全文获取类型
收费全文 | 34399篇 |
免费 | 5639篇 |
国内免费 | 4999篇 |
专业分类
化学 | 25721篇 |
晶体学 | 393篇 |
力学 | 2198篇 |
综合类 | 327篇 |
数学 | 3796篇 |
物理学 | 12602篇 |
出版年
2024年 | 91篇 |
2023年 | 574篇 |
2022年 | 1100篇 |
2021年 | 1154篇 |
2020年 | 1251篇 |
2019年 | 1288篇 |
2018年 | 1039篇 |
2017年 | 1009篇 |
2016年 | 1518篇 |
2015年 | 1641篇 |
2014年 | 1929篇 |
2013年 | 2404篇 |
2012年 | 3034篇 |
2011年 | 3169篇 |
2010年 | 2153篇 |
2009年 | 2098篇 |
2008年 | 2413篇 |
2007年 | 2087篇 |
2006年 | 2054篇 |
2005年 | 1825篇 |
2004年 | 1460篇 |
2003年 | 1175篇 |
2002年 | 1234篇 |
2001年 | 1018篇 |
2000年 | 816篇 |
1999年 | 775篇 |
1998年 | 615篇 |
1997年 | 538篇 |
1996年 | 568篇 |
1995年 | 504篇 |
1994年 | 460篇 |
1993年 | 356篇 |
1992年 | 311篇 |
1991年 | 290篇 |
1990年 | 237篇 |
1989年 | 196篇 |
1988年 | 183篇 |
1987年 | 112篇 |
1986年 | 99篇 |
1985年 | 74篇 |
1984年 | 47篇 |
1983年 | 43篇 |
1982年 | 27篇 |
1981年 | 26篇 |
1980年 | 10篇 |
1979年 | 5篇 |
1977年 | 3篇 |
1966年 | 2篇 |
1957年 | 6篇 |
1936年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
12.
The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and 13C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (Tg) for the in situ blends, contrary to an increase of Tg with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007 相似文献
13.
Zi‐Cai Li Tzon‐Tzer Lu Hung‐Tsai Huang Alexander H.‐D. Cheng 《Numerical Methods for Partial Differential Equations》2007,23(1):93-144
In this article we survey the Trefftz method (TM), the collocation method (CM), and the collocation Trefftz method (CTM). We also review the coupling techniques for the interzonal conditions, which include the indirect Trefftz method, the original Trefftz method, the penalty plus hybrid Trefftz method, and the direct Trefftz method. Other boundary methods are also briefly described. Key issues in these algorithms, including the error analysis, are addressed. New numerical results are reported. Comparisons among TMs and other numerical methods are made. It is concluded that the CTM is the simplest algorithm and provides the most accurate solution with the best numerical stability. © 2006 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq, 2007 相似文献
14.
The following results are proved in this paper. Let G be a 2k-edge-connected eulerian graph. (i) For every set {e1, e2, ?, e2k+1} ? E(G) there is an eulerian trail T of the form e1, e2, ?, e2k+1, ?. (ii) For every set E* = {e1, e2, ?, ek} ? E(G) there is an eulerian trail T = e1, ?, e2, ?, ek, ? in which the elements of E* are traversed in accordance with a prescribed orientation. © 1995 John Wiley & Sons, Inc. 相似文献
15.
In this paper, we discuss the local and global existence ofweak solutions for some hyperbolicparabolic systems modellingchemotaxis. 相似文献
16.
We report viscometric data collected in a Couette rheometry on dilute, single‐solvent polystyrene (PS)/dioctyl phthalate (DOP) solutions over a variety of polymer molecular weights (5.5 × 105 ≤ Mw ≤ 3.0 × 106 Da) and system temperatures (288 K ≤ T ≤ 318 K). In view of the essential viscometric features, the current data may be classified into three categories: The first concerns all the investigated solutions at low shear rates, where the solution properties are found to agree excellently with the Zimm model predictions. The second includes all sample solutions, except for high‐molecular‐weight PS samples (Mw ≥ 2.0 × 106 Da), where excellent time–temperature superposition is observed for the steady‐state polymer viscosity at constant polymer molecular weights. No similar superposition applies at a constant temperature but varied polymer molecular weights, however. The third appears to be characteristic of dilute high‐molecular‐weight polymer solutions, for which the effects of temperature on the viscosity curve are further complicated at high shear rates. The implications concerning the relative importance of hydrodynamic interactions, segmental interactions, and chain extensibility with increasing polymer molecular weight, system temperature, and shear rate are discussed. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 787–794, 2006 相似文献
17.
本文主要论证了在不完全市场条件下带风险指数的金融均衡的存在性,并揭示其均衡结构的特征.本文中建立的模型是一、二期货币投入产出金融经济且具有可微的资产结构,这一模型包括了许多具有特殊资产结构的均衡模型,如实资产结构、虚资产结构、恒秩资产结构的均衡模型.因此本文的这一模型具有广泛的应用前景和实用价值.接着给出了本文的金融均衡的存在性定理,再借助微分拓扑给出它的证明过程,这一证明过程较之以前证明均衡存在性的经典方法(如Duffie,D&W.Shfer(1985)的方法)要简便得多.同时也应注意到本文的这一结论既适用于资产市场下会随机风险因素的情形,也适用于商品空间为无限维的情形,除此之外,还给出了怎样判别资产结构是否属于T类的判别法,为检验均衡存在性提供了更为便利的途径.最后,本文论证了在金融市场里,尽管由于稀缺性的存在,从而导致均衡分配的多样化,然而均衡分配集却形成了一光滑子流,但该流形的维数与稀缺性有关.换句话说,尽管市场是不完全的,但均市分配不确定性的反却是可比的.如此使得人们对均衡资产结构的认识更进一步. 相似文献
18.
Li Changjun; Li Zheng; Evans David J.; Zhang Tie 《IMA Journal of Numerical Analysis》2003,23(4):581-592
Golub et al. (2001, BIT, 41, 7185) gave a generalizedsuccessive over-relaxation method for the augmented systems.In this paper, the connection between the SOR-like method andthe preconditioned conjugate gradient (PCG) method for the augmentedsystems is investigated. It is shown that the PCG method isat least as accurate (fast) as the SOR-like method. Numericalexamples demonstrate that the PCG method is much faster thanthe SOR-like method. 相似文献
19.
Yonggang Shangguan Li Zhao Liyang Tao Qiang Zheng 《Journal of Polymer Science.Polymer Physics》2007,45(13):1704-1712
The effects of preparation method, composition, and thermal condition on formation of β‐iPP in isotactic polypropylene/ethylene–propylene rubber (iPP/EPR) blends were studied using modulated differential scanning calorimeter (MDSC), wide angle X‐ray diffraction (WAXD), and phase contrast microscopy (PCM). It was found that the α‐iPP and β‐iPP can simultaneity form in the melt‐blended samples, whereas only α‐iPP exists in the solution‐blended samples. The results show that the formation of β‐iPP in the melt‐blended samples is related to the crystallization temperature and the β‐iPP generally diminishes and finally vanishes when the crystallization temperature moves far from 125 °C. The phenomena that the lower critical temperature of β‐iPP in iPP/EPR obviously increases to 114 °C and the upper critical temperature decreases to 134 °C indicate the narrowing of temperature interval, facilitating the formation of β‐iPP in iPP/EPR. Furthermore, it was found that the amount of β‐iPP in melt‐blended iPP/EPR samples is dependent on the composition and the maximum amount of β‐iPP formed when the composition of iPP/EPR blends is 85:15 in weight. The results through examining the effect of annealing for iPP/EPR samples at melt state indicate that this annealing may eliminate the susceptibility to β‐crystallization of iPP. However, only α‐iPP can be observed in solution‐blended samples subjected to annealing for different time. The PCM images demonstrate that an obvious phase‐separation happens in both melt‐blended and solution‐blended iPP/EPR samples, implying that compared with the disperse degree of EPR in iPP, the preparation method plays a dominant role in formation of β‐iPP. It is suggested that the origin of formation of β‐iPP results from the thermomechanical history of the EPR component in iPP/EPR. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1704–1712, 2007 相似文献
20.
In this paper, a projection method is presented for solving the flow problems in domains with moving boundaries. In order to track the movement of the domain boundaries, arbitrary‐Lagrangian–Eulerian (ALE) co‐ordinates are used. The unsteady incompressible Navier–Stokes equations on the ALE co‐ordinates are solved by using a projection method developed in this paper. This projection method is based on the Bell's Godunov‐projection method. However, substantial changes are made so that this algorithm is capable of solving the ALE form of incompressible Navier–Stokes equations. Multi‐block structured grids are used to discretize the flow domains. The grid velocity is not explicitly computed; instead the volume change is used to account for the effect of grid movement. A new method is also proposed to compute the freestream capturing metrics so that the geometric conservation law (GCL) can be satisfied exactly in this algorithm. This projection method is also parallelized so that the state of the art high performance computers can be used to match the computation cost associated with the moving grid calculations. Several test cases are solved to verify the performance of this moving‐grid projection method. Copyright © 2004 John Wiley Sons, Ltd. 相似文献