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991.
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Silva Jéssica Priscila Avelino Figueirêdo Camila Bezerra Melo de Medeiros Vieira Amanda Carla Quintas de Lyra Magaly Andreza Marques Rolim Larissa Araújo Rolim-Neto Pedro José de La Roca Soares Mônica Felts Albuquerque Miracy Muniz Soares-Sobrinho José Lamartine 《Journal of Thermal Analysis and Calorimetry》2017,130(3):1643-1651
995.
Michael S. Reid Heera S. Marway Camila Moran-Hidalgo Marco Villalobos Emily D. Cranston 《Cellulose (London, England)》2017,24(11):4743-4757
The recent intensification of industrially produced cellulose nanocrystals (CNCs) and cellulose nanofibrils has positioned nanocelluloses as promising materials for many water-based products and applications. However, for nanocelluloses to move beyond solely an academic interest, a thorough understanding of their interaction with water-soluble polymers is needed. In this work, we address a conflicting trend in literature that suggests polyethylene glycol (PEG) adsorbs to CNC surfaces by comparing the adsorption behaviour of PEG with CNCs versus fumed silica. While PEG is known to have strong hydrogen bonding tendencies and holds water tightly, it is sometimes (we believe erroneously) presumed that PEG binds to cellulose through hydrogen bonding in aqueous media. To test this assumption, the adsorption of PEG to CNCs and fumed silica (both in the form of particle films and in aqueous dispersions) was examined using quartz crystal microbalance with dissipation, isothermal titration calorimetry, rheology and dynamic light scattering. For all PEG molecular weights (300–10,000 g/mol) and concentrations (100–10,000 ppm) tested, strong rapid adsorption was found with fumed silica, whereas no adsorption to CNCs was observed. We conclude that unlike silanols, the hydroxyl groups on the surface of CNCs do not readily hydrogen bond with the ether oxygen in the PEG backbone. As such, this work along with previous papermaking literature supports the opinion that PEG does not adsorb to cellulose surfaces. 相似文献
996.
Lange Camila N. Camargo Iara M. C. Figueiredo Ana Maria G. M. Castro Liliana Vasconcellos Marina B. A. Ticianelli Regina B. 《Journal of Radioanalytical and Nuclear Chemistry》2017,311(2):1235-1241
Rare earth elements (REEs) have several applications and their market demands have increased. Recently, coal fly ash (CFA) has been considered as a source of these elements. The purpose of this study was to evaluate the REEs content in a CFA from a Brazilian coal power plant by instrumental neutron analysis, to classify it according to commercial purposes and to assess the weathering impact in the REEs content, since it is held in fields nearby the power plant. The results pointed no significant REEs leachability and indicated this CFA as a promising REEs source.
相似文献997.
Synthesis of Amphiphilic RuII Heteroleptic Complexes Based on Benzo[1,2‐b:4,5‐b′]dithiophene: Relevance of the Half‐Sandwich Complex Intermediate and Solvent Compatibility 下载免费PDF全文
Dr. Maxence Urbani María Medel Dr. Sangeeta Amit Kumar Dr. Mine Ince Prof. Ashok N. Bhaskarwar Dr. David González‐Rodríguez Michael Grätzel Prof. Mohammad Khaja Nazeeruddin Prof. Tomás Torres 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(45):16252-16265
The detailed synthesis and characterization of four ruthenium(II) complexes [RuLL′(NCS)2] is reported, in which L represents a 2,2′‐bipyridine ligand functionalized at the 4,4′ positions with benzo[1,2‐b:4,5‐b′]dithiophene derivatives (BDT) and L′ is 2,2′‐bipyridine‐4,4′‐dicarboxylic acid unit (dcbpy) (NCS=isothiocyanate). The reaction conditions were adapted and optimized for the preparation of these amphiphilic complexes with a strong lipophilic character. The photovoltaic performances of these complexes were tested in TiO2 dye‐sensitized solar cell (DSSC) achieving efficiencies in the range of 3–4.5 % under simulated one sun illumination (AM1.5G). 相似文献
998.
M. Galan Vallejo M. A. Lopez Torres 《Journal of Dispersion Science and Technology》2013,34(4):441-442
ABSTRACT The specific refraction, specific volume, and viscosity of systems containing sodium alkyl-ether-sulfate(NaEOS)(10, 20, 25, 27.5, and 30% w/w)and sodium xylene-sulfonate(NaXS) (1, 2, and 3% w/w) has been studied in the temperature range of 278 to 313 K. From this study, the following conclusions may be drawn: All systems show Newtonian behavior for the shear-rate range 0 to 28.5 s-1. The addition of sodium xylene-sulfonate produces a progressive viscosity reduction for a constant concentration of sodium alkyl-ether-sulfate. 相似文献
999.
Carolina R. Ganivet Dr. Beatriz Ballesteros Dr. Gema de la Torre Dr. Juan M. Clemente‐Juan Prof. Eugenio Coronado Prof. Tomás Torres 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(4):1457-1465
A series of homoleptic ([TbIII(Pc)2]) and heteroleptic ([TbIII(Pc)(Pc′)]) TbIII bis(phthalocyaninate) complexes that contain different peripheral substitution patterns (i.e., tert‐butyl or tert‐butylphenoxy groups) have been synthesized in their neutral radical forms and then reduced into their corresponding anionic forms as stable tetramethylammonium/tetrabutylammonium salts. All of these compounds were spectroscopically characterized and their magnetic susceptibility properties were investigated. As a general trend, the radical forms exhibited larger energy barriers for spin reversal than their corresponding reduced compounds. Remarkably, heteroleptic complexes that contain electron‐donor moieties on one of the two Pc ligands show higher effective barriers and blocking temperatures than their homoleptic derivatives. This result is assigned to the elongation of the N? Tb distances in the substituted macrocycle, which brings the terbium(III) ion closer to the unsubstituted Pc, thus enhancing the ligand‐field effect. In particular, heteroleptic [TbIII(Pc)(Pc′)] complex 4 , which contains one octa(tert‐butylphenoxy)‐substituted Pc ring and one bare Pc ring, exhibits the highest effective barrier and blocking temperature for a single‐molecule magnet reported to date. 相似文献
1000.
M. L. Riba J. P. Tathy J. Mathieu L. Torres 《International journal of environmental analytical chemistry》2013,93(3-4):255-263
Abstract Up to the present it has been established that natural hydrocarbons, such as isoprene and the monoterpenes, play an important role in the physical chemistry of the atmosphere because of their high reactivity. However, their true contribution to the natural chemical system has not yet been clearly defined as the seasonal variations in their concentrations are not sufficiently accurately known due to their low content in the atmosphere (a few hundredths of a ppb to a few ppb). We have developed an analysis procedure which enables quantitative trapping to be carried out together with excellent chromatographic separation. It consists of enrichment on adsorbents followed by very rapid thermal desorption and instantaneous chromatographic injection without further cryogenic trapping. Our adsorption-desorption cycle does not reduce the efficiency of the chromatographic separation at all and does not bring about any decomposition of these highly reactive plant oils. 相似文献