全文获取类型
收费全文 | 388篇 |
免费 | 17篇 |
国内免费 | 5篇 |
专业分类
化学 | 258篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 115篇 |
物理学 | 31篇 |
出版年
2023年 | 2篇 |
2021年 | 5篇 |
2020年 | 9篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2017年 | 5篇 |
2016年 | 5篇 |
2015年 | 14篇 |
2014年 | 15篇 |
2013年 | 20篇 |
2012年 | 31篇 |
2011年 | 35篇 |
2010年 | 13篇 |
2009年 | 23篇 |
2008年 | 29篇 |
2007年 | 35篇 |
2006年 | 14篇 |
2005年 | 14篇 |
2004年 | 12篇 |
2003年 | 22篇 |
2002年 | 14篇 |
2001年 | 9篇 |
2000年 | 4篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 6篇 |
1995年 | 4篇 |
1993年 | 3篇 |
1991年 | 3篇 |
1989年 | 3篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1967年 | 1篇 |
1963年 | 1篇 |
1921年 | 1篇 |
1918年 | 1篇 |
1915年 | 2篇 |
1913年 | 1篇 |
1912年 | 1篇 |
1909年 | 1篇 |
1906年 | 1篇 |
1903年 | 1篇 |
1889年 | 3篇 |
1885年 | 3篇 |
1883年 | 2篇 |
1877年 | 2篇 |
1870年 | 1篇 |
排序方式: 共有410条查询结果,搜索用时 31 毫秒
141.
Zuidema E Sarmentero MA Bo C Ballester P 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(24):7285-7295
We describe herein a detailed study of the inclusion processes of several positively charged organometallic sandwich complexes inside the aromatic cavity of the self-folding octaamide cavitand 1. In all cases, the binding process produces aggregates with a simple 1:1 stoichiometry. The resulting inclusion complexes are not only thermodynamically stable, but also kinetically stable on the (1)H NMR spectroscopy timescale. The binding constants for the inclusion complexes were determined by different titration techniques. We have also investigated the kinetics of the binding process and the motion of the metallocenes included in the aromatic cavity of the host. Using DFT-based calculations, we have evaluated the energies of a diverse range of potential binding geometries for the complexes. We then computed the proton chemical shifts of the included guest in each one of the binding geometries. The agreement between the averaged computed values and the experimentally determined chemical shifts clearly supports the proposed binding geometries that we assigned to the inclusion complexes formed in solution. The combination of experimental and theoretical results has allowed us to elucidate the origins of the distinct features detected in the complexation process of the different guests, as well as their different motions inside the host. 相似文献
142.
Curutchet C Mennucci B Scholes GD Beljonne D 《The journal of physical chemistry. B》2008,112(12):3759-3766
The use of the F?rster model to predict the dynamics of resonant electronic energy transfer (RET) in a model donor-acceptor dyad (a terphenyl-bridged perylene diimide (PDI)-terrylene diimide (TDI) dyad molecule) embedded at low temperature in a PMMA matrix is tested against experiment. The relevant ingredients involved in the F?rster rate for RET, namely electronic coupling, spectral overlap, and screening effects, are accounted for in a quantitative manner. Electronic couplings are obtained from time-dependent density functional theory calculations, and the effect of the PMMA environment is included both on the transition densities and on their interaction through the IEFPCM model. We find that the presence of the terphenyl bridge induces a slight delocalization of the PDI and TDI transition densities over the bridge originating in a 56% increase in the coupling and in the breakdown of the dipole-dipole approximation. The spectral overlap is determined on the basis of a detailed simulation of the homogeneously broadened donor emission and acceptor absorption line shapes determined by fitting the single molecule spectra measured at 1.2 K. The corresponding distribution of spectral overlap throughout the ensemble is then estimated by assuming an uncorrelated inhomogeneous line broadening for the donor and acceptor. Combining the calculated electronic couplings and spectral overlaps sampled from Monte Carlo realizations of the energetic disorder, we obtain a mean RET time (approximately 8 ps) and a distribution in reasonable agreement with experiment. 相似文献
143.
144.
Polynuclear Gold [AuI]4, [AuI]8, and Bimetallic [AuI4AgI] Complexes: C−H Functionalization of Carbonyl Compounds and Homogeneous Carbonylation of Amines
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Ekaterina S. Smirnova Dr. José M. Muñoz Molina Alice Johnson Dr. Nuno A. G. Bandeira Prof. Carles Bo Prof. Antonio M. Echavarren 《Angewandte Chemie (International ed. in English)》2016,55(26):7487-7491
The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [AuI8] core, and pentanuclear [AuI4MI] (M=Cu, Ag) complexes is presented. The linear [AuI4] complex undergoes C?H functionalization of carbonyl compounds under mild reaction conditions. In addition, [AuI4AgI] catalyzes the carbonylation of primary amines to form ureas under homogeneous conditions with efficiencies higher than those achieved by gold nanoparticles. 相似文献
145.
Ayats C Camps P Fernández JA Vázquez S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(5):1522-1532
Compounds isolated from the reaction of (+/-)-1,3-diiodotricyclo[3.3.0.0(3,7)]octane with molten sodium or tBuLi suggest the intermediate formation of (+/-)-1,3-dehydrotricyclo[3.3.0.0(3,7)]octane. Worthy of note is the formation of stereoisomeric bi(5-methylenebicyclo[2.2.1]hept-2-ylidene) derivatives, probably by coupling of two units of (+/-)-1,3-dehydrotricyclo[3.3.0.0(3,7)]octane of the same or different absolute configuration followed by fragmentation, processes that have been studied by theoretical calculations. 相似文献
146.
In this paper, we analyze the semilocal convergence of k-steps Newton’s method with frozen first derivative in Banach spaces. The method reaches order of convergence k + 1. By imposing only the assumption that the Fréchet derivative satisfies the Lipschitz continuity, we define appropriate recurrence relations for obtaining the domains of convergence and uniqueness. We also define the accessibility regions for this iterative process in order to guarantee the semilocal convergence and perform a complete study of their efficiency. Our final aim is to apply these theoretical results to solve a special kind of conservative systems. 相似文献
147.
Curutchet C Scholes GD Mennucci B Cammi R 《The journal of physical chemistry. B》2007,111(46):13253-13265
This paper presents a quantum-mechanical study of electronic energy transfer (EET) coupling on over 100 pairs of chromophores taken from photosynthetic light-harvesting antenna proteins. Solvation effects due to the protein, intrinsic waters, and surrounding medium are analyzed in terms of screening and reaction field contributions using a model developed recently that combines a linear response approach with the polarizable continuum model (PCM). We find that the screening of EET interactions is quite insensitive to the quantum-mechanical treatment adopted. In contrast, it is greatly dependent on the geometrical details (distance, shape, and orientation) of the chromophore pair considered. We demonstrate that implicit (reaction field) as well as screening effects are dictated mainly by the optical dielectric properties of the host medium, while the effect of the static properties is substantially less important. The empirical distance-dependent screening function we proposed in a recent letter (Scholes, G. D.; Curutchet, C.; Mennucci, B.; Cammi, R.; Tomasi, J. J. Phys. Chem. B 2007, 111, 6978-6982) is analyzed and compared to other commonly used screening factors. In addition, we show that implicit medium effects on the coupling, resulting from changes in the transition densities upon solvation, are strongly dependent on the particular system considered, thus preventing the possibility of defining a general empirical expression for such an effect. 相似文献
148.
149.
The purpose of this paper is to generalize the theory of “equal share analysis”, developed by Selten in 1972, to the one in which every player has a positive weight. We show that for any positive vector of weights, α∈R ++ N , it is always possible to find a coalition structure and a payoff vector forming a proportional regular configuration. 相似文献
150.
Treatment of alk-2-ynyl derivatives of enantiopure phenylglycidol with NaN(3) triggers a cascade reaction consisting of stereospecific and regioselective epoxide ring opening followed by intramolecular azide-alkyne cycloaddition under strictly metal-free conditions. This simple one-pot procedure allows a fast buildup of molecular complexity, generating a wide array of triazolooxazepinols, triazolodiazepinols, and triazolothiazepinols. 相似文献