全文获取类型
收费全文 | 144761篇 |
免费 | 10159篇 |
国内免费 | 6973篇 |
专业分类
化学 | 69463篇 |
晶体学 | 1408篇 |
力学 | 10995篇 |
综合类 | 515篇 |
数学 | 39616篇 |
物理学 | 39896篇 |
出版年
2024年 | 228篇 |
2023年 | 1399篇 |
2022年 | 2280篇 |
2021年 | 2468篇 |
2020年 | 2522篇 |
2019年 | 2423篇 |
2018年 | 12056篇 |
2017年 | 11671篇 |
2016年 | 8701篇 |
2015年 | 3868篇 |
2014年 | 3923篇 |
2013年 | 5132篇 |
2012年 | 9486篇 |
2011年 | 16058篇 |
2010年 | 9439篇 |
2009年 | 9753篇 |
2008年 | 10502篇 |
2007年 | 12239篇 |
2006年 | 3757篇 |
2005年 | 4337篇 |
2004年 | 3942篇 |
2003年 | 3791篇 |
2002年 | 2657篇 |
2001年 | 1752篇 |
2000年 | 1699篇 |
1999年 | 1709篇 |
1998年 | 1518篇 |
1997年 | 1309篇 |
1996年 | 1417篇 |
1995年 | 1183篇 |
1994年 | 1081篇 |
1993年 | 957篇 |
1992年 | 820篇 |
1991年 | 726篇 |
1990年 | 603篇 |
1989年 | 538篇 |
1988年 | 424篇 |
1987年 | 406篇 |
1986年 | 354篇 |
1985年 | 346篇 |
1984年 | 244篇 |
1983年 | 212篇 |
1982年 | 186篇 |
1981年 | 150篇 |
1980年 | 128篇 |
1979年 | 93篇 |
1978年 | 90篇 |
1977年 | 70篇 |
1975年 | 73篇 |
1973年 | 82篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
采用激发样品表层和样品中心两种激发方式,在300K和77K温度下研究叶绿素A(Chla)的较高激发行为,观测到峰值位于493、520和580nm三条新的荧光发射带.分别测量它们的荧光激发光谱,证明这三条新的荧光带属于Chla的第二激发单线态向基态的不同振动能级的辐射跃迁发光.最后提出电子跃迁模型,同时进行了讨论. 相似文献
102.
Yasunari Nagai 《manuscripta mathematica》2003,110(3):273-282
We give a characterization of irreducible symplectic fourfolds which are given as Hilbert scheme of points on a K3 surface.
Received: 26 June 2002 / Revised version: 9 September 2002 Published online: 14 February 2003
Mathematics Subject Classification (2000): Primary 14J32, Secondary 32Q20 相似文献
103.
In this paper, we propose and analyze an SQP-type method for solving linearly constrained convex minimization problems where the objective functions are too complex to be evaluated exactly. Some basic results for global convergence and local superlinear convergence are obtained according to the properties of the approximation sequence. We illustrate the applicability of our approach by proposing a new method for solving two-stage stochastic programs with fixed recourse. 相似文献
104.
105.
Ben Craps Matthias R. Gaberdiel Jeffrey A. Harvey 《Communications in Mathematical Physics》2003,234(2):229-251
We study D-branes in the bosonic closed string theory whose automorphism group is the Bimonster group (the wreath product
of the Monster simple group with ℤ2). We give a complete classification of D-branes preserving the chiral subalgebra of Monster invariants and show that they
transform in a representation of the Bimonster. Our results apply more generally to self-dual conformal field theories which
admit the action of a compact Lie group on both the left- and right-moving sectors.
Received: 20 February 2002 / Accepted: 17 August 2002 Published online: 19 December 2002
Communicated by R.H. Dijkgraaf 相似文献
106.
Sheng‐Huei Hsiao Chien‐Wei Chen Guey‐Sheng Liou 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3302-3313
Two new diamines, 2,4‐diaminotriphenylamine ( 3 ) and N‐(2,4‐diaminophenyl)carbazole ( 4 ), were synthesized via the cesium fluoride‐mediated aromatic substitution reactions of 1‐fluoro‐2,4‐dinitrobenzene with diphenylamine and carbazole, followed by palladium‐catalyzed hydrazine reduction. Amorphous and soluble aramids having pendent diphenylamino and carbazolyl groups were prepared by the phosphorylation polycondensation of aromatic dicarboxylic acids with diamines 3 and 4 , respectively. The aramids derived from diamine 3 had sufficiently high molecular weights to permit the casting of flexible and tough films. They exhibited excellent mechanical properties and moderately high softening temperatures in the 221–298 °C range. However, the reactions of diamine 4 with aromatic diacids gave relatively lower molecular weights products that could not afford flexible films. For a comparative purpose, the parent aramids derived from m‐phenylenediamine and aromatic diacids were also prepared and characterized. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3302–3313, 2004 相似文献
107.
A novel copolymer, poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐2,6‐pyridylene‐1,2‐ethenylene) ( P3 ), containing N‐hexyl‐3,7‐phenothiazylene and 2,6‐pyridylene chromophores was synthesized to investigate the effect of protonation, metal complexation, and chemical oxidation on its absorption and photoluminescence (PL). Poly(N‐hexyl‐3,8‐iminodibenzyl‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) and poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) ( P2 ), consisting of 1,3‐divinylbenzene alternated with N‐hexyl‐3,8‐iminodibenzyl and N‐hexyl‐3,7‐phenothiazylene, respectively, were also prepared for comparison. Electrochemical investigations revealed that P3 exhibited lower band gaps (2.34 eV) due to alternating donor and acceptor conjugated units (push–pull structure). The absorption and PL spectral variations of P3 were easily manipulated by protonation, metal chelation, and chemical oxidation. P3 displayed significant bathochromic shifts when protonated with trifluoroacetic acid in chloroform. The complexation of P3 with Fe3+ led to a significant absorption change and fluorescence quenching, and this implied the coordination of ferric ions with the 2,6‐pyridylene groups in the backbone. Moreover, both phenothiazylene‐containing P2 and P3 showed conspicuous PL quenching with a slight redshift when oxidized with NOBF4. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1272–1284, 2004 相似文献
108.
Zhitian Liu Lei Wang Junwu Chen Feng Wang Xiaoying Ouyang Yong Cao 《Journal of polymer science. Part A, Polymer chemistry》2007,45(5):756-767
2,5‐Bis(2‐bromofluorene‐7‐yl)silole was prepared by a modified one‐pot synthesis with a reverse addition procedure, from which novel silole‐containing polyfluorenes with binary random and alternating structures (silole contents between 4.5 and 25% and high Mw up to 509 kDa were successfully synthesized. The well‐defined repeating unit of the alternating copolymer comprises a terfluorene and a silole ring. Optoelectronic properties including UV absorption, electrochemistry, photoluminescence (PL), and electroluminescence (EL) of the copolymers were examined. The different excitation energy transfers from fluorene to silole of the copolymers in solution and in the solid state were compared. The films of the copolymers showed silole‐dominant green emissions with high absolute PL quantum yields up to 83%. EL devices of the copolymers with a configuration of ITO/PEDOT/copolymer/Ba/Al displayed exclusive silole emissions peaked at around 543 nm and the highest EL efficiency was achieved with the alternating copolymer. Using the alternating copolymer and poly(9,9‐dioctylfluorene) as the blend‐type emissive layer, a maximum external quantum efficiency of 1.99% (four times to that of the neat film) was realized, which was a high efficiency so far reported for silole‐containing polymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 756–767, 2007 相似文献
109.
110.