适用于风向变化条件的毒气扩散模型研究

本文研究基于经典高斯扩散模式但适用于风向变化条件的毒气扩散模型。经典高斯扩散模式，例如高斯烟云模式和高斯烟团模式，成立的前提条件是在扩散过程中风向保持不变。但在实际应用中风向却常常是变化的。本文在经典高斯扩散模式的基础上引入坐标变换的数学方法，建立了一个能够应对风向变化条件的毒气扩散模型。该模型包括网格化预处理、高斯模式选择和坐标变化三个主要环节。文中详细阐述了模型的主要思想和核心算法。最后简要讨论了模型的程序设计和实际应用。     

Ring‐opening polymerization of 1,4‐dioxan‐2‐one initiated by lanthanum isopropoxide in bulk

Lanthanum isopropoxide (La(OiPr)₃) has been synthesized and employed for ring‐opening polymerization of 1,4‐dioxan‐2‐one in bulk as a single‐component initiator. The influences of reaction conditions such as initiator concentration, reaction time, and reaction temperature on the polymerization were investigated. The kinetics indicated that the polymerization is first‐order with respect to the monomer concentration. The Mechanistic investigations according to ¹H NMR spectrum analysis demonstrated that the polymerization of PDO proceeded through a coordination‐insertion mechanism with a rupture of the acyl‐oxygen bond of the monomer rather than the alkyl‐oxygen bond cleavage. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5214–5222, 2008     

Novel four-hydrogen-bond assembled oligoamide dimer with pyrazoline moieties and its photoluminescent properties

In this paper,the synthesis and characterization of a triarylpyrazoline modified four-H-bonded molecular duplex are described. Its molecular structure has been confirmed by ~1H NMR and ESI-MS.The duplex emits strong pure blue light peaking at 448 and 452 nm under UV photoexcitation in solution and solid state,respectively,and its relative photoluminescence quantum efficiency in solution is determined as 0.778 using quinine sulfate as reference.In concentration of>40 mmol/L,the duplex can gelate DMSO, and...     

Tadpole‐shaped amphiphilic copolymers prepared via RAFT polymerization and click reaction

The tadpole‐shaped amphiphilic copolymers with cyclic polystyrene as the head and a linear poly(N‐isopropylacrylamide) as the tail have been successfully synthesized by combination of reversible addition‐fragmentation chain transfer (RAFT) polymerization and “click” reaction. The synthesis involves two main steps: (1) preparation of a linear acetylene‐terminated PNIPAAM‐b‐PS with a side azido group anchored at the junction between two blocks; (2) intramolecular cyclization reaction to produce the cyclic PS block using “click” chemistry under high dilution. The structures, molecular weights, and molecular weight distributions of the resulted intermediates and the target polymers were characterized by their ¹H NMR, FTIR, and gel permeation chromatography. The difference of surface property between tadpole‐shaped polymer and its linear precursor was observed, and the water contact angles on the former surface are larger than that of the latter surface. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2390–2401, 2008     

单调递增分形函数上、下界的估计

Mass distribution principle is one of important tools in studying Hausdorff dimension and Hausdorff measure.In this paper we will give a numerical approximate method of upper bound and lower bound of mass distribution function f(x)(it is a monotone increasing fractal function)and its some applications.     

Ytterbium triflate hydrate catalyzed Michael addition and cyclocondensation of α,β-unsaturated ketones with active methylene compounds

Catalyzed by ytterbium(Ⅲ) triflate hydrate [Yb(OTf)3.xH2O], the Michael addition and cycloeondensation of α,β-unsaturated ketones with active methylene compounds to afford the 1,4-adducts and benzo[b]pyran derivatives, respectively were studied.     

数据采集控制器ADAM—5510和上位机通信的实现

介绍了在VISUAL BASIC环境中研华公司的ADAM-5510数据采集控制器和上位机通信实现的方法。     

Preparation and Recognition Study on the Peptides in Aqueous Media of Poly(pyridine derivative‐co‐acrylamide)

Three copolymers (bearing metal ion coordinated sites) P1 , P2 and P3 were synthesized and their recognition behavior on predetermined peptide sequences was studied by isothermal titration calorimetry.     

PS-TEPA树脂合成及其吸附蛋白质性质

本文以四乙烯五胺与氯乙酰化聚苯乙烯树脂反应合成PS-TEPA树脂。考察了温度、时间、胺用量以及溶剂等合成条件。研究了PS-TEPA树脂吸附牛血清蛋白的条件,包括吸附温度、吸附时间以及蛋白质的用量。结果发现,当以二氯甲烷作分散剂,合成温度为85℃,反应时间为12 h,投料比为32g四乙烯五胺/g树脂条件下,树脂接枝的增重率和氮元素含量最大;当吸附温度为30℃,吸附时间为12 h,牛血清蛋白溶液的浓度为2.0 mg/mL时,PS-TEPA树脂的蛋白吸附量达到80mg/g树脂,吸附回收率为84%。