Cyclohexanecarboxamide

The title compound, C₇H₁₃NO, forms R²₂(8) N—H...O hydrogen‐bonded dimers and C4 N—H...O‐linked chains, which are further stabilized by a C—H...O interaction. The combination of these interactions results in a hydrogen‐bonded network parallel to (100), with a motif that can be described by the secondary graph set R⁴₆(16). The existence of the same hydrogen‐bonding motif in 1‐phenylcyclopentanecarboxamide and 1‐(2‐bromophenyl)cyclohexanecarboxamide [Lemmerer & Michael (2008). CrystEngComm, 10 , 95–102 indicates that replacing the H atom on position 1 with a more bulky group does not necessarily disrupt the observed hydrogen‐bonding pattern. The presence of a C—H...O interaction to stabilize the R⁴₆(16) network does, however, seem to be required. In addition, the title compound is isomorphous with a previously published structure of cyclopentanecarboxamide [Winter et al. (1981). Acta Cryst. B 37 , 2183–2185].     

Acid–base and coordination properties of <Emphasis Type="Italic">Meso</Emphasis>-substituted porphyrins in nonaqueous solutions

Acid–base and coordination properties of alkyl and aryl meso-substituted porphyrins are studied spectrophotometrically in nonaqueous solutions. It is found that the nature of the substituent greatly affects the basicity of ligands for porphyrins characterized by a flat structure of macrocycle. The electronic effects of substituents have a much weaker influence on the kinetics of complexing. These effects could be due to the opposite orientation of some factors: an increase in the basicity and stability of the N–H bonds of porphyrin reaction centers. Dissociation constants pK _b of the cationic forms of meso-substituted derivatives of porphyrin are measured. The values of pK _b are in good agreement with classic concepts of the nature of substituents, particularly those indirectly included in the macrocycle through phenyl buffer rings.     

Molecular Dynamic Study for Chiral Discrimination of a -Phenylethylamine by Modified Cyclodextrin in Gas Chromatography

A molecular dynamic method in conjunction with a statistic test has been utilized to model chiral recognition of a -phenylethylamine on heptakis (2,6-di-O-butyl-3-O-butyryl)-b -cyclodextrin in gas chromatography. The modelling data correlated with the chromatographic elution order, and indicated that the preferred site of a -phenylethylamine is the interior of cavity.     

First experimental research of the bunch compressor at CAEPLI

Magnetic bunch compressor is one of the key technologies on the path to next generation accelerator driven facilities. In this paper we report the design principles and the first experimental research of the bunch compressor developed at Chinese Academy of Engineering Physics (CAEP). The length of the bunch after compressor is found to be about 0.7 ps (rms) and the peak current exceeds 500 A when operated in the optimized condition. The sensitivity of the bunch length on the phase of the acceleration field and magnetic field of the bunch compressor was also measured and analyzed.     

Synthesis,characterization, and star polymer assembly of boronic acid end‐functionalized polycaprolactone

Boronic acid end‐functionalized polycaprolactone (PCL) polymers were synthesized by ring‐opening polymerization using a pinacol boronate ester‐containing (Bpin) initiator. The polymerization provides access to boron‐terminated polymers (i.e. Bpin‐PCL‐OH) with narrow molecular weight distributions (PDI = 1.09). Postsynthetic manipulation of the polymer's terminal hydroxyl group by copper‐catalyzed azide‐alkyne cycloaddition chemistry provides a series of bis end‐functionalized polymers with significant structural diversity at the termini. Deprotection of the boronate ester end group was accomplished with an acidic solid phase DOWEX resin. The boronate ester deprotection methodology does not result in hydrolysis of the polymeric backbone. The boronic acid‐tipped polymers were converted into star polymer assemblies using thermal dehydration and ligand‐facilitated trimerization. Thermal dehydration of (HO)₂B‐PCL‐OAc to the corresponding boroxine‐based star polymer assembly was inefficient and lead to degradation products. Ligand‐facilitated trimerization using either pyridine or 7‐azaindole as the Lewis base was efficient and mild. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

Triphenylamine Derivatives Containing Nitronyl Nitroxide and Iminyl Nitroxide‐Syntheses,Characterization, Crystal Structures and Magnetic Studies

New triphenylamine derivatives 1, 2, 3, and 4 were synthesized and characterized by IR, FAB‐MS, EPR and EA. All of them displayed similar absorption and fluorescence spectra except compound 1, for which a possible explanation was proposed. Quasi‐reversible oxidation waves at about 0.76 V (vs. SCE) and 1.1 V for nitronyl nitroxide and iminyl nitroxide respectively as well as irreversible one at about 1.5 V for triphenylamine group were detected with cyclic voltammetry for compounds 1, 2, 3 and 4. Crystal structures of 2 and 4 were determined by X‐ray diffraction analysis. Their crystal data are as follows: for 2: monoclinic, C2/c, a = 1.69914 (4), b = 1.37435(5), c = 1.24621(5) ran, β= 106.553(2)°, V = 2.7896(2) nm³ Z = 4; for 4: orthorhombic, Pbca, a = 1.95970(6), b = 1.33096(4), c = 4.84691(14) nm, V = 12.6421(7) nm³, Z = 8. Magnetic studies indicated that all of them showed antiferromagnetic properties in solid state, but with strong intermolecular spin‐spin coupling as indicated by the relatively large values of 6, in particular for 4 (θ = ?12 K). Possible spin‐spin interaction mechanism was suggested based on the crystal structures of 2 and 4.     

毛细管电泳法测定人发中铝

用毛细管离子分析 (CIA)法 ,采用 10mmol·L- 1咪唑为背景电解质 ,4 0 %甲醇为选择性改性剂 ,在 pH 2 .5、分离电压为 2 5kV、柱温为 2 2℃的电泳条件下 ,采用间接紫外检测 (2 14nm ) ,在5min内测定了人发中铝 ,方法简便、快速、灵敏度高、重现性好、测定成本低