多重向量值正交小波包

本文引入多重向量值小波包的概念,提供一类多重向量值正交小波包的构造方法,并运用积分变换和算子理论,讨论了多重向量值正交小波包的性质．利用多重向量值正交小波包,构造了空间L2(R,Cs×s)的新的正交基．     

五种氨基酸钆络合物的ESR波谱

迄今未见任何稀土氨基酸络合物的ESR波谱报道,本文在合成Gd³⁺分别与甘氨酸、β-丙氨酸、谷氨酸、天冬氨酸和天冬酰胺五种氨基酸络合物的基础上,测定了不同温度下,水溶液、粉末及分子筛吸附样品的ESR谱,讨论了络合物中晶体场强,对称性及成键特性。     

镁离子内扩散铌酸锂研究(Ⅱ)—— X射线衍射和扫描电子显微镜表征

对不同扩散条件的铌酸锂单晶基片进行了X射线衍射分析(XRD)和扫描电子显微镜观察(SEM)。结果表明,在扩散表面富镁层出现一新相结构,可能是由Li-Mg-Nb-O组成的三元系相结构,这一新相被认为是镁离子内扩散的真正扩散源。并对晶格发生畸变、镁离子内扩散机理以及镁的扩散层折射率变化机理进行了分析和讨论。 关键词：     

Spectroscopic Studies of 1-Aryl-2,2-Dichlorocyclopropanes

Seventeen 1-aryl-2,2-dichlorocyclopropanes were examined by using IR, ¹³C NMR, and mass spectrometry. The data obtained from IR and ¹³C NMR spectra indicate that the bond strength of carbon-chlorine on the cyclopropane ring and the electron density of that carbon depend on the substituent. The mass fragmentation patterns of compounds in this series resemble those of the dibromo analogues. The fragmentation mechanism is proposed to involve the formation of indenium ion through an electrocyclization.     

自集成透镜InGaAsP／InPDHLED及其离子束铣技术

本文报道在国内首次采用离子束铣技术研制自集成透镜InGaAsP/InP DH LED的实验结果。采用烘烤正性光致抗蚀剂来形成球状掩膜适合于离子束铣,且重复性很好。为了获得光洁的刻蚀表面,刻蚀条件均已最优化。     

投资组合保险CPPI策略研究

随着期权理论应用的发展,投资组合保险在国外已成为一种盛行的资产配置策略, 常数比例投资组合保险策略(CPPI)以其模型简单、参数的设置又能充分反映投资人不同的风险偏好、而且易于实施,成为大型安全型基金的基金经理首选的投资策略.本文研究并推广了CPPI策略,找出CPPI与期权的关系,讨论了借贷限制对(CPPI策略的影响,最后对CPPI策略在中国市场的可投资性进行了评测.     

Preparation of new mixed ligand complexes of lanthanide acetylacetonate with dibenzo-18-crown-6 and their IR spectra

Fourteen new mixed ligand complexes of lanthanide acetylacetonate and dibenzo-18- crown-6 (DB18C6) were prepared by three different methods. The composition of the complexes was shown to be Ln(acac)· DB18C6 by elemental analysis and X-ray powder diffraction. Infrared spectra of the complexes were investigated, and the results indicate that their absorption bands in the region of 400—4000 cm^?1 are complicated and without much difference from each other, but in the far infrared region various absorption bands of Ln—O can be observed and they changes regularly with the atomic number of lanthanides.     

抗坏血酸同顺磁离子Mn~(2+)、Gd~(3+)络会的~(13)C NMR研究

该文用顺磁离子对其近邻~(13)C核的NMR吸收增宽效应,系统地研究了抗坏血酸在不同溶剂中对金属离子Mn~(2+)、Gd~(3+)的配合行为.在水溶液中,抗坏血酸可通过两种配合方式与Mn~(2+)作用,但与Gd~(3+)的作用只有一种稳定的结构.在水中抗坏血酸对金属的配位活性部位分别是1位羟基氧,3位离解的羟基氧和6位羟基氧.在DMSO中,3位羟基由于H~+对该基团的静电遮蔽而变得对金属离子Mn~(2+)表现为配位惰性,同时6位羟基配位活性较大增强.对Gd~(3+)来说,此时没有优势配位活性部位存在.文章还讨论了抗坏血酸在H_2O-DMSO混合溶剂中的~(13)C NMR谱及在DMSO中NaOH对其~(13)C NMR谱及其与金属络合结构的影响.     

A flow tube study of methyl iodine uptake on soot surface

The black carbon aerosols are now recognized for their potential impact on climate and the halogenated compounds are thought to be very important in atmospheric chemistry. However, there are very few studies on the interactions between soot aerosols and halogenated compounds. We report the measurement of the uptake of CH₃I on soot. The measured uptake coefficient is 0.0103 ± 0.0015 at a total pressure of 2–4 Torr and 298 K. The results suggest that the uptake of CH₃I occurs efficiently on soot particles. The present work suggests that heterogeneous loss of CH₃I on soot may influence the concentration of CH₃I throughout the atmosphere.