全文获取类型
收费全文 | 10367篇 |
免费 | 1902篇 |
国内免费 | 1244篇 |
专业分类
化学 | 7643篇 |
晶体学 | 65篇 |
力学 | 648篇 |
综合类 | 77篇 |
数学 | 1065篇 |
物理学 | 4015篇 |
出版年
2024年 | 26篇 |
2023年 | 273篇 |
2022年 | 323篇 |
2021年 | 396篇 |
2020年 | 478篇 |
2019年 | 418篇 |
2018年 | 339篇 |
2017年 | 291篇 |
2016年 | 498篇 |
2015年 | 432篇 |
2014年 | 526篇 |
2013年 | 758篇 |
2012年 | 954篇 |
2011年 | 973篇 |
2010年 | 642篇 |
2009年 | 631篇 |
2008年 | 708篇 |
2007年 | 620篇 |
2006年 | 545篇 |
2005年 | 475篇 |
2004年 | 364篇 |
2003年 | 324篇 |
2002年 | 272篇 |
2001年 | 214篇 |
2000年 | 213篇 |
1999年 | 253篇 |
1998年 | 213篇 |
1997年 | 191篇 |
1996年 | 205篇 |
1995年 | 175篇 |
1994年 | 142篇 |
1993年 | 124篇 |
1992年 | 102篇 |
1991年 | 74篇 |
1990年 | 84篇 |
1989年 | 56篇 |
1988年 | 48篇 |
1987年 | 44篇 |
1986年 | 29篇 |
1985年 | 28篇 |
1984年 | 14篇 |
1983年 | 9篇 |
1982年 | 13篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 2篇 |
1957年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 453 毫秒
951.
A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtC12) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, 1H-NMR, 13C-NMR, 29Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC). 相似文献
952.
谢帕莎 《广东微量元素科学》1999,6(7):24
总结了抢救急性心肌梗塞猝死的体会,包括:及早确诊及有效的心肺脑复苏、合理使用复苏药物和警惕老年性心梗的不典型性。 相似文献
953.
954.
955.
An alternative approach to synthesize pedamide,a key building block of pederin was described.Iodine-induced asymmetric heterocyclization was used as the key step to construct the skeleton,a tetrahydropyran ring with three chiral centers.Brown's asymmetric allylation and Lewis acid-mediated allylation were investigated to introduce chains and chiral alcohols.Sharpless dihydroxylation decorated the side chain.And high optically pure target was obtained by removing the epimers formed in these reactions on c... 相似文献
956.
A new approach to synthesize tolunitriles is reported. Tolunitriles can be prepared by selective ammoxidation of methylbenzyl
chlorides prepared by chloromethylation of toluene. The total yields can reach 83% and the selectivity of tolunitriles is
almost 100%. This approach provides a new path for preparing alkylbenzonitriles and other aromatic nitriles. 相似文献
957.
Electromagnetically induced phase grating controlled by spontaneous emission is studied. The results show that the diffraction efficiency of phase grating is strikingly enhanced due to the existence of spontaneously generated coherence (SGC), and the diffraction efficiency of 35% can be obtained in optimal SGC parameter case. Furthermore, at large SGC parameter, the high efficiency of phase grating can be maintained by the application of weak coupled and relatively strong probe fields, and choosing the proper length of atomic sample. At the same time, in such an atomic system, the SGC effect depends on incoherent pump. 相似文献
958.
959.
We have developed a novel alkaline anion exchange membrane derived from poly(ether‐imide) for improved ionic conductivity. The effects of several important parameters on the chloromethylation of the membrane were investigated. These parameters included reaction temperature, reaction time, concentration of chloromethylation agent, concentration of polymer, and the amount of catalyst. The quaternization of the synthesized chloromethylated polymer was studied as well. The results show that all the studied parameters exhibited significant impacts on chloromethylation. Among them, the concentration of the chloromethylation agent played a key role in increasing the chloromethyl functional group attachment onto the polymer. It was found that the gelation could be avoided if these reaction parameters were controlled. It was also found that using an appropriate quaternization approach could significantly improve the ionic conductivity and optimize the conductivity of the membrane even though the functional chloromethyl groups attached to the polymer are limited. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
960.
Jinming LiuXiaoru Zhao Libing DuanMengmeng Cao Huinan SunJifeng Shao Shuai ChenHaiyan Xie Xiao ChangChangle Chen 《Applied Surface Science》2011,257(23):10156-10160
Nb-doped TiO2 (TNO) thin films were prepared by sol-gel dip-coating method with Nb content in a wide range of 0-20 at.%. The prepared films were preheated at 400 °C and then undertaken by two different post-annealing processes: (a) three times vacuum annealing and (b) multi-round annealing. The designed multi-round annealing was shown to be an effective way to improve the conductive properties of the films, compared to the traditional vacuum annealing process. The minimum resistivity reached approximately 0.5 Ω cm with Nb doping concentration around 12 at.%, and the carrier density increased with Nb-doping concentration until the critical point of 12 at.%, which might be the optimal doping content for our TNO films prepared by sol-gel method. 相似文献