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961.
A hybrid particle–continuum method is used to study the shear flow confined between two opposing walls, one of which is coated with polymer chains. Molecular dynamics (MD) is used in the particle region near the brush and Navier–Stokes (NS) equations are applied in the remaining region where the continuum assumption holds. The information exchange from the continuum region to the particle region is implemented using the constrained particle dynamics. Both Couette shear flow and oscillatory flow are considered in the present work. The effect of the shear flow on the conformational characteristics of polymer brushes is analyzed. In the overlap region, the velocities obtained from MD simulations are smoothly connected with those from NS equations. Our investigations demonstrate that the hybrid particle–continuum model is valid in exploring the shear behavior of polymer brushes. 相似文献
962.
The question of extension of functions with bounded mean oscillation (BMO) in one dimension is considered. A method of construction of an extension for which the estimate of its norm is equivalent to the best one is proposed. 相似文献
963.
V. N. Tarasov K. A. Gridnev W. Greiner S. Schramm D. K. Gridnev D. V. Tarasov X. Viñas 《Bulletin of the Russian Academy of Sciences: Physics》2014,78(7):569-575
Properties of even-even nuclei with extreme neutron excess in the vicinity of neutron magic numbers up to and beyond the neutron drip line (NDL) are calculated by the Hartree-Fock (HF) method using Skyrme forces (Ska, SkM*, Sly4, SkI2, SkP) with allowance for axial deformation and BCS-approximation pairing. It is shown that chains of isotones with the neutron numbers N = 32, 58, 82, 126, 184, and 258 beyond the NDL form peninsulas of nuclei stable with respect to emission of one neutron, and occasionally peninsulas of nuclei stable with respect to the emission of two neutrons. The length of these peninsulas in (N, Z) space depends on the choice of the Skyrme forces, while their locations are at the same N = 32, 58, 82, 126, 184, and 258 and do not depend on the choice of forces. The investigated isotones restore stability beyond the NDL due to the complete filling of subshells with high angular momentum and to the intrusion of corresponding neutron levels in the region of discrete bound states. The stability of the numerical solution to the HF equations for nuclei belonging to the peninsulas of stability is analyzed. 相似文献
964.
Nucleic acids dye Goldview is widely used in agarose gel electrophoresis (AGE). However, in this study, a sample of multiplasmid DNA (multi-pDNA) stained with Goldview analyzed by AGE showed its instability at low temperature. Three types of DNA samples were analyzed, including linear DNA (ladder), single-plasmid DNA (single-pDNA), and multi-pDNA, electrophoretic conditions were optimized by adjusting the dye, the buffer, and the temperature (1–50°C). The results showed that the light intensity of Gelred is 2.2-times higher than that of Goldview in staining multi-pDNA. Compared with the single-pDNA and the linear DNA, the multi-pDNA stained with Goldview was greatly affected by temperature. This short communication indicated that Gelred is a highly applicable dye for analyzing multiplasmid samples. The degree and the way of binding of Goldview to multi-pDNA are greatly affected by temperature. 相似文献
965.
966.
Qiuyu He Lirong Cao Yiran Wei Prof. Gregory R. Dake 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(42):e202201328
The utility of 2-diphenylphosphoryloxy-1,3-dienes for the construction of substituted six-membered nitrogen heterocycles is presented. These dienes undergo boron trifluoride-promoted aza-Diels–Alder reactions when reacted with imines or related species formed in situ using aldehydes and amine derivatives. The stability of the dienes allows this three-component reaction to be carried out with no special precautions to eliminate water or air. Thirty-one examples of this process are presented. The usefulness of the enol phosphate functional group is highlighted in further reactions after the cycloaddition step to generate functionalized piperidenes or pyridines. 相似文献
967.
Guiqiang Cao Zhikang Wang Da Bi Prof. Jing Zheng Prof. Qingxue Lai Prof. Yanyu Liang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(45):10314-10320
Lithium-sulfur batteries have been considered as potential electrochemical energy-storage devices owing to their satisfactory theoretical energy density. Nonetheless, the inferior conversion efficiency of polysulfides in essence leads to fast capacity decay during the discharge/charge cycle. In this work, it is successfully demonstrated that the conversion efficiency of lithium polysulfides is remarkably enhanced by employing a well-distributed atomic-scale Fe-based catalyst immobilized on nitrogen-doped graphene (Fe@NG) as a coating of separator in lithium-sulfur batteries. The quantitative electrocatalytic efficiency of the conversion of lithium polysulfides is determined through cyclic voltammetry. It is also proven that the Fe-NX configuration with highly catalytic activity is quite beneficial for the conversion of lithium polysulfides. In addition, the adsorption and permeation experiments distinctly indicate that the strong anchoring effect, originated from the charge redistribution of N doping into the graphene matrix, inhibits the movement of lithium polysulfides. Thanks to these advantages, if the as-prepared Fe@NG catalyst is combined with polypropylene and applied as a separator (Fe@NG/PP) in Li-S batteries, a high initial capacity (1616 mA h g−1 at 0.1 C), excellent capacity retention (93 % at 0.2 C, 70 % at 2 C), and superb rate performance (820 mA h g−1 at 2 C) are achieved. 相似文献
968.
Siberian Mathematical Journal - Let π be a set of primes and let H be a π-prefrattini subgroup of a finite soluble group G. We prove that there exist elements x, y, z ∈ G such that... 相似文献
969.
非Hermitian正定线性方程组的外推的HSS迭代方法 总被引:1,自引:0,他引:1
为了高效地求解大型稀疏非Hermitian正定线性方程组,在白中治、Golub和Ng提出的Hermitian和反Hermitian分裂(HSS)迭代法的基础上,通过引入新的参数并结合迭代法的松弛技术,对HSS迭代方法进行加速,提出了一种新的外推的HSS迭代方法(EHSS),并研究了该方法的收敛性.数值例子表明:通过参数值的选择,新方法比HSS方法具有更快的收敛速度和更少的迭代次数,选择了合适的参数值后,可以提高HSS方法的收敛效率. 相似文献
970.
Xin Dong Juan Yang Xiao-Ting Zheng Yan Chen Li-Hong Ye Bin Wang Hui Zheng Jun Cao Qiu-Yan Wang Yu-Han Hu 《Electrophoresis》2020,41(1-2):123-130
A novel micro matrix solid phase dispersion method was successfully used for the extraction of quaternary alkaloids in Phellodendri chinensis cortex. The elution of target compounds was accomplished with sodium hexanesulfonate as the eluent solvent. A neutral ion pair was formed between ion-pairing reagent and positively charged alkaloids in this process, which was beneficial for selectively extraction of polar alkaloids. Several parameters were optimized and the optimal conditions were listed as follows: silica gel as the sorbent, silica to sample mass ratio of 1:1, the grinding time of 1 min. The exhaustive elution of targets was achieved by 200 µL methanol/water (9:1) containing 150 mM sodium hexane sulfonate at pH 4.5. The method validation covered linearity, recovery, precision of intraday and interday, limits of detection, limits of quantitation, and repeatability. This established method was rapid, simple, environmentally friendly, and highly sensitive. 相似文献