首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1632篇
  免费   32篇
  国内免费   3篇
化学   787篇
晶体学   10篇
力学   33篇
数学   156篇
物理学   681篇
  2021年   10篇
  2020年   17篇
  2019年   20篇
  2018年   10篇
  2017年   14篇
  2016年   26篇
  2015年   21篇
  2014年   26篇
  2013年   68篇
  2012年   67篇
  2011年   63篇
  2010年   47篇
  2009年   35篇
  2008年   66篇
  2007年   71篇
  2006年   70篇
  2005年   66篇
  2004年   51篇
  2003年   23篇
  2002年   52篇
  2001年   35篇
  2000年   29篇
  1999年   15篇
  1998年   22篇
  1997年   27篇
  1996年   46篇
  1995年   47篇
  1994年   37篇
  1993年   54篇
  1992年   43篇
  1991年   23篇
  1990年   38篇
  1989年   16篇
  1988年   20篇
  1987年   16篇
  1986年   17篇
  1985年   20篇
  1984年   17篇
  1983年   18篇
  1982年   20篇
  1981年   23篇
  1980年   18篇
  1979年   25篇
  1978年   21篇
  1977年   19篇
  1976年   16篇
  1975年   20篇
  1974年   12篇
  1973年   10篇
  1972年   10篇
排序方式: 共有1667条查询结果,搜索用时 15 毫秒
991.
In this paper, the authors investigate the electromagnetic properties of stacks of high temperature superconductor (HTS) coated conductors with a particular focus on calculating the total transport AC loss. The cross-section of superconducting cables and coils is often modeled as a two-dimensional stack of coated conductors, and these stacks can be used to estimate the AC loss of a practical device. This paper uses a symmetric two dimensional (2D) finite element model based on the H formulation, and a detailed investigation into the effects of a magnetic substrate on the transport AC loss of a stack is presented. The number of coated conductors in each stack is varied from 1 to 150, and three types of substrate are compared: non-magnetic weakly magnetic and strongly magnetic. The non-magnetic substrate model is comparable with results from existing models for the limiting cases of a single tape (Norris) and an infinite stack (Clem). The presence of a magnetic substrate increases the total AC loss of the stack, due to an increased localized magnetic flux density, and the stronger the magnetic material, the further the flux penetrates into the stack overall. The AC loss is calculated for certain tapes within the stack, and the differences and similarities between the losses throughout the stack are explained using the magnetic flux penetration and current density distributions in those tapes. The ferromagnetic loss of the substrate itself is found to be negligible in most cases, except for small magnitudes of current. Applying these findings to practical applications, where AC transport current is involved, superconducting coils should be wound where possible using coated conductors with a non-magnetic substrate to reduce the total AC loss in the coil.  相似文献   
992.
The capacity of a brass instrument to generate sounds with strong high-frequency components is dependent on the extent to which its bore profile supports nonlinear sound propagation. At high dynamic levels some instruments are readily sounded in a "cuivre?" (brassy) manner: this phenomenon is due to the nonlinear propagation of sound in ducts of the proportions typical of labrosones (lip-reed aerophones). The effect is also evident at lower dynamic levels and contributes to the overall tonal character of the various kinds of brass instrument. This paper defines a brassiness potential parameter derived from the bore geometries of brass instruments. The correlation of the brassiness potential parameter with spectral enrichment as measured by the spectral centroid of the radiated sound is examined in playing tests using musicians, experiments using sine-wave excitation of instruments, and simulations using a computational tool. The complementary effects of absolute bore size on spectral enrichment are investigated using sine-wave excitation of cylindrical tubes and of instruments, establishing the existence of a trade-off between bore size and brassiness potential. The utility of the brassiness potential parameter in characterizing labrosones is established, and the graphical presentation of results in a 2D space defined by bore size and brassiness potential demonstrated.  相似文献   
993.
We have observed exclusive γγ production in proton-antiproton collisions at √s=1.96 TeV, using data from 1.11±0.07 fb(-1) integrated luminosity taken by the Run II Collider Detector at Fermilab. We selected events with two electromagnetic showers, each with transverse energy E(T)>2.5 GeV and pseudorapidity |η|<1.0, with no other particles detected in -7.4<η<+7.4. The two showers have similar E(T) and azimuthal angle separation Δφ~π; 34 events have two charged particle tracks, consistent with the QED process ppˉ→p+e(+)e(-)+pˉ by two-photon exchange, while 43 events have no charged tracks. The number of these events that are exclusive π(0)π(0) is consistent with zero and is <15 at 95% C.L. The cross section for ppˉ→p+γγ+pˉ with |η(γ)|<1.0 and E(T)(γ)>2.5 GeV is 2.48(-0.35)(+0.40)(stat)(-0.51)(+0.40)(syst) pb.  相似文献   
994.
One of the major challenges in environmental analytical chemistry is to develop methods for determining metal speciation in natural waters that contain low metal concentrations and dissolved organic matter (DOM). Because of its complex heterogeneous nature, metal binding to DOM cannot be predicted accurately using equilibrium models. Two independent speciation methods, the equilibrium ion-exchange technique (IET) and equilibrium dialysis (EqD), were used to determine silver binding by standard Suwannee River humic acid. Both approaches gave very similar results, although for a given silver loading, the concentration of free silver obtained by IET was somewhat higher than that determined by EqD. Our results suggest that any high-affinity binding sites present within the humic acid are likely saturated at [Ag(T)] > 10(-9) M. This comparison of free metal ion concentrations with two independent methods provides useful speciation information in the absence of reliable complexation constants for the reaction of silver with humic acid.  相似文献   
995.
996.
Multiple isotope effects were measured at the reactive center of formamide during acid-catalyzed hydrolysis in water at 25 degrees C. The mechanism involves a rapid pre-equilibrium protonation of the carbonyl oxygen, followed by the formation of at least one tetrahedral intermediate, which does not appreciably exchange its carbonyl oxygen with the solvent (kh/kex = 55). The pKa for formamide was determined by 15N NMR and found to be about -2.0. The formyl-hydrogen kinetic isotope effect (KIE) is indicative of a transition state that is highly tetrahedral (Dkobs = 0.79); the carbonyl-carbon KIE (13kobs = 1.031) is in agreement with this conclusion. The small leaving-nitrogen KIE (15kobs = 1.0050) is consistent with some step prior to breaking the C-N bond as rate-determining. The carbonyl-oxygen KIE (18kobs = 0.996) points to attack of water as the rate-determining step. On the basis of these results, a mechanism is proposed in which attachment of the nucleophile to a protonated formamide molecule is rate determining.  相似文献   
997.
This paper seeks to provide a framework and benchmark for the allocation of marketing budget between promotion and loyalty programmes using an approach that combines a Markov-type market share model and the Lagrange multiplier method to maximize market share. The Lagrange multiplier method, that takes into account the market share and the loyalty effect observable in preceding periods along with the estimated promotional effects, permits the allocation to be optimized and future market share to be maximized. Then, loyalty-based consumer segment are used to explain why the budgeting exercise can achieve the maximization objective. To this end, the study uses consumer panel data concerning three categories, namely, adult milk powder, shampoo, and detergent. It extends previous research on loyalty-based segmentation by focusing on the budget allocation between the two options of loyalty enhancement and promotion programming. A Budget Allocation Grid for Loyalty-based Segmentation is proposed as an aid to understand budget allocation between loyalty and promotion programmes based on the relative sizes of exclusive-loyalty and variety-seeking segments.  相似文献   
998.
To improve the properties of polycrystalline Ge thin films, which are a candidate material for the bottom cells of low cost monolithic tandem solar cells, ∼300 nm in situ hydrogenated Ge (Ge:H) thin films were deposited on silicon nitride coated glass by radio-frequency magnetron sputtering. The films were sputtered in a mixture of 15 sccm argon and 10 sccm hydrogen at a variety of low substrate temperatures (Ts)≤450 °C. Structural and optical properties of the Ge:H thin films were measured and compared to those of non-hydrogenated Ge thin films deduced in our previous work. Raman and X-ray diffraction spectra revealed a structural evolution from amorphous to crystalline phase with increase in Ts. It is found that the introduction of hydrogen gas benefits the structural properties of the polycrystalline Ge film, sputtered at 450 °C, although the onset crystallization temperature is ∼90 °C higher than in those sputtered without hydrogen. Compared with non-hydrogenated Ge thin films, hydrogen incorporated in the films leads to broadened band gaps of the films sputtered at different Ts.  相似文献   
999.
We report on direct experimental evidence of the population of the 3/23/2 intruder state in 27Ne in the knockout of a single neutron from the ground state of 28Ne. This low-lying negative parity state is consistent with a narrower shell gap for exotic nuclei with Z?NZ?N and N≈20N20. Monte Carlo shell-model calculations with the modern SDPF-M interaction successfully describe neutron-rich nuclei in the vicinity of N=20N=20 where normal and intruder configurations coexist at low excitation energy. This observation demonstrates the importance of direct reactions for the study of exotic nuclei and the predictive power of these large-scale shell-model calculations.  相似文献   
1000.
The cyclin-dependent kinases (CDKs) have been characterized in complex with a variety of inhibitors, but the majority of structures solved are in the inactive form. We have solved the structures of six inhibitors in both the monomeric CDK2 and binary CDK2/cyclinA complexes and demonstrate that significant differences in ligand binding occur depending on the activation state. The binding mode of two ligands in particular varies substantially in active and inactive CDK2. Furthermore, energetic analysis of CDK2/cyclin/inhibitors demonstrates that a good correlation exists between the in vitro potency and the calculated energies of interaction, but no such relationship exists for CDK2/inhibitor structures. These results confirm that monomeric CDK2 ligand complexes do not fully reflect active conformations, revealing significant implications for inhibitor design while also suggesting that the monomeric CDK2 conformation can be selectively inhibited.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号