and resonance production in exclusive pp interactions at 100 GeV/c

We have investigated the reactions $\text{p}\text{p}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{a}\text{?}\text{and}\text{p}\text{p}\text{a}\text{?}\text{p}\text{p}\text{2π}{}^{\mathrm{+}}\text{2π}{}^{\mathrm{?}}\text{at}\text{100}\text{GeV}\text{/c}$. The $\text{p}\text{p}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}$ final state is dominated by diffractive production of a $\text{p}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{(}\text{or}\text{p}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{)}$ system which shows a strong tendency to form $\text{Δ}{}^{\mathrm{++}}\text{π}{}^{\mathrm{?}}\text{(}\text{or}\text{Δ}{}^{\mathrm{++}}\text{π}{}^{\mathrm{+}}\text{)}$. The process $\text{p}\text{p}\text{a}\text{?}\text{Δ}{}^{\mathrm{++}}\text{Δ}{}^{\mathrm{++}}$ is also observed in this reaction, indicating an energy dependence of s^?1.5±0.1. The $\text{p}\text{p}\text{2π}{}^{\mathrm{+}}\text{2π}{}^{\mathrm{?}}$ channel shows less single diffraction, and has a doubly diffractive component consistent with pomeron factorization. Strong Δ⁺⁺(Δ⁺⁺) production is agoain seen, but in contrast to the $\text{p}\text{p}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}$ channel we also observe considerable ?⁰ production.     

Measurement of the inclusive forward neutron spectrum produced in proton-copper interactions at 24 GeV/c

We present data on the inclusive neutron spectra produced in the forward direction by the interactions of 23.85 GeV/c protons in a copper target. The results are in good agreement with the predictions of the triple-Regge model.     

Reactions of π-allyl with atomic oxygen and hydroxyl on Ag(110)

The oxidation of the adsorbed π-allyl (η³-C₃H₅), prepared on atomic oxygen- and hydroxyl-covered Ag(110) by dissociation of allyl chloride (C₃H₅Cl), is investigated with temperature-programmed desorption and high-resolution electron energy loss spectroscopy. Allyl chloride adsorbs molecularly on oxygen-covered Ag(110) at 110 K. Upon heating to 180 K, some allyl chloride dissociates to form π-allyl and atomic chlorine, and the remainder desorbs molecularly. The π-allyl undergoes combustion to form hydroxyl or carbonate until all of the free oxygen is consumed by 200 K. Migratory insertion of hydroxyl into excess π-allyl commences near 220 and finishes by 250 K, forming adsorbed allyl alcohol (C₃H₅OH), which reacts either with excess hydroxyl near 240 K to form allyl alkoxy (η¹(O)-C₃H₅O) and water, or with π-allyl at 250 K to form allyl alkoxy and propylene (C₃H₆). Th allyl alkoxy evolves acrolein (C₃H₄O) by β-hydrogen elimination near 285 K, and propylene is evolved concurrently as the hydrogen released by this reaction rapidly scavenges π-allyl. Finally, the remaining π-allyl dimerizes to form 1,5-hexadiene (C₆H₁₀), which desorbs at 315 K. The gross observations of reaction pathways and temperatures are used to evaluate important aspects of the thermochemistry of these reactions.     

A new upper limit for the branching ratio (Ξ− → nπ−)(Ξ− → Λπ−)

From a sample of 735 000 Ξ^? decays, we have obtained a new upper limit for the branching ratio $\text{(Ξ}{}^{\mathrm{?}}\text{→}\text{n}\text{π}{}^{\mathrm{?}}\text{)}\text{(Ξ}{}^{\mathrm{?}}\text{→ Λπ}{}^{\mathrm{?}}\text{)}$. The result is 1.9 × 10^?5 at the 90% confidence level.     

Elastic and inelastic scattering of 16O and 12C by 24Mg near the Coulomb barrier

Angular distributions for ¹⁶O + ²⁴Mg and ¹²C + ²⁴Mg elastic and inelastic (2⁺, 1.37 MeV state in ²⁴Mg) scattering have been measured at energies spanning the Coulomb barrier. Apart from the structure typical of strong destructive Coulomb-nuclear interference, the data exhibit some additional specific features. Coupled channel calculations were performed, along with DWBA calculations to analyse the data using fixed coupling strengths deduced from the results of Coulomb excitation work. The importance of higher-order effects such as reorientation, is demonstrated.     

Eicosatetraenehydroxamates: inhibitors of 5-lipoxygenase

The syntheses of 5-hydroxamyl and 5-hydroxamylmethyl-6,8,11,14,-eicosatetraenoic acids ($\text{3}$ and $\text{4}$), which possess potent 5-lipoxygenase inhibitory activity, are described.     

Kinetics of the reactions of O3 and OH radicals with a series of dialkenes and trialkenes at 294 ± 2 K

Rate constants for the gas phase reactions of O₃ and OH radicals with 1,3-cycloheptadiene, 1,3,5-cycloheptatriene, and cis- and trans-1,3,5-hexatriene and also of O₃ with cis-2,trans-4-hexadiene and trans -2,trans -4-hexadiene have been determined at 294 ± 2 K. The rate constants determined for reaction with O₃ were (in cm³ molecule^-1s^?1 units): 1,3-cycloheptadiene, (1.56 ± 0.21) × 10^-16; 1,3,5-cycloheptatriene, (5.39 ± 0.78) × 10^?17; 1,3,5-hexatriene, (2.62 ± 0.34) × 10^?17; cis?2,trans-4-hexadiene, (3.14 ± 0.34) × 10^?16; and trans ?2, trans -4-hexadiene, (3.74 ± 0.61) × 10^?16; with the cis- and trans-1,3,5-hexatriene isomers reacting with essentially identical rate constants. The rate constants determined for reaction with OH radicals were (in cm³ molecule^?1 s^?1 units): 1,3-cycloheptadiene, (1.31 ± 0.04) × 10^?10; 1,3,5-cycloheptatriene, (9.12 × 0.23) × 10^?11; cis-1,3,5-hexatriene, (1.04 ± 0.07) × 10^?10; and trans 1,3,5-hexatriene, (1.04 ± 0.17) × 10^?10. These data, which are the first reported values for these di- and tri-alkenes, are discussed in the context of previously determined O₃ and OH radical rate constants for alkenes and cycloalkenes.     

Potential energy surface intersections for triatomic molecules

The different types of surface intersection which may occur in linear configurations of triatomic molecules are reviewed, particularly with regard to the way in which the degeneracy is split as the molecule bends. The Renner-Teller effect in states of symmetry Π, Δ, Φ, etc., and intersections between Σ and Π, Σ and Δ, and Π and Δ states are discussed. A general method of modelling such intersecting potential surfaces is proposed, as a development of the model previously used by Murrell and Carter and co-workers for single-valued surfaces. Some of the lower energy surfaces of H₂O, NH₂, O₃, C₃, and HNO are discussed as examples.