梨圆蚧性信息素主要组成3,7-二甲基-2,7-辛二烯-1-醇丙酸酯的合成

Title compounds were prepared in 6 steps in 10% overall yield starting with Reformatskii reaction of Et acetobutyrate with Et bromoacetate.     

含磷拟除虫菊酯的研究I:3-[1'-磷(膦)酸酯基-2'-氯代乙烯基]-2,-二甲基环丙烷羧酸酯的合成及其几何异构体的研究

本文合成了九个新型的含磷拟除虫菊酯类化合物和五个新的中间体, 研究了亚磷(膦)酸酯的取代基空间位阻对Perkow重排产物中几何异构体的影响, 结果表明:取代基位阻增大, 产物E/Z比值也增大。     

微乳液的热力学性质 I: 芳烃类的侧链链长对微乳液热力学函数影响

本文研究以非离子型表面活性剂-正辛醇-水-芳烃类所组成的微乳液, 探讨醇从油相转移到界面相时的自由能变化, 以及温度对自由能的影响。计算出熵和焓的变化, 发现在实验范围内, 上述热力学函数的对数值与芳烃侧链的碳原子数(n)呈线性关系。这些关系式对微乳液的构成和稳定性的讨论是重要的, 还对几种芳烃异构体所构成的微乳液的热力学函数进行了实验和讨论。     

THE RELATION OF SEQUENCE DISTRIBUTIONS OF S-SBR TO ITS MOLECULAR WEIGHT DISTRIBUTIONS

The relationship between sequence distributions and molecular weight distributions of S-SBR, obtained from styrene and butadiene anionic copolymerization at various conversions with THF/Li~+ as an initiator has been studied by ~(13)C-NMR,GPC. The results showed that the molecular weight distributions of the copolymer couldbe correlated sophisticatedly to the binary sequcne distributions or the monomer unit distributions of the copolymer in a corrected Poisson's distribution from.     

PHOTOPHYSICAL STUDIES ON ORGANIC COMPOUNDS——TIME-RESOLVED TRANSIENT ABSORPTION SPECTRA STUDIES ON TRIPHENYLAMINE IN VARIOUS SOLVENTS

The transient absorption spectra of triphenylamine (TPA) in various solvents have beeninvestigated by the methods of nanosecond laser photolysis. The lifetimes of TPA were meas-ured. In hexane and ethanol, the transient absorptions of triplet state and triplet excimer ofTPA were observed. However, the transient absorptions of the TPA cation radical was alsoobserved in acetonitrile besides that of the triplet TPA monomer and excimer. According tothe experimental facts, the transient photophysical mechanism of TPA in various solvents hasbeen proposed.     

NATIONAL STANDARD OF HEAT CAPACITY MEASUREMENT OF SOLIDS IN THE RANGE OF 4.2—90K——AN AUTOMATED ADIABATIC CALORIMETER FROM 25 TO 90K AND MOLAR HEAT CAPACITIES OF α-ALUMINA

The construction of an automated adiabatic calorimeter for heat capacity measurement ofsolids in the temperature range of 25- 90K is described in detail. The sample vessel of thecalorimeter has thin radial vanes which make no contact with its inner wall and are distrib-uted evenly, thus greatly improving the internal thermal equilibration of the vessel. Theprecision of temperature control for the adiabatic shields and electrical leads of the calori-metric system are heightened to a great extent by using the high precision ACD- 79 modeladiabatic controller specially developed by us for this purpose. Measurements of the heatcapacities of high purity α-Al_2O_3, one of the internationally-accepted standard referencematerials, agree with those of the National Bureau of Standards (NBS), USA within ±0.3%,demonstrating the reliability of this apparatus.     

CYTOLOGIC AND EMBRYOLOGIC STUDIES ON APOMICTS DISCOVERED FROM MALE STERILITY LINE C1001 IN RICE (Oryza sativa L.)

Cytologic and embryologic studies on the reproductive pattern of male sterility line C1001 in rice (Oryza saliva L.) indicated that several types of apomixis were discovered in partial strains of male sterility line C1001 in rice. Under a fully separate condition, two possible apomixis embryogenesis ways in the ovules were observed: One way was that the embryo was initiated from the somatic cells of the ovules, and then pushed against the embryo sac to develop into a mature embryo. The other way was that the embryo was from the unfertilized egg cell or one of synergids, and then developed into a mature embryo in the form of haploid parthenogenesis without forming endosperm. Besides, the antipodal cells migrated in the embryo sac, and their cytoplasm became thin and vacuolated while mitosis was taking place, giving rise to a multicellular structure or a group of large cells each containing several nuclei. This paper also discusses the significance and patterns of apomixis in rice C1001.     

不同制备条件对纳米Bi~2O~3发光的影响

本文用微乳液法合成了不同表面活性剂包覆的和反应物阴阳离子配比不同的纳米Bi~2O~3有机溶胶。发现阴阳离子配比对纳米体系的发光有很大影响, 不同的表面包覆剂对发光的影响则较小, 并对此进行了解释。