On a dual submanifold homomorphism

In this paper we develop a technique to study the homomorphisma: MU _* (B U₁)→M U_*?2 (B U₁) defined by assigning to the class off: M→B U ₁ the class off _oi: N→B U₁, wherei: N→M is the submanifold dual tof*(γ₁)?f*(γ₁), and γ₁→B U is the 3 universal line boundle. So that we can present a (σ_n), where σ_nis the class of the classifying map of the canonical line boundle overC P ⁿ, in terms of the σ_i’s and chosen generators of Π_★(M U).     

High-throughput experimentation in synthetic polymer chemistry: From RAFT and anionic polymerizations to process development

The application of combinatorial and high-throughput approaches in polymer research is described. An overview of the utilized synthesis robots is given, including different parallel synthesizers and a process development robot. In addition, the application of the parallel synthesis robots to reversible addition fragmentation termination (RAFT) radical polymerizations and ionic copolymerizations is overviewed. Moreover, first results concerning the process development of semi-batch free radical polymerizations are described.     

Photoluminescence asymmetry with quantum state preparation

We show that the number of photons in a strongly coupled exciton–photon system is asymmetric with the detuning of the modes when, in the spontaneous emission regime, the two modes are entangled. As changing the detuning is easy in semiconductor microcavities–where on the other hand the nature of the strong-coupling in terms of single-particle effects is not yet resolved–we propose this effect as a test of the quantum character of microcavity polaritons.     

Scattering Below Critical Energy for the Radial 4D Yang-Mills Equation and for the 2D Corotational Wave Map System

Given g and f  =  gg′, we consider solutions to the following non linear wave equation :

On-Surface Synthesis and Characterization of Acene-Based Nanoribbons Incorporating Four-Membered Rings

A bottom up method for the synthesis of unique tetracene-based nanoribbons, which incorporate cyclobutadiene moieties as linkers between the acene segments, is reported. These structures were achieved through the formal [2+2] cycloaddition reaction of ortho-functionalized tetracene precursor monomers. The formation mechanism and the electronic and magnetic properties of these nanoribbons were comprehensively studied by means of a multitechnique approach. Ultra-high vacuum scanning tunneling microscopy showed the occurrence of metal-coordinated nanostructures at room temperature and their evolution into nanoribbons through formal [2+2] cycloaddition at 475 K. Frequency-shift non-contact atomic force microscopy images clearly proved the presence of bridging cyclobutadiene moieties upon covalent coupling of activated tetracene molecules. Insight into the electronic and vibrational properties of the so-formed ribbons was obtained by scanning tunneling microscopy, Raman spectroscopy, and theoretical calculations. Magnetic properties were addressed from a computational point of view, allowing us to propose promising candidates to magnetic acene-based ribbons incorporating four-membered rings. The reported findings will increase the understanding and availability of new graphene-based nanoribbons with high potential in future spintronics.     

Reflectance and ultraviolet spectroscopy: predicting the relative growth of Saccharomyces cerevisiae in pine biomass

Ultrasound treatment favors enzymatic attack on vegetal materials and influences biological activity. The objective of this study was to develop substrates for Saccharomyces cerevisiae based on the hydrothermal treatment and ultrasound treatment of pine needle biomass. The samples subjected to ultrasound treatment at 550?°C and 650?°C showed higher reflectance bands at around 200?nm after 80?min of ultrasound treatment and lower band gap energies associated with lower IC₃₀ values. The hydrothermal treatment with 100?min of ultrasound treatment generated more promising materials for the use of the substrates with the eukaryotic model S. cerevisiae.     

Two-Photon Absorption Enhancement by the Inclusion of a Tropone Ring in Distorted Nanographene Ribbons

A new family of distorted ribbon-shaped nanographenes was designed, synthesized, and their optical and electrochemical properties were evaluated, pointing out an unprecedented correlation between their structural characteristics and the two-photon absorption (TPA) responses and electrochemical band gaps. Three nanographene ribbons have been prepared: a seven-membered-ring-containing nanographene presenting a tropone moiety at the edge, its full-carbon analogue, and a purely hexagonal one. We have found that the TPA cross-sections and the electrochemical band gaps of the seven-membered-ring-containing compounds are higher and lower, respectively, than those of the fully hexagonal polycyclic aromatic hydrocarbon (PAH). Interestingly, the inclusion of additional curvature has a positive effect in terms of non-linear optical properties of those ribbons.     

Enthalpic characterization of activated carbons with different surface chemistry with organic solvents and water

Journal of Thermal Analysis and Calorimetry - Immersion enthalpies of activated carbons modified on their chemical surface were determined in benzene, cyclohexane, hexane, ethanol and water. Three...     

Differential evolution with enhanced diversity maintenance

Optimization Letters - Differential evolution (de) is a popular population-based meta-heuristic that has been successfully used in complex optimization problems. Premature convergence is one of the...