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21.
Başaran Cansu Toplan Nil Toplan H. Özkan 《Journal of Thermal Analysis and Calorimetry》2018,133(1):313-319
Journal of Thermal Analysis and Calorimetry - Carbon nanotubes (CNTs) with different content of carboxylated groups on their surface (depending on the duration of their treatment with nitric acid)... 相似文献
22.
We determine a weaker sufficient condition than that of Theorem 5.2.1 in Fleming and Soner (2006) for the continuity of the value functions of stochastic exit time control problems. 相似文献
23.
With model uncertainty characterized by a convex, possibly non-dominated set of probability measures, the agent minimizes the cost of hedging a path dependent contingent claim with given expected success ratio, in a discrete-time, semi-static market of stocks and options. Based on duality results which link quantile hedging to a randomized composite hypothesis test, an arbitrage-free discretization of the market is proposed as an approximation. The discretized market has a dominating measure, which guarantees the existence of the optimal hedging strategy and helps numerical calculation of the quantile hedging price. As the discretization becomes finer, the approximate quantile hedging price converges and the hedging strategy is asymptotically optimal in the original market. 相似文献
24.
Density functional theory study of interactions between carbon dioxide and functionalized polyhedral oligomeric silsesquioxanes 下载免费PDF全文
Ilker Tezsevin Cansu Demirtas Isik Onal Cerag Dilek 《International journal of quantum chemistry》2017,117(16)
Polyhedral Oligomeric Silsesquioxanes (POSS) are cage‐structured inorganic–organic hybrid materials which can be used in various industrial applications. It is recently discovered that POSS structures with certain functional groups can be solubilized in supercritical CO2 allowing their applications in environmentally benign supercritical processing of materials. In this theoretical study, nature and energetics of the interactions of octatrifluoropropyl POSS, octatrifluoromethyl POSS, and octamethyl POSS with CO2 are investigated according to the principles of density functional theory (DFT) by use of Gaussian 09 software. Simulations show that CO2‐octamethyl POSS pair has hydrogen bonding between the O atom of CO2 and the H atom of the methyl group, and CO2‐octatrifluoromethyl POSS pair has interactions between the C atom of CO2 and the F atom of the trifluoromethyl group. CO2‐octatrifluoropropyl POSS pair is found to have both interaction types. The octamethyl, the octatrifluoromethyl and the octatrifluoropropyl POSS structures have interaction energies of ?2.18 kcal/mol, ?3.10 kcal/mol, and ?3.77 kcal/mol, respectively. This shows that the presence of Lewis acid–Lewis base interaction between C and F instead of hydrogen bonding between O and H atoms enhances the interaction of the molecule with CO2, while the presence of both interactions between the octatrifluoropropyl POSS‐CO2 pair makes the intermolecular interaction even stronger. 相似文献
25.
Alemdar Bayraktar Ahmet Can Altunişik Barış Sevim Murat Emre Kartal Temel Türker Yasemin Bilici 《Nonlinear dynamics》2009,58(4):655-673
In this paper, it is aimed to compare the near- and far-fault ground motion effects on the nonlinear dynamic response of dams
including dam–reservoir–foundation interaction. Two different types of dams, which are concrete arch and concrete faced rockfill
dams, are selected to investigate the near- and far-fault ground motion effects on the dam responses. The behavior of reservoir
water is taken into account using Lagrangian approach. The Drucker–Prager material model is employed in nonlinear analyses.
Near and far-fault strong ground motion records, which have approximately identical peak ground accelerations, of Loma Prieta
(1989) earthquake are selected for the analyses. Displacements, maximum and minimum principal stresses are determined using
the finite element method. The displacements and principal stresses obtained from the analyses of dams subjected to each fault
effect are compared with each other. It is clearly seen that there is more seismic demand on displacements and stresses when
the dam is subjected to near-fault ground motion. 相似文献
26.
Cemil Aydoan Bekir elebi Aslhan Bayraktar Fatma Ylmaz Adil Denizli Ali Tuncel 《先进技术聚合物》2014,25(8):777-783
A new reactive monolith, poly(3‐chloro‐2‐hydroxypropyl methacrylate‐co‐ethylene dimethacrylate), poly(HPMA‐Cl‐co‐EDMA) was synthesized and post‐functionalized by taurine (2‐aminoethane sulfonic acid) to obtain a zwitterionic stationary phase for capillary electrochromatography. The new stationary phase contained charged groups such as secondary amine providing anodic electroosmotic flow and sulfonic acid groups providing cathodic electroosmotic flow. Hence, the capillary electrochromatography separations with the new zwitterionic monolith were performed with either anodic or cathodic electroosmotic flow. The electrochromatographic separation of alkylbenzenes and phenols was successfully performed. The zwitterionic monolith also allowed the separation of nucleosides using only electrokinetic mode. Theoretical plate numbers up to ~105 plates/m were achieved. Our study is the first report based on poly(HPMA‐Cl‐co‐EDMA) reactive monolith post‐functionalized with a zwitterionic ligand allowing to operate in both anodic and cathodic electroosmotic flow modes. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
27.
Merve Şamlı Oguz Bayraktar Figen Korel 《Journal of inclusion phenomena and macrocyclic chemistry》2014,80(1-2):37-49
In this study, cyclodextrin inclusion complexes with rutin were prepared via co-precipitation method. Stability constant and solubility energy of beta-cyclodextrin complex were calculated as 262 M?1 and 1,737 kJ mol?1, respectively. Aqueous solubility of rutin was increased with inclusion complex of beta-cyclodextrin. The effect of temperature on both aqueous solubility of free rutin, and its inclusion complex was also studied. Characterization of cyclodextrin complexes were conducted with UV–Vis spectrophotometry, Fourier transform infrared spectroscopy, X-ray diffractometry, differential scanning calorimetry, thermal gravimetric analysis, nuclear magnetic resonance spectroscopy and scanning electron microscopy techniques. Characterization results supported formation of inclusion complexes. Dissolution profiles of rutin, physical mixture and inclusion complex of rutin were observed at 37 °C. Dissolution results proved the effect of cyclodextrin addition on solubility rate of rutin. After loading rutin and its complexes into silk fibroin based films, release tests were performed at 37 °C in neutral pH conditions for 24 h. Most of the rutin were released from silk fibroin films within the first 5 h and the rest of it was released slowly (sustained release). Electron microscope analyses showed that films had homogenous and dense morphologies. These results revealed that silk fibroin is useful for preparing bioactive films loaded with natural compounds and for modifying their release behaviour at physiological conditions. 相似文献
28.
CO2 valorization through chemical reactions attracts significant attention due to the mitigation of greenhouse gas effects. This article covers the catalytic hydrogenation of CO2 to methanol and dimethyl ether using Cu-Ho-Ga containing ZSM-5 and g-Al2O3 at atmospheric pressure and at temperatures of 210 °C and 260 °C using a CO2:H2 feed ratio of 1:3 and 1:9. In addition, the thermodynamic limitations of methanol and DME formation from CO2 was investigated at a temperature range of 100–400 °C. Cu-Ho-Ga/g-Al2O3 catalyst shows the highest formation rate of methanol (90.3 µmolCH3OH/gcat/h ) and DME (13.2 µmolDME/gcat/h) as well as the highest selectivity towards methanol and DME (39.9 %) at 210 °C using a CO2:H2 1:9 feed ratio. In both the thermodynamic analysis and reaction results, the higher concentration of H2 in the feed and lower reaction temperature resulted in higher DME selectivity and lower CO production rates. 相似文献
29.
Seyfettin Bayraktar Meral Bayraktar Nurten Vardar 《International Journal of Computational Fluid Dynamics》2013,27(5):331-339
In this paper, water flow in a rib-roughened channel is investigated numerically by using Reynolds stress turbulence models (RSM) on a three-dimensional (3-D) domain. Computational results for mean streamwise velocity component and turbulent kinetic energy show good agreements with available experimental data. Five rib pitch-to-height ratios (p/h) of 1, 5, 10, 15 and 20 are analysed for six different Reynolds numbers (Re) of 3000, 7000, 12,000, 20,000, 40,000 and 65,000. Velocity vectors, streamlines and Reynolds stresses are showed for these ratios and Re numbers. Streamlines revealed that Reynolds numbers do not affect flowfield but play an important role in the Reynolds stresses. 相似文献
30.
Mustafa Germec Fadime Demirel Nurullah Tas Ali Ozcan Cansu Yilmazer Zeynep Onuk Irfan Turhan 《Cellulose (London, England)》2017,24(10):4337-4353
Microwave-assisted pretreatment can be used for fermentable sugar production from lignocellulosic biomass. In this study, the optimum hydrolysis conditions of barley husk, oat husk, wheat bran, and rye bran were determined in power level, treatment time, solid-to-liquid ratio and dilute acid ratio as follows: 700 W, 6.92 min, 1:18.26 w/v, and 3.67% for barley husk, 600 W, 6.96 min, 1:17.22 w/v, and 3.47% for oat husk, 600 W, 6.92 min, 1:16.69 w/v, and 1.85% for wheat bran, and 460 W, 6.15 min, 1:17.14 w/v, and 2.72% for rye bran. The fermentable sugar concentrations were 37.21 (0.68 g/g), 38.84 (0.67 g/g), 49.65 (0.83 g/g), and 36.27 g/L (0.62 g/g) under optimum conditions, respectively. The results showed that microwave-assisted pretreatment is a promising technology which can be successfully implemented for the hydrolysis of lignocellulosic biomass for high sugar yield. On the other hand, hydrolysates included some inhibitors such as organic acids, furans, and phenolic compounds. Lignocellulosic biomass used in this study can be employed as good feedstocks for value-added product production in the fermentation process, after the inhibitors have been detoxified/removed with different detoxification methods. 相似文献