ONOO-活性氧的荧光光谱分析进展

系统介绍了ONOO^-活性氧的化学性质，并对其参与的主要化学反应进行了分类和总结．同时，比较了近年来用于ONOO^-检测的方法，并重点论述了荧光光谱分析方法尤其是酶催化动力学荧光分析法在检测ONOO^-活性氧方面的优势和最新的研究进展．     

纳米级氧化铁的合成及其对六价铬的吸附性能研究

采用溶胶-凝胶法合成了纳米氧化铁,研究了合成条件,并采用TEM对产品进行了表征,测得产品的平均粒径为20-30nm.研究了纳米级氧化铁对Cr（Ⅵ）的吸附.在pH=3.0,吸附比为3.5×10-6:1×10-2（g/g）时,平均吸附效率为95.98％,最大吸附量为398.3μg Cr（Ⅵ）/g.采用2mol/LNaOH可完全洗脱纳米氧化铁所吸附的Cr（Ⅵ）,测定了回收后的纳米氧化铁对Cr（Ⅵ）的吸附效率,结果表明纳米级氧化铁可循环使用,这将为环境污水中Cr（Ⅵ）的治理及研究纳米材料的吸附行为提供参考.     

Chaos Synchronization Criterion and Its Optimizations for a Nonlinear Transducer System via Linear State Error Feedback Control

Global chaos synchronization of two identical nonlinear transducer systems is investigated via linear state error feedback control. The sufficient criterion for global chaos synchronization is derived firstly by the Gerschgorin disc theorem and the stability theory of linear time-varied systems. Then this sufficient criterion is further optimized in the sense of reducing the lower bounds of the coupling coefficients with two methods, one based on Gerschgorin disc theorem itself and the other based on Lyapunov direct method. Finally, two optimized criteria are compared theoretically.     

A MEMS-Based Piezoelectric Power Generator for Low Frequency Vibration Energy Harvesting

A novel power generator has been achieved to convert vibration to electrical energy via the piezoelectric effect. The generator obtained by micro fabrication process mainly consists of silicon based frame and composite cantilever. The prototype tested at resonant vibration generates 1.15μW of effective power to a 20.4-kΩ resistance load. The potential of this work is to offer miniaturization solutions for power generators, and with the proposed method the ambient ubiquitous vibration can be harvested effectively as endless energy source to form an integrated self-powering system.     

Piezoelectric Fiber－optic Spectroelectrochemistry──A New Technique of Spectroelectrochemistry in Combination With Piezoelectric Quartz Crystal Detection

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STUDIES ON POLYMERIZATION KINETICS OF METHYL METHACRYLATE AT HIGH CONVERSION

The bulk polymerization of methyl methacrylate which was carried out in a metallic dilatometer and in a differential scanning calorimeter has been studied over the complete course of the reaction. An attempt was made to quantitatively express the relation on the onset of gel effect and the final conversion with polymerization conditions such as temperature, kinds and concentration of initiators. It was demonstrated further that the final conversion of polymerization in homogeneous ideal systems is only dependent upon the reaction temperature.     

左手材料设计及透明现象研究进展

左手材料具有负的介电常数, 磁导率和折射率,它与电磁波相互作用的规律与传统材料有本质的区别.首先讨论了金属线点阵结构实现负介电常数和开口谐振环点阵结构实现负磁导率的内在机理,综述了目前实现左手材料的设计与制备方法,讨论了左手材料研究中能量如何定义以满足守恒律, 左手材料的宏观等效参数的确定,以及影响左手材料负折射相对频带带宽的因素。最后对左手材料在光子隧道效应和电磁波透明方面的应用进行了介绍,重点讨论了利用力学中的``中性夹杂'概念对电磁波透明的设计.论文还探讨了声波左手材料的概念和物理意义,介绍了用声波左手材料实现声波透明的方法.      

高频感应等离子体流动模型与微型电推进器流场特性分析

微型射频离子推力器具有结构简单、 工作寿命长、 推力动态范围大、 性能调节响应灵敏等特点,是国际微电推进领域的研究热点之一.射频离子推力器电离室内的感性耦合放电等离子体特性和推力器的性能密切相关.为此,文章建立了低气压、小尺寸微型射频离子推力器电离室内感性耦合等离子体流体模型,开展了电磁场、流场、化学反应浓度场的多物理...     

近零排放双燃料多功能系统特性规律分析及优化

本文对煤/天然气双燃料氢电联产多功能系统进行了特性规律分析.从燃料互补和能量综合梯级利用角度,分析了重整条件、氢气分离率对系统节能率的影响,以及多功能系统特征参数的变化规律,得到了新系统可以提高燃料化学能利用效率,同时可以降低CO2分离能耗的结论.在能量利用上的优势和对CO2的有效控制,使得新系统相对参考系统可以实现低能耗分CO2.