全文获取类型
收费全文 | 1516篇 |
免费 | 186篇 |
国内免费 | 177篇 |
专业分类
化学 | 1113篇 |
晶体学 | 13篇 |
力学 | 83篇 |
综合类 | 11篇 |
数学 | 183篇 |
物理学 | 476篇 |
出版年
2024年 | 10篇 |
2023年 | 43篇 |
2022年 | 70篇 |
2021年 | 70篇 |
2020年 | 87篇 |
2019年 | 68篇 |
2018年 | 63篇 |
2017年 | 70篇 |
2016年 | 75篇 |
2015年 | 67篇 |
2014年 | 95篇 |
2013年 | 117篇 |
2012年 | 134篇 |
2011年 | 130篇 |
2010年 | 84篇 |
2009年 | 70篇 |
2008年 | 80篇 |
2007年 | 75篇 |
2006年 | 76篇 |
2005年 | 69篇 |
2004年 | 30篇 |
2003年 | 36篇 |
2002年 | 24篇 |
2001年 | 29篇 |
2000年 | 26篇 |
1999年 | 30篇 |
1998年 | 15篇 |
1997年 | 15篇 |
1996年 | 24篇 |
1995年 | 14篇 |
1994年 | 19篇 |
1993年 | 7篇 |
1992年 | 17篇 |
1991年 | 10篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1987年 | 6篇 |
1986年 | 7篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1970年 | 1篇 |
1965年 | 1篇 |
1958年 | 1篇 |
排序方式: 共有1879条查询结果,搜索用时 15 毫秒
71.
A Cu(OAc)2/DDQ/DTBP/Py system catalyzed oxidative dehydrogenative silylation‐alkenation tandem reaction of readily available alkyl aromatic compounds with silanes was established. A variety of functionalized alkenyl organosilicon compounds were provided in good to high yields with a total β‐(E) selectivity. The control experiments revealed that the transformation might proceed through a radical pathway. 相似文献
72.
Hongfeng Li Peng Wu Yawen Xiao Meng Shao Yu Shen Yun Fan Huanhuan Chen Ruijie Xie Wenlei Zhang Sheng Li Jiansheng Wu Yu Fu Bing Zheng Weina Zhang Fengwei Huo 《Angewandte Chemie (International ed. in English)》2020,59(12):4763-4769
Metal–organic frameworks (MOFs) are promising materials with fascinating properties. Their widespread applications are sometimes hindered by the intrinsic instability of frameworks. However, this instability of MOFs can also be exploited for useful purposes. Herein, we report the use of MOFs as metal ion precursors for constructing functional nanocomposites by utilizing the instability of MOFs. The heterogeneous growth process of nanostructures on substrates involves the release of metal ions, nucleation on substrates, and formation of a covering structure. Specifically, the synthesized CoS with carbon nanotubes as substrates display enhanced performance in a lithium‐ion battery. Such strategy not only presents a new way for exploiting the instability of MOFs but also supplies a prospect for designing versatile functional nanocomposites. 相似文献
73.
AbstractTwo new alkaloids, fluevirines E (1) and F (2), along with six known Securinega alkaloids, were isolated from the methanol extract of the twigs and leaves of Flueggea virosa. The structures and absolute configurations of the new compounds were elucidated by means of MS, NMR, and ECD analyses. Compound 1 is a new dimeric indole alkaloid while 2 is a new securinega-type alkaloid. The in vitro cytotoxic activities of the isolated alkaloids against several human cancer cell lines and their acetylcholinesterase inhibitory activity were also evaluated. 相似文献
74.
Hui Sun Yun-Feng Zhang Hui-Xia Huo Peng-Wei Guan Chao-Chao Wang Hui-Na Yao 《Natural product research》2020,34(14):2030-2036
AbstractTwo new benzophenone glycosides, aquilarisides A (1) and B (2), together with six known analogues (3-8) were isolated from the pericarps of Aquilaria yunnanensis S. C. Huang. Their structures were elucidated on the basis of 1D and 2D NMR and mass spectroscopic analyses, and the absolute configuration of compound 1 was determined by experimental and calculated electronic circular dichroism (ECD) spectra. Anti-inflammatory activities of all compounds 1–8 were evaluated for their inhibitory activities against lipopolysaccharide (LPS)-stimulated induced nitric oxide (NO) production in RAW 264.7 cells using the Griess assay. Compound 2 indicated a weak inhibition of NO production. 相似文献
75.
Shuxin Zhang Chang Chen Chang Xue Dingran Chang Huo Xu Bruno J. Salena Yingfu Li Zai‐Sheng Wu 《Angewandte Chemie (International ed. in English)》2020,59(34):14584-14592
Herein, we report on the design of a programmable DNA ribbon using long‐chain DNA molecules with a user‐defined repetitive padlock sequence. The DNA ribbon can be further combined with gold nanoparticles (AuNPs) to create a composite nanomaterial that contains an AuNP core and a high‐density DNA crown carrying a cancer‐cell‐targeting DNA aptamer, a fluorescent tag for location tracking, and a cell‐killing drug. This composite material can be efficiently internalized by cancer cells and its cellular location can be tracked by fluorescence imaging. The system offers several attractive characteristics, including simple design, tunable DNA crown, high drug‐loading capacity, selective cell targeting, and pH‐sensitive drug release. These features make such a material a promising therapeutic agent. 相似文献
76.
1 引言
小波分析是结合泛函分析、应用数学、逼近论、调和分析、广义函数论等数学知识的结晶,具有深刻的理论意义和广泛的应用范围,被称为”数学显微镜”.基于其多分辨分析的特点以及在时、频两域都具有表征信号局部特征的功能,应用它可以解决许多Fourier变换不能解决的难题,为工程应用提供了一种新的、更有效的分析工具[1],由... 相似文献
77.
78.
79.
大豆中二硝基苯胺类除草剂多残留的气相色谱法定量检测及质谱确证 总被引:3,自引:0,他引:3
建立以凝胶渗透色谱法(GPC)和固相萃取法(SPE)及气相色谱法(GC)联用技术测定大豆中10种二硝基苯胺类除草剂(氟乐灵、乙氟灵、环丙氟、氯乙氟灵、仲丁灵、异乐灵、二甲戊乐灵、二硝胺、氨基丙氟灵和磺乐灵)多残留检测方法。目标农药经正己烷饱和的乙腈提取,凝胶渗透色谱除去大豆中大部分油脂及色素,再经Florisil柱净化和富集,依次用6mL二氯甲烷和6mL二氯甲烷+丙酮(99+1)洗脱。目标农药采用电子捕获检测(GC/ECD),外标法定量,并经质谱(MS)确证。两个添加水平重复6次,回收率分别为74%~105%和59%~105%;相对标准偏差〈20%;检出限为1.8~7.6μg/kg;定量限为6~38μg/kg。 相似文献
80.