A field study to assess the effects of wearing hearing protectors on the perception of warning sounds in an industrial environment

A field study has been performed which assessed the effectiveness of two warning sounds under realistic factory conditions. The thirty subjects were press operators who were involved in their regular work activities during the course of the experiment. The noise levels at their work stations were in the range 85 to 95 dB(A). The warning sound, plus four other irrelevant sounds, each at one of five different intensities, were presented via a loudspeaker in random order and at random time intervals (mean inter-stimulus interval, 30 s; range, 10 to 50 s). The influence of the factors hearing level and age of the subjects and use of hearing protection were investigated.The results showed significant differences between the intentional and incidental warning sounds investigated. Whilst the perception of the intentional horn warning sound was unaffected by the hearing sensitivity of the subjects and the wearing of hearing protectors, these two factors had a significant effect on the perception, as a warning, of the clinking sound of metal components. Subjects classified as having a substantial hearing loss perceived, on average, 18 percent fewer clinking sounds than those subjects with normal hearing or a mild hearing loss and, when wearing hearing protectors, the subjects overall perceived, on average, 9 percent fewer clinks. It is of note that the results of the field study differ from those of earlier laboratory-based experiments in finding that the distinctive intentional warning sound was not entirely reliable as a warning, even at levels substantially above its masked threshold, and in observing more than double the adverse effect of wearing hearing protection.     

Bonding studies of compounds of boron and the group IV elements : X. Photoelectron spectra of compounds Me4M (MC,Si, Ge,Sn, or Pb) and the lack of participation of M d-orbitals

The question of d-orbital participation by the central metal M in molecules containing second and higher row elements is critically examined in relation to the photoelectron spectra of the Group IV compounds Me₄M. It is shown that the splitting between the two strictly symmetry-determined CH levels 1t₁ and 1e drops monotonically from 1.3₅ eV in neopentane to approximately zeor in tetramethyl-plumbane, as is consistent with the decreasing through-space interactions in the (CH₃)₄ tetrahedron. Within the limits of the spectroscopic resolution, d-orbital participation is therefore discounted, as this would tend to increase the separation between these two levels on going down the series.     

A study of the action of wild fires on remote forests

A stochastic model is developed to describe interaction of fires and vegetation in remote forest regions to demonstrate that, given certain circumstances, fires have a dominant effect on the long term, as well as the short term, forest structure. The model describes interactions peculiar to rainforest regions of Tasmania, Australia, but can be adapted to any situation where a similar dependence of vegetation on fires exists.     

Edge plane sites on highly ordered pyrolytic graphite as templates for making palladium nanowires via electrochemical decoration

An approach for the fabrication of metal nanowires is presented. Palladium wires with diameters less than 50 nm were produced by electrochemical decoration of step edge sites on the surface of highly ordered pyrolytic graphite via the following three steps. First an electrochemical activation step was used to oxidize the edge plane sites on highly ordered pyrolytic graphite surfaces in 0.5 M Na(2)SO(4). Second, a potential cycling step in a 1 mM PdCl(2) solution in 0.1 M H(2)SO(4) was used to form palladium oxide (s) and/or complexes of Pd on the step edges. Third, Pd nanowires were formed by electroreduction after transfer of the graphite to 0.1 M H(2)SO(4). The resulting wires showed a high degree of uniformity. A merit of this approach is that it allowed metal nanowires to be fabricated without the simultaneous formation of nanoparticles on the basal plane terraces, in contrast to other studies of this type. The mesoscopic palladium wires are shown to be useful for the electrochemical sensing of hydrazine.     

A modified Brent’s method for finding zeros of functions

Brent’s method, also known as zeroin, has been the most popular method for finding zeros of functions since it was developed in 1972. This method usually converges very quickly to a zero; for the occasional difficult functions encountered in practice, it typically takes $O(n)$ iterations to converge, where $n$ is the number of steps required for the bisection method to find the zero to approximately the same accuracy. While it has long been known that in theory Brent’s method could require as many as $O(n^2)$ iterations to find a zero, such behavior had never been observed in practice. In this paper, we first show that Brent’s method can indeed take $O(n^2)$ iterations to converge, by explicitly constructing such worst case functions. In particular, for double precision accuracy, Brent’s method takes $2{,}914$ iterations to find the zero of our function, compared to the $77$ iterations required by bisection. Secondly, we present a modification of Brent’s method that places a stricter complexity bound of $O(n)$ on the search for a zero. In our extensive testing, this modification appears to behave very similarly to Brent’s method for all the common functions, yet it remains at worst five times slower than the bisection method for all difficult functions, in sharp contrast to Brent’s method.     

Stabilized Carbenium Ions as Latent,Z‐type Ligands

Controlling the reactivity of transition metals using secondary, σ‐accepting ligands is an active area of investigation that is impacting molecular catalysis. Herein we describe the phosphine gold complexes [(o‐Ph₂P(C₆H₄)Acr)AuCl]⁺ ([ 3 ]⁺; Acr=9‐N‐methylacridinium) and [(o‐Ph₂P(C₆H₄)Xan)AuCl]⁺ ([ 4 ]⁺; Xan=9‐xanthylium) where the electrophilic carbenium moiety is juxtaposed with the metal atom. While only weak interactions occur between the gold atom and the carbenium moiety of these complexes, the more Lewis acidic complex [ 4 ]⁺ readily reacts with chloride to afford a trivalent phosphine gold dichloride derivative ( 7 ) in which the metal atom is covalently bound to the former carbocationic center. This anion‐induced Au^I/Au^III oxidation is accompanied by a conversion of the Lewis acidic carbocationic center in [ 4 ]⁺ into an X‐type ligand in 7 . We conclude that the carbenium moiety of this complex acts as a latent Z‐type ligand poised to increase the Lewis acidity of the gold center, a notion supported by the carbophilic reactivity of these complexes.