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61.
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Amalia Rodríguez Carmen Carmona Ernestina Muñoz Francisco Sánchez John Burgess 《Transition Metal Chemistry》1991,16(5):535-541
Summary Different approaches to the interpretation of solvent effects on reactions between ionic reactants are analysed, taking as a basis the kinetic data corresponding to the sulphite-hexacyanoferrate(III) and peroxodisulphate-hexacyanoferrate(III) oxidations. It is concluded that the approach based on the use of solvent parameters is the more promising, although knowledge of the transfer chemical potentials of the reactants may also be useful in the interpretation of kinetic behaviour. 相似文献
64.
Paneque M Sirol S Trujillo M Gutiérrez-Puebla E Monge MA Carmona E 《Angewandte Chemie (International ed. in English)》2000,39(1):218-221
Isolated hydrotris(pyrazolyl)borate anions Tp' were obtained as salts of metal complex cations (see picture) by the displacement of Rh-coordinated kappa(3)-N,N',N"-Tp' by PMe(3) (Tp'=Tp and Tp(Me2)). With [(kappa(3)-Tp(Me2))Rh(C(2)H(4))(2)], stepwise diplacement of the Tp(Me2) ligand allowed the isolation of complexes exhibiting the kappa(2)- Tp(Me2) and kappa(1)-Tp(Me2) coordination modes. 相似文献
65.
Carmona D Sáez J Granados H Pérez E Blair S Angulo A Figadere B 《Natural product research》2003,17(4):275-280
Dichloromethane extracts of both the roots and the leaves of Raimondia cf. monoica showed in vitro antiplasmodial and leishmanicidal activities against Plasmodium falciparum and Leishmania panamensis, respectively. Three 6-substituted 5,6-dihydro-2H-pyran-2-ones were isolated. (1) and (2) were identified as (6S)-(5'-oxohepten-1'E,3'E-dienyl)-5,6-dihydro-2H-pyran-2-one (1) and (6R)-(5'-oxohepten-1'Z,3'E-dienyl)-5,6-dihydro-2H-pyran-2-one (2), respectively. (-)-Arentilactone (3) was also isolated. The structure of the new compound (1) was determined by spectroscopic methods; additional spectroscopic data for (2) are reported for the first time. 相似文献
66.
Cámpora J Maya CM Palma P Carmona E Gutiérrez-Puebla E Ruiz C 《Journal of the American Chemical Society》2003,125(6):1482-1483
The often facile C-/O-tautomerization of transition metal enolates is severely hindered in the cyclic Ni complexes 1 and 2, allowing the study of their individual reactivities. At room temperature only the O-bound tautomer, 2, reacts with aldehydes, giving rise to the corresponding addition products. 相似文献
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68.
Zhou Qingzhi Shubayr Nasser Carmona Marco Standen Timothy M. Kearfott Kimberlee J. 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(2):673-680
Journal of Radioanalytical and Nuclear Chemistry - Flow-through radon sources were widely utilized in the calibration of radon equipment and radon studies. In this paper a broken 266Ra source which... 相似文献
69.
F. J. Arroyo F. J. Carmona I. García De La Fuente J. A. González J. C. Cobos 《Journal of solution chemistry》2000,29(8):743-756
Excess molar volumes V
E
m at 25°C and atmospheric pressure over the entirecomposition range for binary mixtures of 1-heptanol with 2,5-dioxahexane, 2,5,8-trioxanonane,5,8,11-trioxapentadecane, 2,5,8,11-tetraoxadodecane,or 2,5,8,11,14-pentaoxapentadecane, and mixtures of 1-nonanol with 2,5-dioxahexane,3,6-dioxaoctane, 2,5,8-trioxanonane, 3,6,9-trioxaundecane, 5,8,11-trioxapentadecane,2,5,8,11-tetraoxadodecane, or 2,5,8,11,14-pentaoxapentadecane are reportedfrom densities measured with a vibrating-tube densimeter.V
E
m curves are nearlysymmetrical at about 0.5 mole fraction. Excess molar volumes are usually positive,indicating predominance of positive contributions to V
E
m from the disruption ofH bonds of alcohols and from physical interactions. When chain lengths ofboth components of the mixture are increased, the contribution from interstitialaccommodation appears to be sufficiently negative, such that V
E
m becomes negative(e.g., l-nonanol + 5,8,11-tetraoxapentadecane). 相似文献
70.
Dr. Jesús Campos Dr. Joaquín López‐Serrano Dr. Riccardo Peloso Prof. Ernesto Carmona 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(19):6432-6457
Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, that is, based essentially on carbon, with molecular inorganic chemistry, especially with coordination compounds. Transition‐metal methyl complexes probably represent the simplest and most fundamental way to view how these two major areas of chemistry combine and merge into novel species with intriguing features in terms of reactivity, structure, and bonding. Citing more than 500 bibliographic references, this review aims to offer a concise view of recent advances in the field of transition‐metal complexes containing M?CH3 fragments. Taking into account the impressive amount of data that are continuously provided by organometallic chemists in this area, this review is mainly focused on results of the last five years. After a panoramic overview on M?CH3 compounds of Groups 3 to 11, which includes the most recent landmark findings in this area, two further sections are dedicated to methyl‐bridged complexes and reactivity. 相似文献