全文获取类型
收费全文 | 226篇 |
免费 | 18篇 |
专业分类
化学 | 210篇 |
力学 | 4篇 |
数学 | 10篇 |
物理学 | 20篇 |
出版年
2024年 | 2篇 |
2023年 | 4篇 |
2022年 | 7篇 |
2021年 | 10篇 |
2020年 | 14篇 |
2019年 | 7篇 |
2018年 | 4篇 |
2017年 | 6篇 |
2016年 | 9篇 |
2015年 | 18篇 |
2014年 | 6篇 |
2013年 | 17篇 |
2012年 | 21篇 |
2011年 | 14篇 |
2010年 | 9篇 |
2009年 | 12篇 |
2008年 | 17篇 |
2007年 | 11篇 |
2006年 | 13篇 |
2005年 | 9篇 |
2004年 | 6篇 |
2003年 | 4篇 |
2002年 | 9篇 |
2001年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1988年 | 1篇 |
1984年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1974年 | 1篇 |
1970年 | 2篇 |
1968年 | 1篇 |
排序方式: 共有244条查询结果,搜索用时 0 毫秒
21.
Selective Template Removal by Thermal Depolymerization to Obtain Mesostructured Molybdenum Oxycarbide
下载免费PDF全文
Martin Schieder Thomas Lunkenbein Carina Bojer Martin Dulle Julia vom Stein Gudrun Auffermann Tina Löbling Judith Schöbel Holger Schmalz Josef Breu 《无机化学与普通化学杂志》2015,641(10):1829-1834
The carbon content of mesostructured organic‐inorganic hybrid material of a cylindrical block copolymer template of poly(2‐vinylpyridine)‐block‐poly(allyl methacrylate) (P2VP‐b‐PAMA) and ammonium paramolybdate (APM) could be reduced by thermal depolymerization. By calcination in vacuo at 320 °C the PAMA core can be completely removed while the remaining P2VP brush preserves the mesostructure. The P2VP‐APM composite can then be carburized in‐situ to MoOxCy in a second pyrolysis step without any additional carbon source but P2VP. The molybdenum oxycarbide nanotubes obtained, form hierarchically porous non‐woven structures, which were tested as catalyst in the decomposition of NH3. They proved to be catalytically active at temperatures above 450 °C. The activation energy was estimated from an Arrhenius Plot to be 127 kJ · mol–1. 相似文献
22.
Stability and Conversion of Tin Zintl Anions in Liquid Ammonia Investigated by NMR Spectroscopy 下载免费PDF全文
Franziska Fendt Dr. Carina Koch Dr. Maria Neumeier Dr. Stefanie Gärtner Prof. Dr. Ruth M. Gschwind Prof. Dr. Nikolaus Korber 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(41):14539-14544
Homoatomic polyanions of post‐transition main‐group metals, namely, Zintl anions, are precast in analogous Zintl phases and can react in solution to form new materials. Despite comprehensible reaction approaches, the formed products cannot be planned in advance, as hitherto undetected and therefore disregarded side reactions take place. The outcomes and interpretations of the reactions of Zintl anions are so far based mainly on crystal structures, which only allow characterization of the product that has the lowest solubility. Here we present the results of our investigation of the stability of highly charged tin Zintl anions in liquid ammonia, which is not exclusively based on solution effects but also on the oxidative influence of the solvent. This allows for a deeper understanding of the ongoing processes in solution and opens doors to the directed synthesis of transition metal complexes of Sn44?, here shown by its reactivity towards MesCu. 相似文献
23.
Jonas Nilsson Fredrik Noborn Alejandro Gomez Toledo Waqas Nasir Carina Sihlbom Göran Larson 《Journal of the American Society for Mass Spectrometry》2017,28(2):229-241
Purification and liquid chromatography-tandem mass spectrometry (LC-MS/MS) characterization of glycopeptides, originating from protease digests of glycoproteins, enables site-specific analysis of protein N- and O-glycosylations. We have described a protocol to enrich, hydrolyze by chondroitinase ABC, and characterize chondroitin sulfate-containing glycopeptides (CS-glycopeptides) using positive mode LC-MS/MS. The CS-glycopeptides, originating from the Bikunin proteoglycan of human urine samples, had ΔHexAGalNAcGlcAGalGalXyl-O-Ser hexasaccharide structure and were further substituted with 0-3 sulfate and 0-1 phosphate groups. However, it was not possible to exactly pinpoint sulfate attachment residues, for protonated precursors, due to extensive fragmentation of sulfate groups using high-energy collision induced dissociation (HCD). To circumvent the well-recognized sulfate instability, we now introduced Na+ ions to form sodiated precursors, which protected sulfate groups from decomposition and facilitated the assignment of sulfate modifications. Sulfate groups were pinpointed to both Gal residues and to the GalNAc of the hexasaccharide structure. The intensities of protonated and sodiated saccharide oxonium ions were very prominent in the HCD-MS2 spectra, which provided complementary structural analysis of sulfate substituents of CS-glycopeptides. We have demonstrated a considerable heterogeneity of the bikunin CS linkage region. The realization of these structural variants should be beneficial in studies aimed at investigating the importance of the CS linkage region with regards to the biosynthesis of CS and potential interactions to CS binding proteins. Also, the combined use of protonated and sodiated precursors for positive mode HCD fragmentation analysis will likely become useful for additional classes of sulfated glycopeptides. 相似文献
24.
In this contribution three mixed least-squares finite element methods (LSFEMs) for the incompressible Navier-Stokes equations are investigated with respect to accuracy and efficiency. The well-known stress-velocity-pressure formulation is the basis for two further div-grad least-squares formulations in terms of stresses and velocities (SV). Advantage of the SV formulations is a system with a smaller matrix size due to a reduction of the degrees of freedom. The least-squares finite element formulations, which are investigated in this contribution, base on the incompressible stationary Navier-Stokes equations. The first formulation under consideration is the stress-velocity-pressure formulation according to [1]. Secondly, an extended stress-velocity formulation with an additional residual is derived based on the findings in [1] and [5]. The third formulation is a pressure reduced stress-velocity formulation based on a condensation scheme. Therefore, the pressure is interpolated discontinuously, and eliminated on the discrete level without the need for any matrix inverting. The modified lid-driven cavity boundary value problem, is investigated for the Reynolds number Re = 1000 for all three formulations. (© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
25.
de Souza CA Colombo AP Souto RM Silva-Boghossian CM Granjeiro JM Alves GG Rossi AM Rocha-Leão MH 《Colloids and surfaces. B, Biointerfaces》2011,87(2):310-318
The kinetic of chlorhexidine digluconate (CHXDG) uptake from aqueous solution by hydroxyapatite (HA) was investigated by ultraviolet (UV) analysis performed in HA powder (UV-solid) after the CHX adsorption. Adsorption isotherm of chlorhexidine (CHX) uptake was modeled by a combination of Languimir and Langmuir-Freundlich mechanisms. Strong molecule-molecule interactions and positive cooperativity predominated in the surface when CHX concentration was above 8.6 μg(CHX)/mg(HA). UV-solid spectra (shape, intensity and band position) of CHX bound to HA revealed that long-range molecular structures, such as aggregates or micelles, started to be formed at low CHX concentrations (1.52 μg(CHX)/mg(HA)) and predominated at high concentrations. Grazing-incidence X-ray diffraction (GIXRD) analysis from synchrotron radiation discarded the formation of crystalline structures on HA surface or precipitation of CHX crystalline salts, as suggested in previous works. The effect of the HA/CHX association on HA in vitro bioactivity, cytotoxicity and CHX antimicrobial activity was evaluated. It was shown that CHX did not inhibit the precipitation of a poorly crystalline apatite at HA/CHX surface after soaking in simulating body fluid (SBF). Cell viability studies after exposure to extracts of HA and HA/CHX showed that both biomaterials did not present significant in vitro toxicity. Moreover, HA/CHX inhibited Enterococcus faecalis growth for up to 6 days, revealing that binding to HA did not affect antimicrobial activity of CHX and reduced bacterial adhesion. These results suggested that HA/CHX association could result in a potential adjuvant antimicrobial system for clinical use. 相似文献
26.
Andersson S Arasa C Yabushita A Yokoyama M Hama T Kawasaki M Western CM Ashfold MN 《Physical chemistry chemical physics : PCCP》2011,13(35):15810-15820
The photodesorption of H(2)O in its vibrational ground state, and of OH radicals in their ground and first excited vibrational states, following 157 nm photoexcitation of amorphous solid water has been studied using molecular dynamics simulations and detected experimentally by resonance-enhanced multiphoton ionization techniques. There is good agreement between the simulated and measured energy distributions. In addition, signals of H(+) and OH(+) were detected in the experiments. These are inferred to originate from vibrationally excited H(2)O molecules that are ejected from the surface by two distinct mechanisms: a direct desorption mechanism and desorption induced by secondary recombination of photoproducts at the ice surface. This is the first reported experimental evidence of photodesorption of vibrationally excited H(2)O molecules from water ice. 相似文献
27.
28.
In the framework of solving elastodynamic problems using a least-squares mixed finite element method (LSFEM) the implementation of a stress-velocity formulation for small strains is introduced and discussed in the present contribution. The element formulation is based on a first-order div – grad system, with the balance equation of momentum and the constitutive law as the governing equations. Application of the L2-norm to the two residuals leads to a functional depending on stresses and velocities. Different time discretization schemes are considered, a scalar weighting is introduced and chosen in dependency of the different time discretization methods. In a numerical example the influence of the time integration method, the chosen time step width and the related weighing factor are investigated for a two-dimensional problem. (© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
29.
Gdanitz RJ Black GD Lansing CS Palmer BJ Schuchardt KL 《Journal of computational chemistry》2005,26(3):214-225
We describe the integration and use of the Amica software package ("Atoms & Molecules In Chemical Accuracy") within the Extensible Computational Chemistry Environment (Ecce). Amica is capable of accurately solving the electronic Schrodinger equation of small atoms and molecules using terms that are linear in the interelectronic distances, r(12), on multireference level of theory, but it requires expert knowledge to configure and execute its algorithms. Ecce is a comprehensive suite of tools that support the computational chemistry research processes of computation setup, execution, and analysis through a convenient graphical user interface. Additionally, Ecce was architected with mechanisms to integrate alternative electronic structure codes. The successful integration of Amica within Ecce validates the architecture of the latter and brings the high-accuracy capabilities of Amica to a wider audience. 相似文献
30.
B. Svahn A. Johansson B. Nyman G. Malmsten H. Pettersson 《Zeitschrift für Physik A Hadrons and Nuclei》1968,210(5):466-489
The internal conversion spectrum following the decay of193Au has been studied in the electron energy region 0.8 to 700 keV, with the use of high-resolution magnetic beta-ray spectrometers. Several not previously reported transitions have been estabblished. Multipolarities and mixing ratios have been deduced fromK/L and subshell intensity ratios, and the majority of the transitions were found to be ofM1 and/orE2 characters. A revised level scheme for193Pt, which consistently accomodates most transitions, has been constructed. Tentative spin-parity values have been assigned to all levels. 相似文献