基于Franz-Keldysh效应的倏逝波锗硅电吸收调制器设计

本文设计了一种基于Franz-Keldysh (FK) 效应的GeSi电吸收调制器. 调制器集成了脊形硅单模波导. 光由脊形硅波导以倏逝波形式耦合进锗硅吸收层. 在硅基锗二极管FK效应实验测试的基础上, 有源区调制层锗硅中的硅组分设计为1.19%, 从而使得器件工作在C (1528–1560 nm) 波段. 模拟结果显示该调制器的3 dB带宽可达64 GHz, 消光比为8.8 dB, 而插损仅为2.7 dB. 关键词： 锗硅 调制器 电光集成     

ZnAl2O4：Tb3+荧光粉的合成、结构及其光学性能研究

通过溶胶-凝胶法制备出不同Tb³⁺掺杂浓度和不同二次煅烧温度下的ZnAl₂O₄:Tb³⁺荧光粉, 并利用X射线衍射(XRD)和荧光光谱等对样品进行了表征。由XRD结果可知,当Tb³⁺掺杂的摩尔分数不大于9%,二次煅烧温度在600℃以上时,所得粉体为结晶性良好的尖晶石相。在紫外光激发下,ZnAl₂O₄:Tb³⁺荧光粉的发射光谱由位于488 nm(⁵D₄→⁷F₆)、542 nm(⁵D₄→⁷F₅)、587 nm(⁵D₄→⁷F₄ )和621.5 nm(⁵D₄→⁷F₃)的4个发射峰组成。研究发现,Tb³⁺的掺杂浓度和二次煅烧温度对样品发光强度有着重要影响,当Tb³⁺的摩尔分数为5%,二次煅烧温度为900℃时,ZnAl₂O₄:Tb³⁺荧光粉的发光最强,继续增加Tb³⁺掺杂浓度或提高煅烧温度,分别会出现浓度猝灭和温度猝灭现象。     

强流ECR离子源引出系统研究

为了提高强流ECR 离子源的引出束流品质,分别设计了1# 和2# 引出系统,利用束流引出模拟软件PBGUNS 对1# 和2# 引出系统进行了质子束流引出与传输的模拟计算,结合实际测得的发射度数据分析引出系统,发现2# 引出系统比1# 引出系统引出束流品质高。对ECR 离子源引出系统的电势等位线分布等参数引起的球差进行了简单数学推导及MATLAB 绘图,并结合1# 和2# 引出系统束流相图模拟结果证明了球差会使引出束流品质有效发射度增长,通过适当加大电极孔径可改善束流聚焦情况,得到了束流光学聚焦较好的束流引出系统设计。To improve the quality of extracted ion beam from a high current ECR ion source, 1# and 2# extraction systems were designed and tested. The PBGUNS code was used to simulate the 1# and 2# extraction systems of proton ion beam. The emittance measurement results with the two different extraction systems were compared and analyzed with the simulation, the conclusion that more high quality beam extracted from 2# system than 1# system was got. The formula derivation of ECR ion source extraction system spherical aberration and MATLAB drawing was done by the analyzing on the distribution of extraction field equipotentials, effective emittance increasing caused by spherical berration was proved by 1# and 2# extraction systems beam phase space simulation result, beam focusing would be improved if electrode hole size increasing appropriately and a general concept on good optics focusing of ion beam extraction system was proposed finally.     

Formation of hydrophobic coating on PMMA surface using unipolar nanosecond-pulse DBD in atmospheric air

Dielectric barrier discharge (DBD) can modify the material surface and result in complicated physical and chemical reactions to improve the surface hydrophilicity, which is proved to be an effective method for surface modification. Compared with the traditional ac-excitation DBD, the DBD using unipolar pulses can avoid local overheat of microdischarges and can improve discharge efficiency under some conditions. In this paper, DBD excited by repetitive unipolar nanosecond generator was used to improve the hydrophobicity of Plexiglass (PMMA) surface by means of the interaction between air plasma and silicone oil. The output voltage had a rise time of 40 ns and a full width at half maximum of about 70 ns. The surface hydrophobicity of the PMMA, before and after the surface modification, was evaluated via the contact angle measurement under different experimental conditions. The values of the contact angle shown in this paper were the average of eight measured values, and the standard deviations were also calculated. The surface energy including polar and dispersion components was calculated using the measured average contact angles of distilled water and polyethyleneglycol. The results showed that, as the increase of the discharge voltage, the contact angle increased but the surface energy decreased. With the increase of treatment time, the water contact angle of the modified surface increased at the beginning, and it would reach to a maximum at 7.5 min treatment, and then decreased. The effect of pulse frequency on the modification results was different at various treatment times. In addition, the possible physical and chemical reaction among the DBD plasma, silicone oil and the PMMA surface was discussed.     

Calculation on the CO2 influences on the structure,stability of (MgO)m (m = 1–6) clusters

ABSTRACT

The concentration of carbon dioxide (CO₂) has a significant influence on the morphology of thermal decomposition products of magnesite. So, structures, stabilities and adsorption mechanisms of (MgO)_m (m?=?1–6) clusters by one or two CO₂ molecules were calculated by the GGA-PW91 method. The results show that the stability of the considered clusters is (MgO)_m(CO₂)₂ clusters > (MgO)_m(CO₂) clusters > (MgO)_m clusters by the average binding energy. Certain low-lying isomers of (MgO)_m(CO₂) and (MgO)_m(CO₂)₂ clusters which have an isolated O atom are deviating from the cluster center which possess higher kinetic activity. (MgO)_m clusters prefer to adsorb a CO₂ molecule, while (MgO)₃(CO₂) clusters prefer to adsorb a CO₂ molecule rather than the neighbors. Magnesite is difficult to transit to (MgCO₃)₂ clusters at room temperature. However, magnesite will spontaneously transit to (MgO)₂ clusters and further transit to MgO crystal which need to adsorb more energy at 700?K.     

双核铂(Ⅱ)配合物[{Pt(H2O)2I}μ-OOC-COO-{Pt(H2O)2I}]对人体癌细胞的作用

采用MTT和SRB法研究了双核铂(Ⅱ)配合物[{Pt(H2O)2I}μ-OOC-COO-{Pt(H2O)2I}](BPI)对人体癌细胞的增殖抑制作用,又通过流式细胞法、Giemsa染色法、等离子体质谱法研究了它的抗癌机制.实验结果表明:在10 μmol·L-1浓度下,该配合物对HL-60, BGC-823,Bel-7402,KB,Hela,HCT-8,MCF-7和EJ 8种肿瘤细胞都表现出有较高的活性,对HL-60、BGC-823和Bel-7402 3种肿瘤细胞的抑制率都在70%以上,它能阻止HL-60细胞G2+M→G1期的进行;对HL-60细胞的凋亡诱导作用不明显;在相同浓度情况下其与HL-60细胞的DNA键合量大于顺铂.     

The High Energy X-ray telescope (HE) onboard the Insight-HXMT astronomy satellite

The Insight-Hard X-ray Modulation Telescope(Insight-HXMT) is a broadband X-ray and γ-ray(1-3000 ke V) astronomy satellite. One of its three main telescopes is the High Energy X-ray telescope(HE). The main detector plane of HE comprises 18 Na I(Tl)/Cs I(Na) phoswich detectors, where Na I(Tl) is used as the primary detector to measure ~ 20-250 ke V photons incident from the field of view(FOV) defined by collimators, and Cs I(Na) is used as the active shielding detector to Na I(Tl) by pulse shape discrimination. Additionally, Cs I(Na) is used as an omnidirectional γ-ray monitor. The HE collimators have a diverse FOV,i.e. 1.1°×5.7°(15 units), 5.7°×5.7°(2 units), and blocked(1 unit). Therefore, the combined FOV of HE is approximately5.7°×5.7°. Each HE detector has a diameter of 190 mm resulting in a total geometrical area of approximately 5100 cm2, and the energy resolution is ~15% at 60 ke V. For each recorded X-ray event by HE, the timing accuracy is less than 10 μs and the deadtime is less than 10 μs. HE is used for observing spectra and temporal variability of X-ray sources in the 20-250 ke V band either by pointing observations for known sources or scanning observations to unveil new sources. Additionally, HE is used for monitoring the γ-ray burst in 0.2-3 Me V band. This paper not only presents the design and performance of HE instruments but also reports results of the on-ground calibration experiments.     

激光束散角复合控制技术

为了降低部分相干光光学系统设计的复杂度及成本,增加部分相干光应用的便捷性,提出了一种液晶空间光调制器的激光相干度及束散角复合控制方法。首先介绍了对激光光束进行相干度和束散角复合控制的基本理论和方法;然后分别设置了相干度和束散角检测实验,检测了本方法所调制激光光束的相干度和束散角的准确性。实验结果表明,采用液晶空间光调制器生成相干度为0.9 mm、束散角为7.5 mrad,以及相干度为1.5 mm、束散角为3.8 mrad的部分相干光束,其相干度与理论值相比误差在5%以内,其相干度均方根误差分别为0.027386和0.031314,峰谷值分别为0.084 658和0.089 103;其束散角与理论值相比误差在5%以内,其束散角均方根误差分别为0.022 478和0.023 186,峰谷值分别为0.081 201和0.092 130。可见,该方法可以实现高精度的相干度及束散角复合控制。     

基于拉曼光谱鉴定黑色签字笔笔迹的种类与书写时间

黑色签字笔字迹种类与书写时间的鉴定一直是国内外法庭科学研究领域的热点问题。基于拉曼光谱法的分辨率高、稳定性好、效率高以及无损检测等优点,对收集的16种品牌或牌号的黑色签字笔字迹样本进行测试。完成同一品牌或牌号同一时间在不同存储条件(暗室和光照)与不同纸张本底(复印纸和笔记本)字迹样本的制备。将样本字迹剪裁,双面胶固定在载玻片上,放入储存箱内避光保存,间隔一段时间对样品进行测试,测试工作共持续1年,形成图谱数据库。在考察实验条件如测量点、激光功率及共焦类型等因素影响的基础上,筛选出最佳条件。在此条件基础上,检测黑色签字笔在不同书写时间、储存环境、纸张本底等条件下的字迹样本。实验结果表明:(1)存储条件(暗室和光照)、纸张本底(复印纸和笔记本)等不同条件下,同种黑色签字笔字迹的拉曼位移相同,重复性好,受水和纸张等本底的干扰较小。(2)根据拉曼位移的差异可将16种黑色签字笔分成5类。(3)以2#样本为例, 1 140 cm^-1处拉曼光谱特征峰,归属为酯类化合物的C-O伸缩振动ν(CO)。酯类化合物的含量随着时间延长而不断减少,因此随着书写时间越久远,特征峰的相对强度越大(8→1)。通过拟合后计算出相对面积数值I,样本书写时间越早,I值越大,反之I值越小。研究结果可用于快速、准确、无损判定黑色签字笔字迹的种类和推断其相对书写时间。