Efficient Solution Concepts and Their Relations in Stochastic Multiobjective Programming

In this work, different concepts of efficient solutions to problems of stochastic multiple-objective programming are analyzed. We center our interest on problems in which some of the objective functions depend on random parameters. The existence of different concepts of efficiency for one single stochastic problem, such as expected-value efficiency, minimum-risk efficiency, etc., raises the question of their quality. Starting from this idea, we establish some relationships between the different concepts. Our study enables us to determine what type of efficient solutions are obtained by each of these concepts.     

Ion-exchange properties of P2-NaxMnO2: evidence of the retention of the layer structure based on chemical reactivity data and electrochemical measurements of lithium cells

The ion-exchange properties of two P2-type layered Na_xMnO₂ bronzes (x=0.6, 0.75) with a differential microstructure were studied in LiCF₃SO₃ solutions in acetonitrile under ambient conditions. Na⁺ ions are readily exchanged with Li⁺, but the reaction causes a significant loss of crystallinity that results in some amorphization. The feasibility of the process increases with increasing structural disorder in the parent compound; conversion, however, is incomplete. The ability of the exchanged material to intercalate water in the air is consistent with the formation of an Li-Mn-O compound that retains the layered framework. Also, the electrochemical data obtained for this material as cathode in lithium cells are consistent with retention of the layer structure and exclude a potential spinel transition due to the ion-exchange reaction. However, the cycling properties of cells made from these layered compounds are quite modest, probably because of the strong structural disorder induced by the lithium reaction.     

Plasma chemistry of NO in complex gas mixtures excited with a surfatron launcher

The plasma chemistry of NO has been investigated in gas mixtures with oxygen and/or hydrocarbon and Ar as carrier gas. Surface wave discharges operating at microwave frequencies have been used for this study. The different plasma reactions have been analyzed for a pressure range between 30 and 75 Torr. Differences in product concentration and/or reaction yields smaller than 10% were found as a function of this parameter. The following gas mixtures have been considered for investigation: Ar/NO, Ar/NO/O2, Ar/NO/CH4, Ar/CH4/O2, Ar/NO/CH4/O2. It is found that NO decomposes into N2 and O2, whereas other products such as CO, H2, and H2O are also formed when CH4 and O2 are present in the reaction mixture. Depending on the working conditions, other minority products such as HCN, CO2, and C2 or higher hydrocarbons have been also detected. The reaction of an Ar/NO plasma with deposits of solid carbon has also been studied. The experiments have provided useful information with respect to the possible removal of soot particles by this type of plasma. It has been shown that carbon deposits are progressively burned off by interaction with the plasma, and practically 100% decomposition of NO was found. Plasma intermediate species have been studied by optical emission spectroscopy (OES). Bands and/or peaks due to N2*, NO*, OH*, C2*, CN*, CH*, or H* were detected with different relative intensities depending on the gas mixture. From the analysis of both the reaction products and efficiency and the type of intermediate species detected by OES, different plasma reactions and processes are proposed to describe the plasma chemistry of NO in each particular mixture of gases. The results obtained provide interesting insights about the plasma removal of NO in real gas exhausts.     

Selective fluorescence sensing of Li+ in an aqueous environment by a ferrocene-anthracene-linked dyad

A new 1-(9-anthryl)-4-ferrocenyl-2-aza-1,3-butadiene showing selective fluorescence enhancement upon binding to lithium cations over other alkaline cations in aqueous environment has been conveniently synthesized and characterized. [structure: see text]     

Molecular mechanics calculation on the hydroxyl stretching frequency in saturated alcohols Part II. Cyclohexanols

The applicability of a previously developed MM2/CNDO model, based on five saturated alcohols, for the calculation of ν_OH gas frequencies has been tested for the rotamers of several cyclohexanols in both the equatorial and the axial conformation. Experimental ν_OH values are assigned to the various OH rotamers present. Reasonable agreement is achieved between calculated and experimental data for ν_OH frequencies and rotamer populations. The decrease of the observed ν_OH frequencies upon substitution of an -hydrogen vicinal to the OH proton by a methyl group, is properly described in the MM2/CNDO scheme by the implemented electrostatic interactions between calculated CNDO/2 atomic charges. The shifts of ν_OH observed when the substitution concerns β-hydrogens are in general less well predicted. In order to improve these results an additional interaction is required.     

Measuring clock jumps using pulsar timing

In this paper,we investigate the statistical signal-processing algorithm to measure the instant local clock jump from the timing data of multiple pulsars.Our algorithm is based on the framework of Bayesian statistics.In order to make the Bayesian algorithm applicable with limited computational resources,we dedicated our efforts to the analytic marginalization of irrelevant parameters.We found that the widely used parameter for pulsar timing systematics,the"Efac"parameter,can be analytically marginalized.This reduces the Gaussian likelihood to a function very similar to the Student’s t-distribution.Our iterative method to solve the maximum likelihood estimator is also explained in the paper.Using pulsar timing data from the Yunnan Kunming 40-m radio telescope,we demonstrate the application of the method,where 80-ns level precision for the clock jump can be achieved.Such a precision is comparable to that of current commercial time transferring service using satellites.We expect that the current method could help developing the autonomous pulsar time scale.