全文获取类型
收费全文 | 817篇 |
免费 | 31篇 |
国内免费 | 1篇 |
专业分类
化学 | 504篇 |
晶体学 | 7篇 |
力学 | 14篇 |
数学 | 81篇 |
物理学 | 243篇 |
出版年
2023年 | 4篇 |
2022年 | 11篇 |
2021年 | 16篇 |
2020年 | 23篇 |
2019年 | 16篇 |
2018年 | 16篇 |
2017年 | 11篇 |
2016年 | 35篇 |
2015年 | 21篇 |
2014年 | 34篇 |
2013年 | 54篇 |
2012年 | 54篇 |
2011年 | 44篇 |
2010年 | 48篇 |
2009年 | 31篇 |
2008年 | 49篇 |
2007年 | 39篇 |
2006年 | 44篇 |
2005年 | 34篇 |
2004年 | 26篇 |
2003年 | 23篇 |
2002年 | 32篇 |
2001年 | 18篇 |
2000年 | 15篇 |
1999年 | 11篇 |
1998年 | 5篇 |
1997年 | 16篇 |
1996年 | 13篇 |
1995年 | 9篇 |
1994年 | 8篇 |
1993年 | 13篇 |
1992年 | 10篇 |
1990年 | 6篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 5篇 |
1983年 | 9篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1964年 | 1篇 |
排序方式: 共有849条查询结果,搜索用时 46 毫秒
61.
Manoel Raimundo dos Santos Junior Elinia Castro Costa Caio Campos Ferreira Lucas Pinto Bernar Marcilene Paiva da Silva Andria de Andrade Mncio Marcelo Costa Santos Sílvio Alex Pereira da Mota Douglas Alberto Rocha de Castro Sergio Duvoisin Junior Luiz Eduardo Pizarro Borges Marilena Emmi Araújo Nlio Teixeira Machado 《Molecules (Basel, Switzerland)》2022,27(7)
In this work, the deoxygenation of organic liquid products (OLP) obtained through the thermal catalytic cracking of palm oil at 450 °C, 1.0 atmosphere, with 10% (wt.) Na2CO3 as a catalyst, in multistage countercurrent absorber columns using supercritical carbon dioxide (SC-CO2) as a solvent, with an Aspen-HYSYS process simulator, was systematically investigated. In a previous study, the thermodynamic data basis and EOS modeling necessary to simulate the deoxygenation of OLP was presented. This work addresses a new flowsheet, consisting of 03 absorber columns, 10 expansions valves, 10 flash drums, 08 heat exchanges, 01 pressure pump, and 02 make-ups of CO2, aiming to improve the deacidification of OLP. The simulation was performed at 333 K, 140 bar, and (S/F) = 17; 350 K, 140 bar, and (S/F) = 38; 333 K, 140 bar, and (S/F) = 25. The simulation shows that 81.49% of OLP could be recovered and that the concentrations of hydrocarbons in the extracts of absorber-01 and absorber-02 were 96.95 and 92.78% (wt.) on a solvent-free basis, while the bottom stream of absorber-03 was enriched in oxygenated compounds with concentrations of up to 32.66% (wt.) on a solvent-free basis, showing that the organic liquid products (OLP) were deacidified and SC-CO2 was able to deacidify the OLP and obtain fractions with lower olefin contents. The best deacidifying condition was obtained at 333 K, 140 bar, and (S/F) = 17. 相似文献
62.
M. Campos E. M. Cavalcante J. Kalinowski 《Journal of Polymer Science.Polymer Physics》1996,34(4):623-629
The conductivity of poly(p-phenylene sulfide) (PPS) amorphous samples sandwiched between metallic electrodes has been studied as a function of applied voltage, temperature, and electrode material. The voltage (U) dependence of the currents for electric fields within the range 103–106 V/cm exhibits exp βU1/2 behavior with β = βSchottky below the glass transition temperature (Tg ≊ 90°C), and β = βPoole-Frenkel above Tg. Coordinated temperature measurements of dc currents with different metallic contacts and thermally stimulated currents (TSC) indicate, however, that the conductivity at T < Tg is consistent with the so-called “anomalous” Poole-Frenkel effect rather than the Schottky effect. Consequently, the p-type conductivity in amorphous PPS is proposed to be a bulk-limited process due to ionization of two different types of acceptor centers in the presence of neutral hole traps. © 1996 John Wiley & Sons, Inc. 相似文献
63.
Patrícia Homobono Brito de Moura Wolfgang Brandt Andrea Porzel Roberto Carlos Campos Martins Ivana Correa Ramos Leal Ludger A. Wessjohann 《Molecules (Basel, Switzerland)》2022,27(8)
A rare dihydoxyflavan-epicatechin proanthocyanidin, entcassiflavan-(4β→8)-epicatechin, was isolated from Dalbergia monetaria, a plant widely used by traditional people from the Amazon to treat urinary tract infections. The constitution and relative configuration of the compound were elucidated by HR-MS and detailed 1D- and 2D-NMR measurements. By comparing the experimental electronic circular dichroism (ECD) spectrum with the calculated ECD spectra of all 16 possible isomers, the absolute configuration, the interflavan linkage, and the atropisomers could be determined. 相似文献
64.
Dayanne Cristiane Mozaner Bordin Marcela Nogueira Rabelo Alves Eduardo Geraldo de Campos Bruno Spinosa De Martinis 《Journal of separation science》2016,39(6):1168-1172
Disposable pipette tips extraction consists of a solid‐phase extraction in which the sorbent is poorly dispersed in a pipette tip, which allows a quick and dynamic contact between the aspirated analyte from the sample and the solid phase. It is a technique used particularly in food and forensic analysis, since it requires a small amount of sample and solvent. This article highlights the principles, advantages and disadvantages of the disposable pipette tips extraction method and reviews recent applications. 相似文献
65.
The reactivity of ethyl‐, propyl‐ and octylgallate towards diphenylpicryl hydracil radicals has been measured in homogeneous solution (ethanol) and in Triton X‐100 micellar solutions. Similar reactivities were measured in homogeneous solutions, indicating that the length of the alkyl chain does not influence the reactivity of the phenolic groups. On the other hand, different reactivities were measured in micellar solutions, particularly at low (5 mM) surfactant concentrations. Data obtained at different surfactant concentrations allow estimation of partitioning of the gallates and their intramicellar bimolecular rate constant. The values obtained indicate that all the observed differences in reactivity are attributable to differences in substrate partitioning between the micellar and aqueous pseudophases. In fact, similar values of the intramicellar rate constants were obtained, suggesting that the average location of the reactive groups inside the micelles is independent of the solute alkyl chain length. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
66.
67.
Reyes-Chilpa R Jiménez-Estrada M Godínez MV Hernández-Ortega S Campos M Béjar E 《Natural product letters》2002,16(4):239-242
A new cacalolide sesquiterpenoid, named as Romo-A, was isolated from the roots of Psacalium decompositum, Asteraceae, a Mexican medicinal shrub with antidiabetic properties. Its structure was elucidated by NMR, MS, IR, UV, and confirmed by X-ray diffraction studies. 相似文献
68.
69.
Relative transition probabilities for lines belonging to the 5p-nd (n = 4,5,6,7) transition arrays of neutral krypton have been determined by means of emission line-intensity measurements. The experimental values of the present work are compared with the experimental and theoretical data given by other authors. The relative transition probabilities for lines arising from some levels belonging to the 4p5nd (n = 6,7) configurations have been put on an absolute scale, taking into account experimental and theoretical data. 相似文献
70.
Wipf P Lynch SM Birmingham A Tamayo G Jiménez A Campos N Powis G 《Organic & biomolecular chemistry》2004,2(11):1651-1658
Spiroketal naphthodecalins are readily assembled by Barton's base mediated Ullmann binaphthyl ether coupling, Dakin reactions and hypervalent iodine spirocyclization. The core structures can be further diversified by enone addition and Stille coupling reactions. Nanomolar inhibitors for the Trx/TrxR redox control system were prepared by this approach and compared to series of natural product isolates. Cytotoxicity in MCF-7 cell assays ranged from an IC50 of 1.6 to >100 microM. 相似文献