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11.
2,5-Diphenyloxazole is protonated by sulfuric acid in acetonitrile solvent. The existence of a simple acid base equilibrium is demonstrated by u.v.—visible spectroscopy. Polarographic and cyclic voltammetric data suggest that the protonated heteroaromatic is reduced in a diffusion-controlled step at potentials slightly less negative than the nonprotonated form. 相似文献
12.
CM Thaker S Rayaprol Krushna Mavani DS Rana MS Sahasrabudhe SI Patil DG Kuberkar 《Pramana》2002,58(5-6):1035-1039
The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO3 perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good
example of these properties is (La1−2x
Pr
x
Ca
x
)MnO3 (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T
c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using
X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for
understanding the structural, transport and magnetic properties are discussed in detail. 相似文献
13.
CM Silva MF Duarte ML Mira MH Florêncio K Versluis AJ Heck 《Rapid communications in mass spectrometry : RCM》1999,13(12):1098-1103
Fast atom bombardment, combined with high-energy collision-induced tandem mass spectrometry, has been used to investigate gas-phase metal-ion interactions with captopril, enalaprilat and lisinopril, all angiotensin-converting enzyme inhibitors.Suggestions for the location of metal-binding sites are presented. For captopril, metal binding occurs most likely at both the sulphur and the nitrogen atom. For enalaprilat and lisinopril, binding preferably occurs at the amine nitrogen. Copyright 1999 John Wiley & Sons, Ltd. 相似文献
14.
Benavides GF Zimmerman JW Woodard BS Day MT King DM Carroll DL Palla AD Verdeyen JT Solomon WC 《Optics letters》2012,37(9):1409-1411
The authors report the development of an electric oxygen-iodine laser with higher output using a larger product of gain and gain length, g0L. A factor of 4.4 increase in laser power output on the 1315 nm atomic iodine transition was achieved with a factor of 3 increase in gain length. I(2P1/2) is pumped using energy transferred from O2(a1Δ) produced by flowing a gas mixture of O2-He-NO through three coaxial geometry radio-frequency discharges. Continuous wave (CW) average total laser power of 481 W was extracted with g0L=0.042. 相似文献
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Helen Quincy Woodard K. Fajans E. A. Koćsis 《Analytical and bioanalytical chemistry》1935,102(5-6):211-213
19.
Helen Quincy Woodard K. Fajans und E. A. Kosis 《Fresenius' Journal of Analytical Chemistry》1935,102(5-6):211-213
Ohne Zusammenfassung 相似文献
20.
We present an analysis of oil prices in USD and in other major currencies that diagnoses unsustainable faster-than-exponential behavior. This supports the hypothesis that the recent oil price run-up was amplified by speculative behavior of the type found during a bubble-like expansion. We also attempt to unravel the information hidden in the oil supply-demand data reported by two leading agencies, the US Energy Information Administration (EIA) and the International Energy Agency (IEA). We suggest that the found increasing discrepancy between the EIA and IEA figures provides a measure of the estimation errors. Rather than a clear transition to a supply restricted regime, we interpret the discrepancy between the IEA and EIA as a signature of uncertainty, and there is no better fuel than uncertainty to promote speculation! Our post-crash analysis confirms that the oil peak in July 2008 occurred within the expected 80% confidence interval predicted with data available in our pre-crash analysis. 相似文献