首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1488篇
  免费   183篇
  国内免费   172篇
化学   1094篇
晶体学   13篇
力学   83篇
综合类   11篇
数学   183篇
物理学   459篇
  2024年   6篇
  2023年   40篇
  2022年   60篇
  2021年   66篇
  2020年   87篇
  2019年   67篇
  2018年   62篇
  2017年   68篇
  2016年   71篇
  2015年   65篇
  2014年   93篇
  2013年   116篇
  2012年   132篇
  2011年   130篇
  2010年   84篇
  2009年   70篇
  2008年   80篇
  2007年   75篇
  2006年   76篇
  2005年   69篇
  2004年   30篇
  2003年   36篇
  2002年   24篇
  2001年   29篇
  2000年   26篇
  1999年   30篇
  1998年   15篇
  1997年   15篇
  1996年   24篇
  1995年   14篇
  1994年   19篇
  1993年   7篇
  1992年   17篇
  1991年   10篇
  1990年   4篇
  1989年   2篇
  1988年   3篇
  1987年   6篇
  1986年   7篇
  1985年   2篇
  1984年   1篇
  1983年   1篇
  1982年   1篇
  1970年   1篇
  1965年   1篇
  1958年   1篇
排序方式: 共有1843条查询结果,搜索用时 15 毫秒
61.
A model for competition between antibiotic-sensitive and antibiotic-resistant bacteria with nutrient recycling and antibiotic treatment in a chemostat is considered. The sufficient and necessary conditions for boundedness of the solution and existence of non-negative equilibria are derived. The extinction and uniform persistence of antibiotic-sensitive and antibiotic-resistant bacteria are also carried out. Numerical simulations are then given to illustrate our main results.  相似文献   
62.
Triarylaminium salt was disclosed as a highly efficient nonmetallic initiator for the Friedel–Crafts reaction between chalcone epoxides and heteroarenes to construct a series of complex β-heteroaryl α-ketols in mild conditions and with good yields. Chalcone epoxides were presented as valuable halogen-free pre-electrophile in Friedel–Crafts alkylation through the formation of the stabilized benzylic cation intermediates. A plausible radical cation chain mechanism was also proposed.  相似文献   
63.
64.
65.
In the present paper, we introduce some new subclasses of meromorphic starlike,convex, close-to-convex and quasi-convex functions of β-reciprocal in terms of the linear operator using subordination. We obtain the coefficient estimates, convolution properties, integral preserving properties and inclusion relationships of the classes. The results presented here include several results as their special cases.  相似文献   
66.
The polyhydroxyurethane/attapulgite nanocomposites (PHU/ATP) were prepared by in-situ surface-initiated polymerization of a five-membered cyclic carbonate, 2, 2-bis [p-(1, 3-dioxolan-2-one-4-yl-methoxy) phenyl] propane (B5CC) and hexamethylene diamine, from the surface of the aminopropyl attapulgite nanoparticles (APATP) for the first time. The chemical grafting of the polymer on the surface of ATP was confirmed by FTIR and the morphology of the attapulgite nanoparticles in the nanocomposites was examined by TEM. The thermal stabilities of the polyhydroxyurethane (PHU) and the polyhydroxyurethane/attapulgite nanocomposites (PHU/ATP) were compared with thermogravimetric analysis (TGA).The %G of the attapulgite nanoparticles was also calculated from the results of TGA after the free polyhydroxyurethane was washed off.  相似文献   
67.
The anode materials Li4?xMgxTi5?xZrxO12 (x=0, 0.05, 0.1) were successfully synthesized by sol‐gel method using Ti(OC4H9)4, CH3COOLi·2H2O, MgCl2·6H2O and Zr(NO3)3·6H2O as raw materials. The crystalline structure, morphology and electrochemical properties of the as‐prepared materials were characterized by XRD, SEM, cyclic voltammograms (CV), electrochemical impedance spectroscopy (EIS) and charge‐discharge cycling tests. The results show that the lattice parameters of the Mg‐Zr doped samples are slightly larger than that of the pure Li4Ti5O12, and Mg‐Zr doping does not change the basic Li4Ti5O12 structure. The rate capability of Li4?xMgxTi5?xZrxO12 (x=0.05, 0.1) electrodes is significantly improved due to the expansile Li+ diffusion channel and reduced charge transfer resistance. In this study, Li3.95Mg0.05Ti4.95Zr0.05O12 represented a relatively good rate capability and cycling stability, after 400 cycles at 10 C, the discharge capacity retained as 134.74 mAh·g?1 with capacity retention close to 100%. The excellent rate capability and good cycling performance make Li3.95Mg0.05Ti4.95Zr0.05O12 a promising anode material in lithium‐ion batteries.  相似文献   
68.
69.
70.
Torreyanoxane, a novel 3,4‐secoglutinane triterpenoid, was isolated from the pulp of Torreya nucifera. The structure was determined on the basis of spectroscopic methods.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号