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61.
The electronic and energetic properties of bimetallic surfaces Pt/Ni(111) and Pt/Co(111) are examined using the FP-LAPW (Full-PotentialLinearized Augmented Plane Wave) method by means of spin-polarized and non-polarized calculations. We present both the results of the shifts in the d-band centers when one metal (Pt) is pseudomorfically deposited on another with smaller lattice constant (Ni, Co) and those corresponding to the surface and adhesion energies. The surface is modeled by a seven layer slab separated in z direction by a vacuum region of six substrate layers. The results obtained for pure Ni, Co and Pt surfaces are presented in order to compare with experimental and theoretical data reported in the literature 相似文献
62.
Antonio Salmerón-García Emilio Lopez-Lopez Eva Román José Cabeza Natalia Navas Luís Fermín Capitán-Vallvey 《Chromatographia》2008,67(9-10):767-772
A novel LC method was applied to enhance the peak resolution of two ecdysteroids: 20-hydroxyecdysone and its 3-epimer. An isocratic solvent system of methanol–water (6:4, v/v) was used on a C18 column, and 100 μL of water was injected during the development in such a manner that the eluted solvent peak appeared exactly between the two overlapping peaks. This resulted in the increased retardation of the later-eluted peak, and in a good separation of the two compounds within 4.5 min. 相似文献
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67.
Marisa Scrocco 《Journal of Electron Spectroscopy and Related Phenomena》1980,19(3):311-319
The satellite structure in the X-ray photoelectron spectra of nickel halides has been measured. The satellites found in the photoelectron spectra of Ni2+ 3p and 2p subshells have two common sources: multiples splitting and multi-electron excitations. The experimental spectra are compared with theoretical results on multiples splitting and with calculations of band structure. 相似文献
68.
We introduce the concept of s–formal minimal model as an extension of formality. We prove that any orientable compact manifold M, of dimension 2n or (2n−1), is formal if and only if M is (n−1)–formal. The formality and the hard Lefschetz property are studied for the Donaldson submanifolds of symplectic manifolds
constructed in [13]. This study permits us to show an example of a Donaldson symplectic submanifold of dimension eight which
is formal simply connected and does not satisfy the hard Lefschetz theorem.
An erratum to this article is available at . 相似文献
69.
Ohne Zusammenfassung 相似文献
70.
Marina Biagini Cingi Anna Maria Manotti Lanfredi Antonio Tiripicchio Marisa Tiripicchio Camellini 《Transition Metal Chemistry》1979,4(4):221-224
Summary The crystal structure of CuCl2(C7H8N4O2)(H2O)2 has been determined from diffractometer data by Patterson and Fourier methods and refined by full-matrix least-squares to R=0.067 for 2123 observed reflections. Unit cell constants are:a=9.930(8),b=9.987(8),c=7.483(6) Å,=123.2(1),=94.5(1),= 83.9(1)°. The space group is P¯1 withZ=2. The structure consists of diaquadichlorotheophyllinecopper(II) complexes linked by hydrogen bonds. The coordination polyhedron of copper is a square pyramid whose base, severely tetrahedrally distorted, is formed by a water molecule [Cu-Ow=2.025(7) Å], two chlorines [Cu-Cl=2.273(4), 2.296(4) Å] and an imidazole nitrogen [Cu-N=1.983(9) Å] from the theophylline ligand. A second water molecule is at the apex of the pyramid [Cu-Ow=2.292(7) Å]. Coordination is completed to a distorted octahedral one by a long Cu ... O=3.164(7) Å contact involving the exocyclic oxygen at C6 of the theophylline ligand. 相似文献