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Formation Mechanism of Laser‐Synthesized Iron–Manganese Alloy Nanoparticles,Manganese Oxide Nanosheets and Nanofibers 下载免费PDF全文
Dongshi Zhang Zheng Ma Marina Spasova Anna E. Yelsukova Suwei Lu Michael Farle Ulf Wiedwald Bilal Gökce 《Particle & Particle Systems Characterization》2017,34(3)
Laser ablation in liquids (LAL) has emerged as a versatile approach for the synthesis of alloy particles and oxide nanomaterials. However, complex chemical reactions often take place during synthesis due to inevitable atomization and ionization of the target materials and decomposition/hydrolysis of solvent/solution molecules, making it difficult to understand the particle formation mechanisms. In this paper, a possible route for the formation of FeMn alloy nanoparticles as well as MnOx nanoparticles, ‐sheets, and ‐fibers by LAL is presented. The observed structural, compositional, and morphological variations are clarified by transmission electron microscopy (TEM). The studies suggest that a reaction between Mn atoms and Fe ions followed by surface oxidation result in nonstoichiometric synthesis of Fe‐rich FeMn@FeMn2O4 core–shell alloy particles. Interestingly, a phase transformation from Mn3O4 to Mn2O3 and finally to Ramsdellite γ‐MnO2 is accompanied by a morphology change from nanosheets to nanofibers in gradually increasing oxidizing environments. High‐resolution TEM images reveal that the particle‐attachment mechanism dominates the growth of different manganese oxides. 相似文献
995.
Don Koks 《Foundations of Physics》2017,47(4):505-531
The disk that rotates in an inertial frame in special relativity has long been analysed by assuming a Lorentz contraction of its peripheral elements in that frame, which has produced widely varying views in the literature. We show that this assumption is unnecessary for a disk that corresponds to the simplest form of rotation in special relativity. After constructing such a disk and showing that observers at rest on it do not constitute a true rotating frame, we choose a “master” observer and calculate a set of disk coordinates and spacetime metric pertinent to that observer. We use this formalism to resolve the “circular twin paradox”, then calculate the speed of light sent around the periphery as measured by the master observer, to show that this speed is a function of sent-direction and disk angle traversed. This result is consistent with the Sagnac Effect, but constitutes a finer analysis of that effect, which is normally expressed using an average speed for a full trip of the periphery. We also use the formalism to give a resolution of “Selleri’s paradox”. 相似文献
996.
Andrei Khrennikov 《Foundations of Physics》2017,47(8):1077-1099
We discuss the problems of quantum theory (QT) complicating its merging with general relativity (GR). QT is treated as a general theory of micro-phenomena—a bunch of models. Quantum mechanics (QM) and quantum field theory (QFT) are the most widely known (but, e.g., Bohmian mechanics is also a part of QT). The basic problems of QM and QFT are considered in interrelation. For QM, we stress its nonrelativistic character and the presence of spooky action at a distance. For QFT, we highlight the old problem of infinities. And this is the main point of the paper: it is meaningless to try to unify QFT so heavily suffering of infinities with GR. We also highlight difficulties of the QFT-treatment of entanglement. We compare the QFT and QM based measurement theories by presenting both theoretical and experimental viewpoints. Then we discuss two basic mathematical constraints of both QM and QFT, namely, the use of real (and, hence, complex) numbers and the Hilbert state space. We briefly present non-archimedean and non-hilbertian approaches to QT and their consequences. Finally, we claim that, in spite of the Bell theorem, it is still possible to treat quantum phenomena on the basis of a classical-like causal theory. We present a random field model generating the QM and QFT formalisms. This emergence viewpoint can serve as the basis for unification of novel QT (may be totally different from presently powerful QM and QFT) and GR. (It may happen that the latter would also be revolutionary modified.) 相似文献
997.
We show that in Oeckl’s boundary formalism the boundary vectors that do not have a tensor form represent, in a precise sense, statistical states. Therefore the formalism incorporates quantum statistical mechanics naturally. We formulate general-covariant quantum statistical mechanics in this language. We illustrate the formalism by showing how it accounts for the Unruh effect. We observe that the distinction between pure and mixed states weakens in the general covariant context, suggesting that local gravitational processes are naturally statistical without a sharp quantal versus probabilistic distinction. 相似文献
998.
Xin-Chang Liu 《International Journal of Theoretical Physics》2017,56(2):427-436
Recently, entanglement plays an important role in quantum information science. Here we propose an efficient and applicable method which transforms arbitrary three-qubit unknown state to a maximally entangled Greenberger-Horne-Zeilinger state, and the proposed method could be further generalized to multi-qubit case. The proposed setup exploits only linear optical elements and quantum non-demolition detectors using cross-Kerr media. As the quantum non-demolition detection could reveal us the output state of the photons without destroying them. This property may make our proposed setup flexible and can be widely used in current quantum information science and technology. 相似文献
999.
Gang Ren Jian-ming Du Wen-hai Zhang Hai-jun Yu 《International Journal of Theoretical Physics》2017,56(5):1537-1549
We examine nonclassical properties of the quantum state generated by applying Hermite polynomials photon-added operator on the even/odd coherent state (HPECS/HPOCS). Explicit expressions for its nonclassical properties, such as quantum statistical properties and squeezing phenomenon, are obtained. It is interesting to find that the HPECS/HPOCS exhibits sub-Poissonian distribution, anti-bunching effects and negative values of the Wigner function. Thus, we confirm the HPPECS/HPPOCS is a new nonclassical state. Finally, we reveal that the HPPECS/HPPOCS is a novel intelligent state by its squeezing effects in position distribution and quadrature squeezing. 相似文献
1000.
In the present paper we explore the Hawking radiation as a quantum tunneling effect from a rotating 5 dimensional Myers-Perry black hole (5D-MPBH) with two independent angular momentum components. First, we investigate the Hawking temperature by considering the tunneling of massive scalar particles and spin-1 vector particles from the 5D-MPBH in the Painlevé coordinates and then in the corotating frames. More specifically, we solve the Klein-Gordon and Proca equations by applying the WKB method and Hamilton-Jacobi equation in both cases. Finally, we recover the Hawking temperature and show that coordinates systems do not affect the Hawking temperature. 相似文献