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51.
Hwang SH Moorefield CN Wang P Jeong KU Cheng SZ Kotta KK Newkome GR 《Journal of the American Chemical Society》2006,128(23):7505-7509
CdS nanoparticles on the surface of single-walled carbon nanotubes (SWNTs) were templated and stabilized through the initial attachment of 1 --> 3 C-branched amide-based dendrons and were both photophysically and morphologically characterized. The CdS clusters were shown to be ca. 1.4 nm in diameter as calculated from their optical absorption spectra and exhibited reduced fluorescence emission intensity at 434 nm compared to that of CdS quantum dots stabilized by untethered dendrons due to partial emission quenching by the SWNT. Unchanged UV absorption behavior of these materials indicated that they are stable > 90 days at 25 degrees C. 相似文献
52.
Newkome GR Yoo KS Kim HJ Moorefield CN 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(14):3367-3374
Routes for the syntheses of isomeric, zwitterionic, bisterpyridine-Ru(II)-based macromolecules are described. Access to these novel architectures is facilitated by the construction of terpyridine-modified, 1-->3 C-branched, ester-terminated building blocks. Constitutional isomers result from the interchangable placement of methyl and tert-butyl ester groups on both the branched framework near the Ru(II) centers and the termini of the branched construct. Water solubility is imparted to each isomer through selective transformation of the tert-butyl esters to their corresponding carboxylates. Along with the standard characterization techniques, electrochemical and spectroscopic data also support the structural formation. 相似文献
53.
Reversible Self‐Assembly of Terpyridine‐Functionalized Graphene Oxide for Energy Conversion 下载免费PDF全文
Shungang Song Dr. Yuhua Xue Prof. Lianfang Feng Hany Elbatal Dr. Pingshan Wang Dr. Charles N. Moorefield Prof. George R. Newkome Prof. Liming Dai 《Angewandte Chemie (International ed. in English)》2014,53(5):1415-1419
Terpyridine‐functionalized graphene oxides were prepared for self‐assembly into 3D architectures with various metal ions (e.g., Fe, Ru). The resulting electrode materials showed significantly improved electroactivities for efficient energy conversion and storage. They showed promise for application in the oxygen reduction reaction (ORR), photocurrent generation, and supercapacitance. 相似文献
54.
Wang JL Li X Lu X Chan YT Moorefield CN Wesdemiotis C Newkome GR 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(17):4830-4838
The synthesis, purification, structural analysis, and photophysical properties of a series of five-, six-, and seven-sided Fe(II) macrocycles and the corresponding hexameric Cd(II) macrocycle, all prepared by self-assembly of a 120° bis(terpyridine) ligand modified with first- and second-generation 1→3 C-branched dendrons, are reported. All metallomacrocycles were fully characterized by (1)H and (13)C NMR spectroscopy, traveling-wave ion-mobility mass spectrometry (TWIM MS), molecular modeling, UV/Vis absorption spectroscopy, photoluminescence, and cyclic voltammetry. A gradual increase of the collision cross sections of the Fe(II) metallomacrocycles was observed with a successive increase of the number and molecular size of the ligands. The combination of ion-mobility mass spectrometry and NMR techniques unveils structural features that agree well with calculations. Extinction coefficients and emission are significantly modulated by increasing the ring size and changing the metal ion center from Fe(II) to Cd(II) . 相似文献
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Newkome GR Cho TJ Moorefield CN Cush R Russo PS Godínez LA Saunders MJ Mohapatra P 《Chemistry (Weinheim an der Bergstrasse, Germany)》2002,8(13):2946-2954
Methods for the self-assembly, as well as directed construction, of hexaruthenium metallomacrocycles employing bisterpyridine building blocks are described. Self-assembly is effected by a combination of equimolar mixtures of bismetalated and nonmetalated bis(terpyridinyl) monomers each possessing the requisite planar, 60 degrees, terpyridine-metal-terpyridine connectivity. Stepwise synthesis of the identical hexamer is also discussed and used to aid in verification of the self-assembled product. Preparation and analysis of the related FeII metallomacrocycle are detailed and its TEM image confirms the hexameric structure. Characterization of the metalated products includes cyclic voltammetry along with the routine analytical techniques. 相似文献
57.
Towards Molecular Construction Platforms: Synthesis of a Metallotricyclic Spirane Based on Bis(2,2′:6′,2“‐Terpyridine)RuII Connectivity 下载免费PDF全文
Dr. Ting‐Zheng Xie Kai Guo Mingjun Huang Dr. Xiaocun Lu Sheng‐Yun Liao Rajarshi Sarkar Dr. Charles N. Moorefield Prof. Stephen Z. D. Cheng Prof. Chrys Wesdemiotis Prof. George R. Newkome 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(36):11291-11294
The design and construction of the first multicomponent stepwise assembly of a <tpy‐RuII‐tpy>‐based (tpy=terpyridine), three‐dimensional, propeller‐shaped trismacrocycle, 8 , are reported. Key steps in the synthesis involve the preparation of a hexaterpyridinyl triptycene and its reaction with dimeric, 60°‐directional, bisterpyridine‐RuII building blocks. Characterization includes ESI‐ and ESI‐TWIM‐MS and TEM, along with 1D and 2D 1H NMR spectroscopy. 相似文献
58.
To expand the utility of bis(terpyridine) metal connectivity, the selective symmetrical and unsymmetrical 4,4"-functionalization (-CN, -Me, -CO2Me) of 4'-(4-bromophenyl)-2,2':6',2"-terpyridines was achieved using the Kr?hnke synthesis. The final substituted 2,2':6',2"-terpyridines along with their corresponding intermediates, 4a-c, were recrystallized and characterized by 1H NMR and 13C NMR as well as X-ray crystallography; COSY correlations were also conducted to permit definitive proton assignment. 相似文献
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Eryazici I Wang P Moorefield CN Panzer M Durmus S Shreiner CD Newkome GR 《Dalton transactions (Cambridge, England : 2003)》2007,(6):626-628
The self-assembly of 3,5-bis(2,2':6',2'-terpyridin-4'-phen-3-yl)toluene with an equimolar amount of a Fe(II) salt afforded a high yield of an interlocked dinuclear tetracationic "molecular gear" that was confirmed by single crystal X-ray data. 相似文献