叶酸-壳聚糖偶联物的制备及对人体血红细胞的影响

通过叶酸活性酯与壳聚糖的氨基反应,制备出叶酸-壳聚糖偶联物;经红外光谱、核磁共振表征该偶联物的化学结构,紫外分光光度法测定每个壳聚糖上叶酸的接枝量。通过溶血实验、扫描电镜、原子力显微镜观察比较了壳聚糖、叶酸-壳聚糖对人体红细胞的影响。结论:成功制备出叶酸-壳聚糖偶联物;与壳聚糖相比,接枝叶酸的壳聚糖对血红细胞的形貌没有改变。     

Generation of Entanglement Between Two Noninteracting Qubits via Interaction with Nonclassical Radiation Field

We study the interaction between a single-mode quantized field and a quantum system composed of two qubits. We suppose that two qubits initially be prepared in the mixed and separable state, and study how entanglement between two qubits arises in the course of evolution according to the Jaynes-Cummings type interaction with nonclassical radiation field. We also investigate the relation between entanglement and purity of qubit subsystem. We show that different photon statistics have different effects on the dynamical behavior of the qubit subsystem. When the qubits are initially prepared in the maximally mixed and separable state, for coherent state field we cannot find entanglement between two qubits; for squeezed state field entanglement between two qubits exists in several short period of time; for even and odd coherent state fields of large photon number, the dynamical behavior of the entanglement between two qubits shows collapse and revival phenomenon. For odd coherent state field of small photon number, the entanglement with both qubits initially prepared in maximally mixed state can be stronger than that with both qubits initially prepared in pure states. For fields of small photon number, the entanglement strongly depends on the states they are initially prepared in. For coherent state field, and odd and even coherent state fields of large photon number, the entanglement only depends on the purity of the initial state of qubit subsystem. We also show that during the evolution the unentangled state may be purer than the entangled state, and the maximum degree of entanglement may not occur at the time when the qubit subsystem is in the purist state.     

干涉显微镜中相移误差分析

相移误差是影响干涉显微镜测量表面形貌精度的主要因素之一。介绍了四帧算法、五帧算法、四帧免疫算法、五帧免疫算法的原理和计算公式 ,并对其特点进行了分析比较。利用自行研制的带旋转检偏器的干涉显微测量系统 ,分别用四种算法对Ra=0 35μm和Ra=0 .0 9μm粗糙度样块进行了实测。结果表明 ,五帧算法的重复测量精度优于0 5nm ,五帧免疫算法的重复测量精度优于 0 3nm。同时对在普通干涉显微镜上进一步提高其测量精度做了初步探讨     

硫化锂分子的分析势能函数和光谱

应用密度泛函理论的B3LYP方法和6-311++g（d,p）基组,研究Li₂、LiS和Li₂S分子的基态构型.结果表明它们的基电子态分别为X¹Σ_g⁺、X²Π和X¹Σ_g⁺.通过非线性曲线拟合,得到基态LiS和Li₂分子的4参数Murrell-Sorbie分析势能函数,计算它们的光谱参数和力常数.基于多体项展式理论得到了基态Li₂S分子的单重态势能面的分析函数.利用得到的分析势能函数重构基态单重Li₂S分子的旋转图、伸缩图和旋转伸缩图,准确地再现了Li₂S分子的静态特征,如平衡结构,最低能量,合理反应通道.从等值势能面图看出,反应Li+S+Li→Li₂S是一个无阈值反应.S原子攻击Li₂分子的反应通道上,有一个过渡态.Li原子攻击LiS分子通道上也有一个过渡态.     

Electromagnetically Induced Transparency and Absorption of A Monochromatic Light Controlled by a Radio Frequency Field

Electromagnetically induced transparency and absorption of a monochromatic light controlled by a radio frequency field in the cold multi-Zeeman-sublevel atoms are theoretically investigated. These Zeeman sublevels are coupled by a radio frequency(RF) field. Both electromagnetically induced transparency and electromagnetically induced absorption can be obtained by tuning the frequency of RF field for both the linear polarization and elliptical polarization monochromatic lights. When the transfer of coherence via spontaneous emission from the excited state to the ground state is considered, electromagnetically induced absorption can be changed into electromagnetically induced transparency with the change of intensity of radio field. The transparency windows controlled by the RF field can have potential applications in the magnetic-field measurement and quantum information processing.     

ICP-AES结合SVDV技术应用于饮用水品质检测性能诊断

采用电感耦合等离子体原子发射光谱(ICP-AES)技术,通过轴向、径向、同步垂直双向(SVDV)三个视角配置,快速检测生活饮用水样本中的As,Ba,Mg和Ni等微量元素。ICP-AES光谱仪在三个检测视角均能实现快速预热,预热时间仅需2 min,而且,ICP-AES光谱的短期稳定性和长期稳定性表现良好,其相对标准偏差(RSD)均低于2%。以3份商业瓶装饮用水和2份添加标准物的饮用水为检测的对象,利用ICP-AES技术结合SVDV视角,分别从轴向和SVDV两个视角检测As,Ba,Cr,Cu,Mn,Mo,Ni,V和Zn等元素,利用水微量元素含量的国家标准来验证结果的准确性,这两个视角的检测具有较高的准确度和灵敏度。检测所得结果符合国家环境保护总局发布的饮用水微量元素限制标准,并符合国际卫生组织的标准,满足人类所需饮用水标准要求。     

飞秒激光与固体靶相互作用的前向快电子束发散研究

为了研究前向快电子束的发散问题,采用飞秒激光辐照平面铜靶,以电子角分布仪和氟化锂(LiF)热释光探测器探测快电子的前向发散角。实验显示前向快电子束发散角均在95°(半高宽FWHM)以上。理论计算指出预等离子体中电子的初速度以及加速后的电子在靶内碰撞效应均不是产生大发散角的重要原因。根据激光-等离子体相互作用理论,等离子体中的电磁场才是导致前向快电子束产生较大发散角的主要原因。这个研究为获取较小发散角的前向快电子束提供了实验设置的依据。     

牛肉嫩度的近红外光谱法检测技术研究

利用近红外光谱技术研究了牛肉嫩度的检测方法。在波数为4 000～10 000 cm-1范围内测定牛肉样本近红外吸收光谱,然后用沃-布剪切仪测得牛肉样本(背长肌)的最大剪切力值并进行主观嫩度等级评价。把剪切力值小于6 kg的牛肉归为嫩牛肉,等级值定为1;大于9 kg的牛肉归为老牛肉,等级值定为3;介于6和9 kg之间的牛肉归为中等嫩度的牛肉,等级值定为2。研究结果表明,老牛肉吸收的近红外光一般都要比嫩牛肉多,表现为吸光度要大;用多元线性回归法对校正集建立模型,得到相关系数r为0.806;用此模型对牛肉预测集19个样本进行预测,分级正确率为84.21%。该研究说明利用近红外技术对牛肉嫩度进行预测是可行的。     

靶向分子羧甲基多糖与DNA作用机理研究

以溴化乙锭(EB)为荧光探针,结合紫外光谱法研究了壳聚糖、羧甲基壳聚糖、羧甲基纤维素与DNA的相互作用,药物分子与DNA作用程度可用作用常数D来表示,实验表明: 几种生物多糖与DNA分子的作用强弱顺序为: 壳聚糖＞羧甲基壳聚糖＞羧甲基纤维素;多糖主要以嵌插方式与DNA作用, 使EB-DNA荧光猝灭。     

Nd:GGG晶体荧光寿命的测试

针对Nd:GGG激光器,介绍了荧光寿命测试原理,设计了低频窄脉宽荧光寿命测试系统.该系统由光源、光路系统、驱动电路和探测系统等几部分组成.利用脉冲取样技术测试了Nd:GGG晶体的荧光寿命约为250μs左右.