The Synthesis of Some Novel N-[α-(Isoflavone-7-O-) Acetyl]Amino Acid Derivatives

IsoflavonoidsarebiologicallyimportantnaturalproductsoccurringmainlyinspeciesoftheLeguminosaefamilyandhaveshownawidespectrumofbiologicalactivitiesincludingestrogenic,anticancer,insecticidal,pisciadalandantifungalproperty'.Theseisoflavonoidphytoestrogensarerichinsomeplantdietsuchassoybean'.Animalexperimentshadshownthatsoybeandietinhibitradiation-andchemical-inducedtumorofthemammary',skin',andlivers.AstudyconductedbyBarnesetal.6suggestedthatsoybeanisoflavonesmayberesponsiblefortheanticarcinogeni…     

Synthesis,Structure and Electrochemical Property of a New Copper(II) Complex Based on Benzene-1,2,4,5-tetracarboxylate and 2,5-Bis(3-pyridyl)-1,3,4-oxadiazole Ligands

Abstract  

A new three-dimensional (3-D) supramolecular complex, [Cu₂(btec)(bpo)₂(H₂O)₂]·8H₂O (1), has been synthesized by hydrothermal reaction with the mixed ligands benzene-1,2,4,5-tetracarboxylate (btec) and bent dipyridyl based ligand 2,5-bis(3-pyridyl)-1,3,4-oxadiazole (bpo), and structurally characterized by elemental analysis, IR, TG, powder-XRD and single-crystal X-ray diffraction analysis. The results reveal that each Cu(II) ion is bridged by two different ligands (btec and bpo) to form a 2-D polymer layer in complex 1. The adjacent layers are further linked by 1-D H-bonded water chains simultaneously containing (H₂O)₆ rings and (H₂O)₈ rings to form a 3-D supramolecular framework. Moreover, the electrochemical behavior of complex 1 bulk-modified carbon paste electrode (1-CPE) has been reported.     

Study on Phase Equilibrium Properties for CO_(2+) Cosolvent Binary Systems

Recently, the application of supercritical fluid technology is very interested, and it is applied in many areas for its special properties. The performance of supercritical fluid (SCF) as a solvent can be greatly affected by addition of an entrainer to the system. An entrainer can be added to a supercritical fluid to enhance its solvent strength and/or selectivity. Critical point data for these dilute supercritical fluid-cosolvent systems are imperative for the design of efficient separation …     

非视线紫外光大气传输模型的建立及验证

基于蒙特卡罗方法建立了非视线紫外光传输模型。利用此模型模拟了不同传输距离、不同发射和接收仰角等多种传输条件下的传输情况,并在同等条件下进行了相关实验。结果表明,在相同条件下,信号强度模拟曲线与实验曲线的变化趋势相同且吻合较好,但具有一定的误差。进一步分析指出,模型中大气散射系数、吸收系数、分子散射比、传输测试距离等参数的误差影响了模拟结果的准确,以及模拟与实验曲线的吻合程度。     

One-pot tandem Barbier-Prins synthesis of tetrahydropyrans in aqueous media

Tetrahydropyran is an important structural core ofmany carbohydrates and their polymers. Its structure ispresent in numerous natural compounds such as poly-ether antibiotics, marine toxins and pheromones[1,2].Thus many reactions have been developed toward…     

分子动力学模拟纳米晶体铜的结构与性能

通过分子动力学方法模拟纳米面心立方晶体铜的结构，并对模拟的结果进行了不同晶粒尺寸的纳米晶体的密度、能量分布以及弛豫前后的X射线衍射、径向分布函数等计算.结果表明，大体积分数的晶界和畸变的晶粒是纳米晶体有别于传统的粗晶粒晶体材料结构的重要方面，由此导致纳米晶体一系列不同性能. 关键词：     

CSRm束流径向和轴向振荡的耦合

介绍了由于磁铁的安装误差和螺线管的存在而造成的束流径向和轴向的耦合，以及耦合对束流稳定的影响。结合CSRm结构的典型参数分析得出:二极磁铁和四极磁铁在纵向角安装偏差为-0.5~0.5 mrad；有螺线管存在的情况下，工作点落在和共振线时，将导致束流不稳定而大量损失，落在差共振线时，束流稳定。通过模拟计算发现:螺线管产生的耦合远大于磁铁的纵向角安装偏差产生的耦合。     

关于H.Yoshida的一个问题

H.Yoshida曾经提出下述问题:对级小于1/2的整函数f（z）,是否自原点出发的每一条射线,或者为它的Julia方向,或者在包含该射线的某个角域内当|z|→∞时有|f（z）|→∞.本文的结论表明对正则增长的整函数,H.Yoshida问题的答案是肯定的,而且对许多其他的Julia型方向,类似的问题的答案也是肯定的.     

C_(60)衍生物分子的拉曼光谱研究

本文通过对C6 0 衍生物拉曼光谱的研究发现 ,由于有机官能团的出现使得C6 0 分子的结构发生了变化 ,从而导致C6 0 衍生物的拉曼光谱有了明显不同。本文对此现象进行了分析与解释。     

不同负冲角工况下透平叶栅二次流的数值模拟及分析

本文应用TVD格式和Baldwin－Lomax代数紊流模型求解三维NS方程，对一个透平直列叶栅流场在两个不同的负冲角工况下进行了数值模拟，给出了叶栅马蹄涡及其分离鞍点、通道涡、角涡等二次流涡系的结构及其产生发展过程，并对不同工况下的涡系结构及冲角的影响作了详细的分析和比较．本文结果有助于对叶栅二次流涡系结构的产生发展机制的深入了解，同时表明所用数值求解技术有较高的精度和分辨率。