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Maria do Carmo Rangel Varela Milton Francisco de Jesus Filho Fernando Galembeck 《Hyperfine Interactions》1994,83(1):159-167
Mössbauer spectroscopy was used to follow the aging of ferrihydrite with different amounts of acetate, to achieve more crystalline products. Mössbauer spectra of fresh samples did not show any magnetic components. After two years aging, the solids presented crystalline fractions. Hematite formation was inhibited as acetate content increased in solids. For an acetate/iron molar ratio equal to 0.63 goethite was formed instead of hematite. X-ray diffraction confirmed these results. This work shows that synthetic samples can be used for elucidating the anti-hematitic effect of organic matter already detected in soils. 相似文献
44.
A. González Arias A. del Cueto J. M. Muñoz C. de Francisco L. Torres A. G. Flores M. Zazo J. Iñiguez 《Applied Physics A: Materials Science & Processing》1996,63(5):453-459
Silica may dissolve up to about 0.05 wt% in an iron excess NiZnCo spinel matrix, affecting noticeably the magnetic properties at low and high values of the applied field. The initial permeability is reduced by about 50% with the addition of only 0.1 % SiO2, while the coercivity almost triples, without noticeable changes in porosity or grain distribution. The vacancy and Fe2+ content of the sintered material also show a considerable change. The energy associated to the transformation Fe3+ Fe2+ for the samples without SiO2 was found to be 0.41–0.42 eV, while for the samples with SiO2 additions it decreased to 0.26 eV. The changes in magnetic properties are thought to be caused, more than because of the mentioned changes in ion distribution, by the stresses and defects created in the lattice due to the very small size of the Si4+ ion, which substitutes Fe3+ ions in tetrahedral sites. The transition Fe3+ Fe2+ seems to take place exclusively in the octahedral sites. 相似文献
45.
Francisco J. Castro-Jimé nez Luis Narvá ez-Macarro David Mond 《Transactions of the American Mathematical Society》1996,348(8):3037-3049
We prove that if is a ``strongly quasihomogeneous" free divisor in the Stein manifold , and is its complement, then the de Rham cohomology of can be computed as the cohomology of the complex of meromorphic differential forms on with logarithmic poles along , with exterior derivative. The class of strongly quasihomogeneous free divisors, introduced here, includes free hyperplane arrangements and the discriminants of stable mappings in Mather's nice dimensions (and in particular the discriminants of Coxeter groups).
46.
Fustero S Navarro A Díaz D de La Torre MG Asensio A Sanz F González ML 《The Journal of organic chemistry》1996,61(25):8849-8859
Reaction of azaenolates of 2-alkyl-oxa(thia)zolines 6 with imidoyl chlorides 7 as electrophiles to furnish masked N-substituted beta-enamino acid derivatives 1-2 in 70-90% yield is described. Alternative routes are discussed. Compounds 1-2 generally appear in one tautomeric form, imino or enamino, depending on the nature of the imidoyl chloride. The configuration of the enamino moiety (Z) and the conformation (s-cis) of compounds 1-2 obtained were established by an NMR study and unequivocally set by nuclear Overhauser effect difference experiments. An X-ray structure of compound 1e is also reported, showing a strong intramolecular NH.N hydrogen bond. Ab initio calculations (HF/3-21G and HF/3-21+G) have been carried out on several representative examples (1e, 1p, and 1l) in an attempt to support and provide the correct geometry of these derivatives. Structural considerations among the possible isomers of compounds 1 are discussed. From these studies it was concluded that the theoretical calculations agree with the experimental results. In addition, a very simple one-pot procedure for the preparation of masked N-substituted alpha-alkylated beta-enamino acid derivatives 2 from 6, 7, and different alkyl halides (R(3)Y) is described. 相似文献
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Rafael Bilbao María Benita Murillo Angela Millera Jos Francisco Mastral 《Thermochimica Acta》1991,190(2):163-173
An experimental system that allows the use of large particle sizes and the simulation of different operating conditions was built to study the thermal decomposition of lignocellulosic materials. The values of solid conversion and of temperature obtained at different points using spherical particles of pine wood 2 cm in diameter are shown. The conversion values are compared with those calculated from the equations obtained in a thermobalance for small particle sizes. 相似文献
50.
Carmen R. Alonso-Cruz Francisco J. Ortiz-López Ernesto Suárez 《Tetrahedron letters》2005,46(32):5265-5268
The reaction of derivatives of 3-acetyl-d-glucal, 3-acetyl-l-rhamnal, 3-acetyl-d-galactal, and 3-acetyl-d-lactal with sodium benzenesulfinate in acid medium catalyzed by HgSO4 afforded diastereoisomeric mixtures of the corresponding 2,3-dideoxy-3-(phenylsulfonyl)-hexopyranoses through a Ferrier rearrangement. The anomeric alkoxyl radical fragmentation of these γ-hydroxy sulfones using the system (diacetoxyiodo)benzene and iodine gave vinyl sulfones with structures of 1,2-dideoxy-4-O-formyl-2-(phenylsulfonyl)-pent-1-enitol and configurations d-erythro, l-erythro, and d-threo at the two stereogenic centers. 相似文献