聚对氨基苯磺酸修饰玻碳电极不可逆双安培法测定酪氨酸

在玻碳电极上成功地制备了聚对氨基苯磺酸修饰电极(P-p-ABSA/GCE),研究了酪氨酸在该修饰电极上的电化学行为.将此修饰电极用于流动注射不可逆双安培体系的构建,建立了流动注射双安培法直接测定酪氨酸的方法.在0 V外加电压下,在0.005 mol/L硫酸载液中,酪氨酸的氧化峰峰电流与其浓度在2.0×10-6 ～2.0×10-4 mol/L范围内呈良好的线性关系,方法的检出限(S/N=3)为1.0×10-7 mol/L.连续测定1.00×10-5 mol/L的酪氨酸标准溶液,电流值的相对标准偏差(RSD)为1.48%(n=20).该方法具有较高的选择性和灵敏度,应用于测定复方氨基酸注射液中酪氨酸的含量的测定,结果比较满意.     

水杨酸在多壁碳纳米管修饰电极上的电化学行为及其测定

用循环伏安法(CV)研究了水杨酸(SA)在多壁碳纳米管修饰玻碳电极上的电化学行为,并初步探讨了反应机理.实验结果表明,水杨酸在该电极上为一个2e/H~+的完全不可逆过程.在pH=5.0的磷酸盐缓冲溶液(PBS)中,用循环伏安法在该电极上测定了水杨酸.方法线性范围为2.0×10~(-5)～1.0×10~(-3)mol/L,检出限为8.93×10~(-6)mol/L.将该电极用于药品分析,结果令人满意.     

Beltrami定理的推广

本文研究了Berwald流形之间的射影对应.利用Berwald流形上Weyl射影曲率张量的射影不变性,证明了当n>2时,与射影平坦的Berwald流形射影对应的黎曼流形M~n是常曲率流形,从而推广了Beltrami定理.     

中国乡镇企业增长的随机前沿生产函数分析

论文在运用中国1990-2005年间省际平衡面板数据的基础上,采用考虑非效率项的非中性技术进步随机前沿生产函数模型,分析了影响我国各省区乡镇企业增长的规模报酬、技术效率和技术进步因素。主要得出结论如下:在乡镇企业的发展过程中,资本产出弹性不断接近甚至有超过劳动产出弹性的趋势,呈现出一定的"资本深化"过程;整个规模报酬略大于1,这表明适当扩大乡镇企业经营规模存在着一定的规模经济效应;而整体平均技术效率水平逐年递增,技术进步率则逐年下降。在这些实证工作的基础上,论文还得出一些政策建议,希冀能够对实现我国乡镇企业的可持续发展有所裨益。     

双圆性质曲线和拟共形映射

设 f : R²→R² 是一同胚, f (∝)=∝. 该文证明了f 是拟共形映射的充要条件是f 保持曲线的双圆性质不变.     

Double hydrophilic block copolymer controlled growth and self-assembly of CaCO3 multilayered structures at the air/water interface

Double hydrophilic block copolymers PEG-b-PEI-linear with different PEI block lengths have been examined for CaCO3 mineralization at the air/water interface. The results demonstrated that either PEI length or the solution acidity had a significant influence on the morphogenesis of vaterite crystals at the air/water interface. A possible mechanism for the stratification of CaCO3 vaterite crystals has been proposed. Increasing either PEI length or the initial pH value of the solution will decrease the density of the PEG block anchored on the binding interface and result in exposing more space as binding interface to solution and favoring the subnucleation and stratification growth on the polymer-CaCO3 interface. In contrast, higher density of PEG blocks will stabilize the growing crystals more efficiently and inhibit subnucleation on the polymer-CaCO3 interface, and thus prevent the formation of stratified structures. This study provides an example that it is possible to access morphogenesis of calcium carbonate structures by a combination of a block copolymer with the air/water interface.     

利用水平沉积法制作PS微球二元胶体薄膜及其它复杂结构

本文采用水平沉积方法,制作出各种胶体晶体薄膜.以聚苯乙烯微球为构建单元,制作了多种二元胶体晶体和非单一平面的胶体晶体.为实现太赫兹光子晶体波导,还采用这一方法将线缺陷植入胶体晶体.结果显示通过该方法可以获得很好的有序结构,说明水平沉积方法可以广泛于各种胶体晶体制作.     

分子动力学模拟BCC铁中级联碰撞产生的缺陷结构及其演变(英文)

用分子动力学模拟BCC铁中级联碰撞原子的演变过程.结果显示,级联碰撞的原子不仅可以临时地产生自间隙原子、空位、以及<100>,<110>和<111>哑铃型缺陷,也可以产生<110>和<111>,以及<110>和<110>哑铃型缺陷的复合缺陷.模拟显示在模拟的能量范围内,如果初级碰撞原子的能量越大,该原子引起的级联碰撞覆盖区域会越大.发现具有几千电子伏特初级碰撞能量的原子引起的级联碰撞覆盖区域大约为11~15个晶格常数大小.同时还发现在级联碰撞的初始阶段(0.0~0.75 ps)不仅会有自间隙原子与空位的生成,同时也会有少量的自间隙原子与空位缺陷复合而消失.     

MEND——-—个计算250 MeV以下中重核数据的程序(英文)

基于球型光学模型、 预平衡发射和Hauser Feshbach统计等理论, 编制了MEND程序（Medium Energy Nuclear Data）, 该程序适用于中重原子核在入射粒子能量低于250 MeV的中低能区的全套核数据计算。对于中子和质子在250 MeV以下诱发的核反应, 其全截面、 反应截面、 弹性散射微分截面、 双微分截面和能谱等理论计算值与相应的实验值基本一致。MEND是计算中低能核反应的基础程序, 在我国已被广泛用于核数据计算及建立中能核数据库Based on the spherical optical model, pre equilibrium statistical theory, and Hauser Feshbach theory, etc., the code MEND (Medium Energy Nuclear Data) is written for calculating the complete set of nuclear data of medium heavy nuclei in medium low energy region (≤250 MeV). For the reactions induced by neutron and proton below 250 MeV, the total cross sections, reaction cross sections, elastic scattering differential cross sections, double differential cross sections and energy spectra, etc. calculated by the code MEND, generally agree with those corresponding experimental data. MEND is a foundational program for nuclear reaction in medium low energy region and is wildely used for nuclear data calculation and establishing ENDF/B6 format files of medium low energy region in China.     

HPLC Fingerprint with Multi-components Analysis for Quality Consistency Evaluation of Traditional Chinese Medicine Si-Mo-Tang Oral Liquid Preparation

Si-Mo-Tang(SMT) oral liquid preparation, a traditional Chinese medicine, was prepared from four crude herbal drugs, Fructus Aurantii Submaturus, Radix Aucklandiae, Semen Arecae and Radix Linderae Aggregatae. A combinative method using HPLC fingerprint and quantitative analysis was developed and validated for quality consistency evaluation of SMT. Individual HPLC chromatograms were evaluated against the mean chromatogram generated via a similarity evaluation computer program. Data from chromatographic fingerprints were also processed with principal component analysis(PCA) and hierarchical cluster analysis(HCA). Additionally, six components (naringin, isonaringin, hesperidin, neohesperidin, norisoboldine and potassium sorbate) in SMT were simultaneously determined to interpret the quality consistency. For fingerprint analysis, 20 peaks were selected as the characteristic peaks to evaluate the similarities of 26 SMT collected from different manufacturers. Among the 20 characteristic peaks, 10 peaks were assigned to be naringin, hesperidin, neohesperidin, isonaringin, neoeriocitrin, tangeretin, nobiletin, norisoboldine, 5-(ethoxymethyl)furan-2-carbaldehyde and potassium sorbate, respectively. The results of similarity analysis, PCA and HCA, indicate that the samples from different manufacturers were consistent with each other in composition. The results from the quantitative data show that the contents of six compounds were significantly different in SMT oral liquid preparations from different manufacturers. The combinative method of chromatographic fingerprint with quantitative analysis developed here offered an efficient way for the quality consistency evaluation of the traditional Chinese medicine SMT.