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11.
Two new compounds from Zingiber officinale 总被引:1,自引:0,他引:1
Yu Zhao Qiao Feng Tao Rong Ping Zhang Chang Xin Zhou Hui Dou Shu Yun Shi Ye Cheng Xiao Lian Li Sun Su Zeng Ke Xin Huang Xiao Dong Zhang Xiao Kun Li 《中国化学快报》2007,18(10):1247-1249
A new cyclic diarylheptanoid,1,5-epoxy-3-hydroxy-1-(3-methoxy-4,5-dihydroxyphenyl)-7-(4-hydroxyphenyl)-heptane (1),as well as a new monoterpene,10-O-β-D-glucopyranosyl-hydroxy cineole (2) were isolated from the rhizomes of Zingiber officinale. The structures of compounds 1 and 2 were established based on their spectral data.In addition,the antioxidant activities of these compounds were also measured. 相似文献
12.
Henri J.-M. Dou Maria Ludwikow Parina Hassanaly Jacky Kister Jacques Metzger 《Journal of heterocyclic chemistry》1980,17(2):393-395
A general study of the chemical behavior of heterocyclic anions, dianions and dianionic reagents under phase transfer catalysis conditions allowed us to synthesize various heterocyclic compounds such as imidazo[2,1-b]thiazole and derivatives; imidazo[2,1-b]thiazine and imidazo[2,1-b]benzothiazepine. Reaction conditions e.g., catalyst, solvent, temperature, etc., are indicated. 相似文献
13.
Henri J.-M. Dou Parina Hassanaly Jacques Metzger 《Journal of heterocyclic chemistry》1977,14(2):321-323
Alkylation of ambident-anions derived from 2- and 4-pyridones yield by phase transfer catalysis, 80% of N-substitution and 20% of O-substitution. Change of salts, solvents, temperature and alkyl halide do not interfere very much with the N- and O-alkylation percentage of substitution. Overall yields range from 40 to 80% with primary or secondary alkyl halides. 相似文献
14.
以H2S和CS2作硫化剂,用PPS和TPDS方法研究了水煤气变换催化剂CoMoK/γ-Al2O3的硫化及反硫化过程。用H2S/H2硫化时,只发现H2S的消耗和H2O的生成,用CS2/H2硫化时,只发现H2S的消耗和H2O的生成。用CS2/H2硫化时,首先生成CO2,然后是CH4,H2O和H2S,TPG实验表明催化剂表面上积炭,造成催化剂和活性降低,但积炭在水煤变换反应进行了逐渐除法。TPDS实验表 相似文献
15.
Zhang Z Wang J Yuan H Gao Y Liu D Song L Xiang Y Zhao X Liu L Luo S Dou X Mou S Zhou W Xie S 《The journal of physical chemistry. B》2005,109(39):18352-18355
At a low temperature of 450 degrees C, ZnS nanoribbons have been synthesized on Si and KCl substrates by a simple chemical vapor deposition (CVD) method with a two-temperature-zone furnace. Zinc and sulfur powders are used as sources in the different temperature zones. X-ray diffraction (XRD), selected area electron diffraction (SEAD), and transmission electron microscopy (TEM) analysis show that the ZnS nanoribbons are the wurtzite structure, and there are two types-single-crystal and bicrystal nanoribbons. Photoluminescence (PL) spectrum shows that the spectrum mainly includes two parts: a purple emission band centering at about 390 nm and a blue emission band centering at about 445 nm with a weak green shoulder around 510 nm. 相似文献
16.
A full-wave solution is presented for the waveguide to microstrip transition. The exact Green's function of the transition is used in a moment method procedure. The behavior of the microstrip transition to a rectangular waveguide is studied with respect to the critical dimensions of the microstrip width, length and backshort location. The convergence characteristics of the full wave analysis method are investigated, along with the current distribution and the input impedance. Results given for the return loss is compared with measurements. 相似文献
17.
Hong-Shuo Li J. M. Cadogan Jian-Min Xu S. X. Dou H. K. Liu 《Hyperfine Interactions》1994,94(1):1929-1935
A study of the Nd-Fe-Ti phases at the Fe-rich end of the phase diagram has been carried out using57Fe Mössbauer spectroscopy, scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDAX). In particular,57Fe Mössbauer spectroscopy has been used to characterize the phases present in these samples. In addition to the two well-known 217 and 112 phases, twonovel phases have been identified, with compositions denoted by3–29 and9–94, which are closely linked to the orthorhombic ScFe6Ga6-type and the hexagonal TbCu7-type structures, respectively. The possible crystal structures of these new phases will be discussed in terms of the dumbbell substitution sequence in the CaCu5 structure. 相似文献
18.
Y. Lian H. Gao S. X. Dou H. Wang P. Ye Q. Guan J. Wang 《Applied physics. B, Lasers and optics》1994,59(6):655-658
Mechanism transitions of Self-Pumped Phase Conjugation (SPPC) with wavelength and doping concentration are observed in KTN:Fe (KTa1 –x
Nb
x
O3:Fe with
x
= 0.48) crystals. The SPPC mechanism in KTN: Fe (0.4 wt. %) crystal transforms from Stimulated Photorefractive Backscattering and Four-Wave Mixing (SPB-FWM) to cat (or total internal reflection) as the wavelength increases from 514.5 nm to 620 nm. SPPC at 514.5 nm is formed with the cat mechanism in a 0.2 wt. % doped KTN:Fe crystal, while with the SPB-FWM mechanism in a 0.4 wt. % doped one. These mechanism transitions are discussed with respect to the dependence of the backscattering gain coefficient of the crystals on wavelength and doping concentration. 相似文献
19.
20.
核酸切割试剂与寡聚核苷酸(ODN)偶联制得的人工核酸酶能在特定位点断裂DNA或RNA,为人工核酸酶的分子设计提供了一种新方法.本文综述了金属配合物-ODN识别切割试剂的偶联方式及其与靶分子的作用机制,并指出了今后的研究方向. 相似文献