β-SiC薄膜在SF6和SF6+O2中的等离子体刻蚀研究

以SF₆和SF₆+O₂为刻蚀气体,采用等离子体刻蚀工艺成功地对化学气相淀积工艺制备的β-SiC单晶薄膜进行了有效的刻蚀去除.实验指出当气体混合比约为40%时,刻蚀速率达到最大值.俄歇能谱分析表明,在SF₆和SF₆+O₂气体中被刻蚀后的样品没有形成富C表面的SiC层.研究结果为各种SiC器件的研制奠定了必要的实验基础. 关键词：     

外开槽同轴波导大轨道回旋自谐振脉塞放大器

 运用大轨道电子束,对外开槽同轴波导回旋自谐振放大器进行了线性动力学理论分析和非线性自洽模型模拟。由线性动力学理论分析和非线性模拟得到的结果在线性增长部分吻合得很好。为了有效抑制绝对不稳定性,对电子束流的选择进行了讨论。计算结果表明：对于电压为700 kV, 电流为100 A, 电子束纵横向速度比为0.8的大轨道电子束, TE₅₁外开槽同轴波导回旋自谐振脉塞放大器的峰值功率和峰值效率分别可以达到6.27 MW和8.96%。     

Multi-Slit Diffraction of Evanescent Electromagnetic Waves

The well-known Fraunhofer multi-slit diffraction is described as the multi-slit interference modulated by the singleslit diffraction, namely the multiplication between the single-slit diffraction factor and the multi-slit interference factor. By considering the simplified argument we show that the multi-slit diffraction of evanescent waves which are in the near-field region also has the interference and diffraction effects, and that this two-fold effect can be expressed as the convolution of the diffraction factor and the interference factor. Our conclusion could be helpful to understand the contribution of evanescent waves to the optical responses of sub-wavelength structures such as slits and grooves.     

A Cation and Anion Dual Doping Strategy for the Elevation of Titanium Redox Potential for High-Power Sodium-Ion Batteries

Titanium-based polyanions have been intensively investigated for sodium-ion batteries owing to their superior structural stability and thermal safety. However, their low working potential hindered further applications. Now, a cation and anion dual doping strategy is used to boost the redox potential of Ti-based cathodes of Na₃Ti_0.5V_0.5(PO₃)₃N as a new cathode material for sodium ion batteries. Both the Ti³⁺/Ti⁴⁺ and V³⁺/V⁴⁺ redox couples are reversibly accessed, leading to two distinctive voltage platforms at ca. 3.3 V and ca. 3.8 V, respectively. The remarkably improved cycling stability (86.3 %, 3000 cycles) can be ascribed to the near-zero volume strain in this unusual cubic symmetry, which has been demonstrated by in situ synchrotron-based X-ray diffraction. First-principles calculations reveal its well-interconnected 3D Na diffusion pathways with low energy barriers, and the two-sodium-extracted intermediate NaTi_0.5V_0.5(PO₃)₃N is also a stable phase according to formation energy calculations.     

Manipulating the Click Reactivity of Dibenzoazacyclooctynes: From Azide Click Component to Caged Acylation Reagent by Silver Catalysis

Strain-promoted azide–alkyne cycloaddition using dibenzoazacyclooctyne (DBCO) is widely applied in copper-free bioorthogonal reactions. Reported here is the efficient acid-promoted rearrangement and silver-catalyzed amidation of DBCO, which alters its click reactivity robustly. In the switched click reaction, DBCO, as a caged acylation reagent, enables rapid peptide/protein modification after decaging facilitated by silver catalysts, rendering site-specific conjugation of an IgG antibody by a Fc-targeting peptide.     

Spatial variability and radiation assessment of the radionuclides in soils and sediments around a uranium tailings reservoir,south of China

Journal of Radioanalytical and Nuclear Chemistry - The concentrations of 238U, 226Ra, 232Th and 40K and gross α, β were measured in soils and sediments around a uranium tailings reservoir...     

Synthesis of Caffeic Acid Sulphonamide Derivatives and Preliminary Exploration of Their Biological Applications

Structural modification of native compounds is an effective way to develop new drugs with increased pharmacological activities and improved material characteristics. In this study, caffeic acid sulphonamide derivatives(CSs) were synthesised by conjugating sulphonamides to the backbone of caffeic acid. The structures of these derivatives were elucidated by means of Fourier transform infrared spectroscopy(FTIR), ¹H NMR, ¹³C NMR, and electrospray ionization mass spectroscopy(ESI-MS). A content determination method was established by ultraviolet detection. The lipophilicity, 2,2-diphenyl-1-picrylhydrazy free radical(DPPH) scavenging capacity, anti-coagulant effects, anti-bacterial activity, cytotoxicity, in vitro anti-proliferative activity against tumour cells, and the ability of the compounds to promote the proliferation of chondrocytes were evaluated. The results indicate that CSs exhibit strong DPPH scavenging activity, high lipophilicity, good anti-coagulant activities, wide anti-bacterial activity range, low cytotoxicity, and an excellent ability to promote chondrocyte proliferation.     

多孔活性自燃金属的光谱辐射特性研究

多孔活性金属材料因为内部存在大量的孔隙,大大地增加了与空气的接触面积,使得其在空气中的燃烧较为猛烈,燃烧温度迅速上升。其燃烧过程属于固体燃烧的范畴,较为复杂。以镁为例,通过建立燃烧模型,来研究多孔活性金属的光谱辐射特性。首先,建立氧气总消耗量与活性金属剩余质量的关系,研究氧气在活性金属孔隙内的扩散浓度关系,通过求解活性金属热平衡方程得到活性金属燃烧过程中温度与时间的关系式,进而得到活性金属的峰值光谱辐射强度表达式;然后,将模型计算的仿真结果与红外热像仪测得的实验结果对比,结果表明,模型的计算结果与实验结果相一致,误差在了10%以内;最后,通过建立的燃烧模型来研究活性金属燃烧规律以及其光谱辐射特性,解决了高空、高速下的活性金属光谱辐射强度难以实验获得的问题,大大减小了实验成本与时间。分别对比不同时间活性金属箔片在1～3,3～5以及8～12 μm波段下的辐射强度,得出活性金属燃烧时的辐射强度主要集中在3～5 μm波段的结论。研究结果表明：自燃金属最大燃烧温度随高度的增加逐渐下降,随气流速度的增加先增加后减小,在速度为30 m·s-1时,温度达到最大;自燃金属的光谱辐射强度在2～6 μm波段达到最大。该模型也可以用来研究其他活性金属的燃烧特性。     

DISCRETE HUYGENS' MODELLING APPROACH TO WAVE PROPAGATIONS IN A HOMOGENEOUS ELASTIC FIELD

The application of the discrete Huygens' modelling has been discussed for acoustic wave propagation problems, in which the scalar wave field problems have been focused. The present paper extends the application of the modelling to the elastic wave propagation in a homogeneous elastic medium in which two types of waves, the longitudinal wave and the shear wave, are independent except at the boundary. Each wave can be treated like a scalar wave until the two waves reach the boundary where they couple so as to satisfy the displacement or stress boundary condition. We propose the approach confining ourselves to the two-dimensional field. Some examples are demonstrated, whose solutions are compared with the vectorial wave modelling and finite difference modelling solutions whenever they are available.     

碘-四氯化碳萃取光度法间接测定食品中的痕量过氧化氢

在 p H1.0— 3.0稀硫酸介质中 ,一定的反应条件下 ,过氧化氢与碘化钾反应 ,释放出一定量的碘 ,建立了碘 -四氯化碳萃取光度法间接测定痕量过氧化氢。共存离子基本上不干扰测定 ,过氧化氢的检测限为0 .0 5 μg·m L-1;回收率在 94 %— 98%之间 ,结果令人满意