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991.
992.
We investigated the formation of Pt nanocubes (NCs) and their electrocatalytic oxygen reduction reaction (ORR) properties and structural stability using two different capping agents, namely, polyvinylpyrrolidone (PVP) and oleylamine (OAm). The mono-dispersity of the obtained Pt NCs and their interactions with PVP and OAm were analyzed by transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), Fourier-transformed infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA). The TEM data show a high mono-dispersity (82 %) and a large mean particle size (9-10 nm) for the Pt NCs obtained by the oleylamine-assisted method compared to those prepared via the PVP-assisted procedure (68 %, 6–7 nm). FTIR, XPS, and TGA data show that PVP and OAm still remain at the Pt surface, despite washing. Interestingly, the OAm-capped Pt NCs show significantly higher electrochemically active surface area (ECSA) and ORR activity than the PVP-capped ones. An accelerated stress protocol, however, reveals that the OAm-capped NCs possess a poor structural stability during electrochemical cycling. The loss of a defined surface arrangement in the NCs is connected with a transformation into a near-spherical particle shape. In contrast, the PVP-capped NCs mainly retain their particle shape due to their strong capping behavior. In addition, we have developed a degradation model for NCs as a function of electrochemical parameters such as upper potential and cycle number. Altogether, we provide fundamental insights into the electronic interactions between capping agent and Pt NCs and the role of the adsorption strength of the capping agent in improving the electrochemical ORR performance as well as the structural stability of shape-controlled nanoparticles. 相似文献
993.
994.
Xingchao Dai Sven Adomeit Jabor Rabeah Carsten Kreyenschulte Angelika Brückner Hongli Wang Feng Shi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(16):5305-5309
Glycolic acid (GA), as important building block of biodegradable polymers, has been synthesized for the first time in excellent yields at room temperature by selective oxidation of 1,3‐dihyroxyacetone (DHA) using a cheap supported Cu/Al2O3 catalyst with single active CuII species. By combining EPR spin‐trapping and operando ATR‐IR experiments, different mechanisms for the co‐synthesis of GA, formates, and formamides have been derived, in which .OH radicals formed from H2O2 by a Fenton‐like reaction play a key role. 相似文献
995.
In the field of direct homogenization methods large representative volume elements (RVE's) cause a high computational cost, which is indicated by a large number of history variables allocating a large amount of memory. Additionally, a high computation time is necessary to solve the systems of equations on the micro-scale as well as on the macro-scale. In this contribution we focus on random microstructures consisting of a continuous matrix phase with a high number of embedded inclusions with arbitrary morphology. We present a method for the construction of statistically similar representative volume elements (SSRVE's) which are characterized by a much less complexity than usual RVE's in order to obtain an efficient simulation tool. The basic goal of the underlying procedure is to find a SSRVE, where some selected statistical measures describing the inclusion morphology are as close as possible to the ones of the original arbitrary microstructure. (© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
996.
Maximilian Jux Benedikt Finke Thorsten Mahrholz Michael Sinapius Arno Kwade Carsten Schilde 《Journal of nanoparticle research》2017,19(4):139
Several epoxy Al(OH)O (boehmite) dispersions in an epoxy resin are produced in a kneader to study the mechanistic correlation between the nanoparticle size and mechanical properties of the prepared nanocomposites. The agglomerate size is set by a targeted variation in solid content and temperature during dispersion, resulting in a different level of stress intensity and thus a different final agglomerate size during the process. The suspension viscosity was used for the estimation of stress energy in laminar shear flow. Agglomerate size measurements are executed via dynamic light scattering to ensure the quality of the produced dispersions. Furthermore, various nanocomposite samples are prepared for three-point bending, tension, and fracture toughness tests. The screening of the size effect is executed with at least seven samples per agglomerate size and test method. The variation of solid content is found to be a reliable method to adjust the agglomerate size between 138–354 nm during dispersion. The size effect on the Young’s modulus and the critical stress intensity is only marginal. Nevertheless, there is a statistically relevant trend showing a linear increase with a decrease in agglomerate size. In contrast, the size effect is more dominant to the sample’s strain and stress at failure. Unlike microscaled agglomerates or particles, which lead to embrittlement of the composite material, nanoscaled agglomerates or particles cause the composite elongation to be nearly of the same level as the base material. The observed effect is valid for agglomerate sizes between 138–354 nm and a particle mass fraction of 10 wt%. 相似文献
997.
Solutions to non–convex variational problems typically exhibit enforced finer and finer oscillations called microstructures such that the infimal energy is not attained. Those oscillations are physically meaningful, but finite element approximations typically experience dramatic difficulty in their reproduction. The relaxation of the non–convex minimisation problem by (semi–)convexification leads to a macroscopic model for the effective energy. The resulting discrete macroscopic problem is degenerate in the sense that it is convex but not strictly convex. This paper discusses a modified discretisation by adding a stabilisation term to the discrete energy. It will be announced that, for a wide class of problems, this stabilisation technique leads to strong H1–convergence of the macroscipic variables even on unstructured triangulations. This is in contrast to the work [2] for quasi–uniform triangulations and enables the use of adaptive algorithms for the stabilised formulations. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
998.
Non-smooth friction systems such as systems with dry friction show several bifurcation phenomena. The discontinuity of these so called slip-stick vibrations makes these systems interesting and there has been a lot of research in this field, see for example Hinrichs [1]. Due to the non-smooth friction force even the deterministic system shows a rich bifurcation behavior. Measurements indicate that the friction coefficient which plays a large role in the system behavior is not deterministic but can be described as a friction characteristic with added white noise. Therefore, the stochastic characteristic is introduced into the non-smooth system and the change of the bifurcation behavior is studied. (© 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
999.
We realize an absolute position control of drifting dissipative optical solitons by injecting an incoherent amplitude parameter gradient onto the nonlinear optical system. This allows for two-dimensional, arbitrary control patterns. The control of the soliton drift velocity is studied applying a periodic, hexagonally shaped modulation. The guiding of dissipative solitons by one- and two-dimensional parameter modulations is demonstrated. Furthermore, one-dimensional, line-shaped parameter modulations are designed to act as barriers for dissipative solitons, allowing implementations of position selectors for solitons. The interaction of dissipative optical solitons with barriers is studied for different barrier parameters. 相似文献
1000.
High-order harmonic generation from atomic systems is considered in the crossed fields of a relativistically strong infrared laser and a weak attosecond pulse train of soft x rays. Due to one-photon ionization by the x-ray pulse, the ionized electron obtains a starting momentum that compensates the relativistic drift, which is induced by the laser magnetic field, and allows the electron to efficiently emit harmonic radiation upon recombination with the atomic core in the relativistic regime. This way, short pulses of coherent hard x rays of up to 40 keV energy can be generated. 相似文献