硅晶体表面石墨烯褶皱形貌的分子动力学模拟研究

本文利用分子动力学的方法和模拟退火技术从原子尺度分析研究了Si (100), Si (111)和Si (211)表面单原子层石墨烯的褶皱形貌及其演化特点. 研究表明, 分别置于Si晶体的三种不同原子表面的石墨烯都展现出原子尺度的褶皱形貌. 石墨烯与Si晶体表面原子的晶格失配是引起石墨烯褶皱的主要原因. 研究发现, Si晶体表面石墨烯的褶皱形貌强烈的依赖于退火温度. 石墨烯的褶皱形貌还将直接影响其在Si晶体表面的吸附稳定性. 这些研究结果有助于人们认识基于Si晶体衬底的石墨烯的结构形貌及其稳定性, 为石墨烯的进一步应用提供理论参考.     

铜锌锡硫薄膜材料及其器件应用研究进展

铜锌锡硫薄膜材料组成元素储量丰富, 环境友好, 成本低廉, 成为最具前景的薄膜材料之一. 目前, Cu₂ZnSn(S, Se)₄ (CZTSSe)薄膜太阳电池的最高转换效率已经达到12.6%. 本文总结了Cu₂ZnSnS₄ (CZTS)的发展历史, 依次介绍了CZTS薄膜材料的结构特性、光学特性、电学特性、界面特性和Na对CZTS 薄膜的影响, 详细介绍了CZTS薄膜的制备方法及器件应用的最新研究进展, 总结了目前CZTS薄膜太阳电池发展中存在的问题, 展望了今后的研究方向.     

全光固体条纹相机的理论及其静态实验研究

全光固体条纹相机采用空间调制抽运光激发平板波导光偏转器,通过精确控制抽运光和信号光之间的时间延迟,实现对入射到波导芯层信号光的偏转扫描.它能有效解决传统变像管条纹相机因空间电荷效应造成的动态范围降低以及光电阴极材料在红外波段探测受限等问题,且结构简单,系统稳定性高,理论时间分辨率可达皮秒甚至亚皮秒量级.本文围绕全光固体条纹相机的核心部件—–AlxGa1-xAs/GaAs/AlxGa1-xAs平板波导光偏转器,研究了在带填充效应、带隙收缩效应以及自由载流子吸收效应作用下GaAs折射率的变化情况;在GaAs折射率变化达到0.01量级,信号光束斑大小和波导宽度之比p=0.5时,得到系统的理论时间分辨率为2 ps;按照静态实验条件求得的理论空间分辨率为17 lp/mm,实验结果显示其值为9 lp/mm.     

基于比率的三种群混合扩散模型的动力学行为

讨论了一类基于比率的非自治三种群混合扩散模型,三种群间既有捕食关系又有竞争关系.我们研究了该模型的动力学行为:包括一致持久性,全局渐近稳定性,周期解,概周期解的存在唯一性.表明即使食饵种群在某些孤立的斑块中可能绝灭,也可以通过适当选取扩散率来保证系统持续生存.     

不同水底介质对有限域中装药沉底爆炸特性的影响

通过开展装药沉底爆炸原理性实验研究,得到了不同水底条件对装药沉底爆炸气泡运动和冲击波压力的影响规律:沉底装药水下爆炸气泡通常呈半球形,依附在水底并同时急剧膨胀达到最大半径,随后气泡做收缩运动并连带水底介质颗粒迅速上浮,同时形状发生显著变化,如在石底和泥底时气泡在水底射流的作用下呈蘑菇状上浮,砂底时气泡则呈现出柱状上浮、未出现明显脉动运动即已坍塌破裂;沉底爆炸与水底介质发生强烈耦合作用而形成不同程度的反射波,通常水下石底的反射冲击波较泥底和砂底更强烈,且一般迭加后的冲击波峰值压力高于入射波阵面压力;不同水底介质条件下,装药与水底发生的强烈耦合作用均对水底造成强冲击破坏。     

DFT study on electronic structure and optical properties of N-doped,S-doped,and N/S co-doped SrTiO3

The electronic structures and optical properties of N-doped, S-doped and N/S co-doped SrTiO₃ have been investigated on the basis of density functional theory (DFT) calculations. Through band structure calculation, the top of the valence band is made up of the O 2p states for the pure SrTiO₃. When N and S atoms were introduced into SrTiO₃ lattice at O site, the electronic structure analysis shows that the doping of N and S atoms could substantially lower the band gap of SrTiO₃ by the presence of an impurity state of N 2p on the upper edge of the valence band and S 2p states hybrid with O 2p states, respectively. When the N/S co-doped, the energy gap has further narrowing compared with only N or S doped SrTiO₃. The calculations of optical properties also indicate a high photo response for visible light for N/S co-doped SrTiO₃. Besides, we find a new impurity state which separates from the O 2p states could improve the photocatalytic efficiency and we also propose a model for light electron-hole transportation which can explain the experiment results well. All these conclusions are in agreement with the recent experimental results.     

Second-order Asymptotics on Distributions of Maxima of Bivariate Elliptical Arrays

Let {(ξni, ηni), 1 ≤ i ≤ n, n ≥ 1} be a triangular array of independent bivariate elliptical random vectors with the same distribution function as(S_1, ρ_n S_1 +(1-ρ_n~2S_2)~(1/2)), ρn∈(0, 1), where(S1, S2) is a bivariate spherical random vector. For the distribution function of radius (S_1~2+ S_2~2)~(1/2) belonging to the max-domain of attraction of the Weibull distribution, the limiting distribution of maximum of this triangular array is known as the convergence rate of ρn to 1 is given. In this paper,under the refinement of the rate of convergence of ρn to 1 and the second-order regular variation of the distributional tail of radius, precise second-order distributional expansions of the normalized maxima of bivariate elliptical triangular arrays are established.     

汞原子6sns 3S1,6snd 3D1 Rydberg系列的寿命

利用多通道量子数亏损理论计算了汞原子6sns^3S1(n=11～25),6snd^3D1(n=12～24)两个Rydberg系列的能级和寿命,给出了这两个系列寿命所遵循的公式,6sns^3S。系列为r=0．814v^2.835(ns),6snd^3D1系列为r=0．302v^2.926ns),其中v为有效量子数。     

Spatiotemporal propagation characteristics based on the exact solutions of the generalized nonlinear Schrödinger equation by intensity moments

Based on the exact solutions of the (3 + 1)-dimensional ((3 + 1)D) generalized nonlinear Schrödinger equation (GNLSE), we analyze the spatiotemporal propagation characteristics by intensity moments when a laser propagates in an inhomogeneous nonlinear medium. The different order intensity moment can describe the characteristics of a laser, and in the paper, the beam width (BW), the pulse width (PW), the skewness and the kurtosis parameter are calculated. The spatiotemporal propagation stability of the exact solutions is analyzed in detail by the second-order intensity moment. We find that when the diffraction and dispersion coefficients are the identical distributed functions, the BW and PW of the exact solutions are constants or vary periodically during nonlinear propagation. So, the spatiotemporal propagation of the exact solutions is stable. When the diffraction and dispersion coefficients are other coefficients, the BW and PW of the exact solutions vary irregularly due to the effect of a chirp. Thus the spatiotemporal propagation of the exact solutions is unstable. The results are helpful to the extendable investigation of nonlinear propagation and control of a laser pulse.     

P2P保险的道德风险问题研究

伴随信息产业的快速发展和互联网保险的广泛运用,近几年来国际上出现了一种新型保险模式――P2P保险(Peer to Peer Insurance)。该模式基于互联网,通过聚集若干风险类型相似的投保人组建风险共担互助小组,风险互助小组成员间一般是亲戚、朋友等熟人关系。P2P保险形成的相互监督机制和声誉机制,可以较好地解决传统保险市场中存在的道德风险问题。本文利用经济学中的比较静态分析方法,研究了P2P保险的道德风险问题,并从理论上证明了在P2P保险模式下,投保人会倾向于更加努力防范风险以降低出险概率,道德风险问题可以得到有效缓解。